1-Butyl-3-methylimidazolium chloride 1-丁基-3-甲基咪唑氯化物

CAS 79917-90-1 MFCD03095425

化学结构图

79917-90-1
SMILES: [Cl-].CCCCN1C=[N+](C)C=C1

化学属性

Mol. FormulaC8H15ClN2
Mol. Weight174.67
Melting Point70
TSCANo
Density1.422
Flash Point192 °C
Stability对湿度敏感
Appearance white to off-white solid

别名和识别编码

Chemical Name1-Butyl-3-methylimidazolium chloride
Synonym BASIONIC(R) ST 70, BMIMCL BMIMCL
MDL NumberMFCD03095425
PubChem Substance ID87565054
Beilstein Registry Number6449277
CAS Number79917-90-1
EC Number250-023-7
Chemical Name Translation1-丁基-3-甲基咪唑氯化物
Reaxys-RN6449224
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分类

  • {SNA} Chemical Synthesis, Imidazolium, Ionic Liquids, Specialty Synthesis
  • {SNA} Basionics, Chemical Synthesis, Imidazolium, Ionic Liquids, Specialty Synthesis

产品应用

  • 这种盐 (bmim) Cl- 和 AlCl3 可用于 Friedel-Crafts 烷基化反应

相关文献及参考

  • In the presence of methanesulfonic acid, alcohols can be converted to alkyl chlorides under mild conditions: Org. Lett., 3, 3727 (2001).
  • Merck: 14,1581

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R51/53
Storage condition Hygroscopic
Hazard Codes 6.1 T,N
Packing GroupIII
UN Number 2811
Hazard Class6.1

其他信息

  • Sigma Aldrich:79917-90-1(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. Ionic Liquids - Specialty Synthesis
  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. Ionic Liquids - Specialty Synthesis
  4. Imidazolium - Ionic Liquids
  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. Ionic Liquids - Specialty Synthesis
  4. Basionics® - Ionic Liquids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Imidazolium Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Ionic Liquids 离子液体
  3. Ammonium
  1. Ionic Liquids
  2. Ionic Liquids
  1. Ionic Liquids
  2. 96-6510 Ionic Liquid Kit 2: BMIM Kit