Cyclooctene 环辛烯

CAS 931-87-3 MFCD00001753

化学结构图

931-87-3
SMILES: C1=C\CCCCCC/1

化学属性

Mol. FormulaC8H14
Mol. Weight110
Refractive indexn20/D 1.469(lit.)
Boiling Point145-146 °C(lit.)
Density0.846 g/mL at 25 °C(lit.)
Flash Point24°C(lit.)
TSCAYes
Melting Point-16 °C(lit.)
Solubility不溶于水，溶于乙醇、乙醚。

别名和识别编码

Chemical NameCyclooctene
CAS Number931-87-3
PubChem Substance ID638079
EC Number213-243-4
Beilstein Registry Number5(1)35
MDL NumberMFCD00001753
Synonym 顺-环辛烯 {uni_hamburg} CIS-CYCLOOCTENE cis-Cyclooctene,94% Cyclooctene, (Z)- (Z) cyclooctene 環辛烯 Cyclooctene, (1Z)- 环辛烯 CYCLOOCTENE, STANDARD FOR GC cis-Cyclooctene, stabilized, 95% Cis-Cyclooctene, 95%, stabilized (Z)-1-Cyclooctene cis-Cyclooctene, 95%, stab. (Z)-cyclooctene 1-Cyclooctene (Z)-Cycloocten cis-cyclooctene CYCLOOCTENE 顺-环辛烯, 95%, STAB.
Chemical Name Translation环辛烯
Reaxys-RN1280166
LabNetwork Molecule IDLN00195260
InChIInChI=1S/C8H14/c1-2-4-6-8-7-5-3-1/h1-2H,3-8H2/b2-1-
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分类

  • {SNA} A-C, Additional Standards, Alpha Sort, Analytical Standards, C, Chemical Class, Chromatography, Environmental Standards, Hydrocarbons, Neats and Solutions, Olefins, Organic Pollutant Standards, Petrochemical Standards, Substance classes, Volatile & Semivolatile Standards, Volatiles/ Semivolatiles, 分析/色谱
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, C, CO - CZ, Chemical Class, Chromatography, Environment

相关文献及参考

  • Beil. 5 ,IV,263
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oils, paraffins and polyethylenes; Subvolume C: Diamagnetic susceptibility and magnetic anisotropy of organic compounds. The data presented in this volume are based on the literature survey of the chemical abstracts up to 2005. The calculated values of diamagnetic susceptibility of organic compounds in the present subvolume II/27B are presented along with their experimental values. They have been calculated with the use of
  • For example of the addition of NOCl to an alkene and subsequent cleavage of the ɑ-chloro oxime by the abnormal Beckmann reaction to the ω-cyanoaldehyde, see: Org. Synth. Coll., 5, 266 (1973).
  • Addition of dibromocarbene (see Bromoform, A11904) and ring-opening by reaction with MeLi leads to the cyclic allene 1,2-cyclononadiene: Org. Synth. Coll., 5, 306 (1973).
  • The epoxidation of alkenes by H2O2 in methanol in the presence of acetonitrile is described for cyclooctene. The active species is the peroxyimidic acid, and the reaction is, with proper precautions, suitable for scale-up: Org. Synth. Coll., 7, 126 (1990).

安全信息

GHS Symbol
WGK Germany2
Hazard Codes 3 Xn
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P316
  • P303+P361+P353
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
UN Number 3295 UN 3295 3/PG 3
Risk Statements
  • R10 Flammable 易燃
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
Safety Statements
  • S29 Do not empty into drains 不要排入下水道；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Storage condition Flammables area Air Sensitive
Packing GroupIII
Hazard Class3
Warnings 危化品目录(2015) 危险化学品

其他信息

  • Acros Organics:顺-环辛烯 cis-Cyclooctene, stabilized, 95%(931-87-3)
  • TCI Shanghai:环辛烯 Cyclooctene,>;95.0%(GC)(931-88-4)
  • MSDS 信息:环辛烯(931-87-3).msds
  • MSDS 信息:cis-Cyclooctene(931-88-4).msds
  • 下游产品:1,2-环氧环辛烷
  • MOL 文件:931-88-4.mol
  • 图谱信息:环辛烯(931-88-4)红外图谱(IR1) 环辛烯(931-88-4)核磁图( 13 CNMR) 环辛烯(931-88-4)Raman光谱 环辛烯(931-88-4)核磁图( 1 HNMR) 环辛烯(931-88-4)质谱(MS)
  • 上游原料:四氢呋喃 --> 钯 --> 苯酐 --> 1,5-环辛二稀 --> 环辛醇
  • Alfa Aesar:顺-环辛烯,95%,stab. cis-Cyclooctene, 95%, stab.(931-87-3)
  • MOL 文件:931-87-3.mol
  • 不溶于水，溶于乙醇、乙醚。
  • 外观性质:无色液体。
  • 环辛烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0506 环辛烯 Cyclooctene 500ML 1690元 2014/06/02 C0506 环辛烯 Cyclooctene 25ML 306元
  • 环辛烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 154860010 环辛烯 cis-Cyclooctene 95%, stabilized 1 LT 4525元 2010/06/21 154862500 环辛烯 cis-Cyclooctene 95%, stabilized 250 ML 1599元 2010/05/25 A13477 顺-环辛烯, 95%, stab. cis-Cyclooctene, 95%, stab. 2.5L 2548元
  • Sigma Aldrich:931-87-3(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkenes 烯烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Hydrocarbons - Chemical Class
  5. Neats - Hydrocarbons
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkenes 烯烃
  5. Cyclic - Alkenes
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. C - Alphabetic
  5. CO - CZ - C
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkenes 烯烃
  5. Acyclic

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