Anthracene 蒽
CAS 120-12-7 MFCD00001240
化学结构图
SMILES: C1CCC2CC3CCCCC3CC2C1
化学属性
| Mol. Formula | C14H10 |
|---|---|
| Mol. Weight | 178 |
| Boiling Point | 340 |
| Melting Point | 215-218 |
| Density | 1.250 |
| Flash Point | 121°(249°F) |
| TSCA | Yes |
| Autoignition Point | 1004 °F |
| Vapor Density | 6.15 (vs air) |
| Vapor Pressure | 1 mmHg ( 145 °C) |
| Solubility | 0.045 MG/L (25 ºC) |
| Stability | 对光敏感 |
| Appearance | powder |
| Refractive index | 1.5948 |
别名和识别编码
| Chemical Name | Anthracene |
|---|---|
| CAS Number | 120-12-7 |
| Synonym | 蒽 Anthracene Paranaphtalene 绿油脑,多环芳烃(PAH) Paranaphthalene Anthraxcene Paranaphthalene Anthracin anthracene Paranaphthalin C14H10 (anthracene) Coal tar pitch volatiles:anthracene 多环芳烃(PAH) Tetra Olive N2G 蒽标准溶液;绿油脑;多环芳烃(PAH) Anthracen NSC 7958 蒽标准溶液 Green Oil Paranaphtalene; Anthraxcene; Green oil Anthraxcene 绿油脑 蒽 溶液 |
| PubChem Substance ID | 87562040 |
| EC Number | 204-371-1 |
| Beilstein Registry Number | 1905429 |
| MDL Number | MFCD00001240 |
| Reaxys-RN | 1905429 |
| Merck Number | 682 |
| Chemical Name Translation | 蒽 |
| Wiswesser Line Notation | L C666J |
| LabNetwork Molecule ID | LN00193500 |
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分类
- {SNA} Additional Standards, All PAH Standards, Analytical Standards, CRMs, Certified Reference Materials (CRMs), Chromatography, Environmental Standards, Fluka CRMs for Chromatography (neats), Food and Cosmetic Component Standards, Organic CRMs Alphabetical, Organic CRMs TraceCERT, Organic Pollutant St
产品应用
- 用以检定茚。制造蒽醌及茜素染料，也用作杀虫剂、杀菌剂、汽油阻凝剂等。
相关文献及参考
- Merck: 14,682
- Short: II/25D
- Merck: 14,682 Beilstein: 5,IV,2281
安全信息
GHS Symbol
- H370 Causes damage to organs 导致器官损伤
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H301+H311+H331
- H303 May be harmfully swallowed 吞食可能有害
- H315 Causes skin irritation 会刺激皮肤
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P333+P313+P362+P364
- P304+P340+P312
- P305+P351+P338
- P305+P351+P338+P337+P313
- P308+P313
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S24 Avoid contact with skin 避免皮肤接触；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R50/53
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 660 mg/kg/33W-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application REFERENCE : ZEKBAI Zeitschrift fuer Krebsforschung. (Berlin, Fed. Rep. Ger.) V.1-75, 1903-71. For publisher information, see JCROD7. Volume(issue)/page/year: 60,697,1955
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3300 mg/kg/33W-I TOXIC EFFECTS : Tumorigenic - neoplastic by RTECS criteria Tumorigenic - tumors at site of application REFERENCE : NATWAY Naturwissenschaften. (Springer-Verlag, Heidelberger Platz 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.1- 1913- Volume(issue)/page/year: 42,159,1955
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 20 gm/kg/79W-I TOXIC EFFECTS : Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors REFERENCE : ZEKBAI Zeitschrift fuer Krebsforschung. (Berlin, Fed. Rep. Ger.) V.1-75, 1903-71. For publisher information, see JCROD7. Volume(issue)/page/year: 60,697,1955
TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : >17 gm/kg TOXIC EFFECTS : Liver - fatty liver degeneration REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 13(5),59,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 430 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PMRSDJ Progress in Mutation Research. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.1- 1981- Volume(issue)/page/year: 1,682,1981
TYPE OF TEST : Phage inhibition capacity TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 500 mg/L REFERENCE : PMRSDJ Progress in Mutation Research. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.1- 1981- Volume(issue)/page/year: 1,224,1981
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Rodent - mouse Lymphocyte DOSE/DURATION : 500 ug/L REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 12(Suppl 13),103,1988
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 500 mg/L REFERENCE : PMRSDJ Progress in Mutation Research. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017)
TYPE OF TEST : DNA damage TEST SYSTEM : Rodent - rat Liver DOSE/DURATION : 300 umol/L REFERENCE : SinJF# Personal Communication from J.F. Sina, Merck Institute for Therapeutic Research, West Point, PA 19486, Oct. 26, 1982 Volume(issue)/page/year: 26OCT1982
TYPE OF TEST : Morphological transformation TEST SYSTEM : Rodent - rat Embryo DOSE/DURATION : 108 ug/plate REFERENCE : JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 1,190,1981
TYPE OF TEST : Specific locus test ROUTE OF EXPOSURE : Oral TEST SYSTEM : Insect - Drosophila melanogaster DOSE/DURATION : 1 mmol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 341,235,1995
其他信息
- TCI Shanghai:蒽(区域精制法精制,熔段数:30) Anthracene Zone Refined (number of passes:30),>;99.5%(GC)(120-12-7)
- Acros Organics:Anthracene, p.a.(120-12-7)
- {
- 毒性分级:中毒
- 有蓝紫色荧光 ，澡纯品色黄，带绿色荧光。见光色变深。容易升华。溶于乙醇和乙醚，1g溶于67ml无水乙醇、70ml甲醇、62ml苯、85ml氯仿、200ml乙醚、31ml二硫化碳、86ml四氯化碳、125ml甲苯，不溶于水。有刺激性。
- {Chemical
- 上游原料:焦油 --> 焦油 --> 咔唑 --> 菲 --> 蒽油
- 灭火剂:砂土、二氧化碳、泡沫、雾状水
- col
- 稠环芳烃:蒽是含有三个环的稠环芳烃类化合物，分子式C14H10。天然存在于煤焦油中。蒽的三个环的中心在一条直线上，是菲的同分异构体。蒽为带有淡蓝色荧光的白色片状晶体或浅黄色针状结晶；熔点216℃，沸点340℃，相对密度1.283(25/4℃)；容易升华；不溶于水，难溶于乙醇和乙醚，易溶于热苯。蒽分子中9,10位的化学活性较高，用硝酸氧化，生成9，10－蒽醌（结构式见蒽醌），蒽是合成蒽醌染料及单宁的重要中间体；用钠和乙醇还原，生成9,10－二氢化蒽；加氯生成9,10－二氯化蒽，后者加热失去一分子氯化氢，变成9－氯蒽；蒽还可以作为共轭二烯，与顺丁烯二酐等在9,10位发生狄尔斯-阿尔德反应。 工业上从分馏煤焦油所得蒽油馏分中用结晶法分出粗蒽，再经升华提纯。高纯蒽用于制取单晶蒽，用在闪烁计数器上。蒽还可用作杀虫剂、杀菌剂和汽油阻凝剂。 以上信息由Chemicalbook的晓楠编辑整理。
- {Chemica
- 方法一:在煤焦油中，蒽的含量为1.4%。焦油连续蒸馏所得的I蒽油馏分段，占焦油12-14%，初馏点为300℃，在350℃前的馏出量为95%。I蒽油经冷却结晶、真空过滤
- 用途一:用于提取蒽、菲、咔
- 标准值 不确定度 单位
- 蒽价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xp400341 蒽;绿油脑 5ml 120元 2011/08/23 L0735501 蒽;绿油脑 250g 475元 2011/04/16 A09
- 用途四:本品主要用于制造染料中间体蒽醌及
- 方法一:在煤焦油中，蒽的含量为1.4%。焦油连续蒸馏所得的I蒽油馏分段，占焦油12-14%，初馏点为300℃，在350℃前的馏出量为95%。I蒽油经冷却结晶、真空过滤或用离心机脱除部分油分，离心后的粗蒽含油分大于20-25%，其余成分是：蒽25-30%，咔唑20-25%、菲30%左右。其中蒽的收率占焦油中蒽源的58-87%。除了苯和萘以外，蒽是煤焦油中最重要的组分之一。在蒽的工业生产中，因为必须把沸点相近的菲和咔唑分离掉，所以比萘的制造困难得多。即使把蒸馏、结晶及溶剂抽提巧妙地结合起来，其产率也只有40-50%。从粗蒽中提取和精制蒽，是先利用菲易溶于油的特性使菲与蒽、咔唑分离。进一
- 图谱信息:蒽(120-12-7)核磁图( 1 HNMR) 蒽(120-12-7)红外图谱(IR2) 蒽(120-12-7)红外图谱(IR1) 蒽(120-12-
- 用途四:本品主要用于制造染料中间体蒽醌及单宁。可用作杀虫剂、杀菌剂和汽油阻凝剂。高纯蒽用于制取单晶蒽，用在闪烁计数器上。
- 图谱信息:蒽(120-12-7)核磁图( 1 HNMR) 蒽(120-12-7)红外图谱(IR2) 蒽(120-12-7)红外图谱(IR1) 蒽(120-12-7)质谱(MS) 蒽(120-12-7)核磁图( 1
- 蒸气密度:6.15 (vs air)
- MOL 文件:120-12-7.mol
- Alfa Aesar:蒽,99% Anthracene, 99%(120-12-7)
- 下游产品:蒽醌 --> 9-乙烯基蒽 --> 9,10-蒽
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