Aluminum trifluoromethanesulfonate 三氟甲磺酸铝

CAS 74974-61-1 MFCD00143596

化学结构图

74974-61-1
SMILES: O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.[AlH3+3]

化学属性

Mol. Formula(CF3SO3)3Al
Mol. Weight474.19
Melting Point300
TSCANo
Appearance white pwdr.
Stabilityhygroscopic

别名和识别编码

Chemical NameAluminum trifluoromethanesulfonate
MDL NumberMFCD00143596
Synonym AgOTf cpd Al(OTf)3 Aluminum triflate Aluminum triflate; Aluminum tris(trifluoromethanesulfonate); Tris(trifluoromethanesulfonato)aluminum As(otf)2 Cu(OTf)2 Eu(OTf)3 In(OTf)3 TFMSA cpd aluminum triflate cerium triflate cupric trifluoromethanesulfonate indium triflate mercury(II) trifluoromethanesulfonate samarium triflate silver triflate silver trifluoromethanesulfonate triflic acid trifluoromethanesulfonate trifluoromethanesulfonic acid trifluoromethanesulfonic acid, aluminum salt trifluoromethanesulfonic acid, barium salt trifluoromethanesulfonic acid, cerium (+3) salt trifluoromethanesulfonic acid, cupric salt trifluoromethanesulfonic acid, indium salt trifluoromethanesulfonic acid, lanthanum (+3) salt {} {PubC
CAS Number74974-61-1
PubChem Substance ID2737634
Chemical Name Translation三氟甲磺酸铝
InChIInChI=1S/3CHF3O3S.Al/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
LabNetwork Molecule IDLN00220193
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分类

  • {SNA} Aluminum, Catalysis and Inorganic Chemistry, Chemical Synthesis

相关文献及参考

  • Catalyst for efficient, Chemoselective thioacetalization of carbonyl compounds, e.g. with 1,3-Propanedithiol, A15261: Synth. Commun., 33, 167 (2003).

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupIII
UN Number 3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition Hygroscopic
WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 8 C

系列性分类


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