Cyclopentadienylmanganese(I) Tricarbonyl 三羰基环戊二烯合锰
CAS 12079-65-1 MFCD00001440
化学结构图
SMILES: [Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1 |^1:7,8,9,10,11|
化学属性
| Mol. Formula | C5H5Mn(CO)3 |
|---|---|
| Mol. Weight | 204.06 |
| Melting Point | 72-76 °C(lit.) |
| TSCA | Yes |
| Appearance | yellow xtl. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | Cyclopentadienylmanganese(I) Tricarbonyl |
|---|---|
| MDL Number | MFCD00001440 |
| PubChem Substance ID | 24857312 |
| CAS Number | 12079-65-1 |
| EC Number | 235-142-4 |
| Synonym | Cyclopentadienyltricarbonylmanganese; Cymantrene; Manganese cyclopentadienyltricarbonyl Cyclopentadienylmangantricarbonyl Manganese cyclopentadienyltricarbonyl Manganese, tricarbonyl(η(5)-2,4-cyclopentadien-1-yl)- Manganese cyclopentadienyl tricarbonyl h5-Cyclopentadienylmanganese tricarbonyl Cyclopentadienylmanganese tricarbonyl Tricarbonylcyclopentadienylmanganese η5-Cyclopentadienylmanganese tricarbonyl Tricarbonyl(η5-2,4-cyclopentadien-1-yl)mangan Cymantrene Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)- Cyklopentadientrikarbonylmanganium Manganese, tricarbonyl(h5-2,4-cyclopentadien-1-yl)- Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)- p-Cyclopentadienylmanganese tricarbonyl Manganese, tricarbonyl-p-cyclopentadienyl- tricarbonyl(η-cyclopentadienyl)manganese 三羰基环戊二烯锰(I) Cyclopentadienyl-p-tricarbonylmanganese Manganese, tricarbonyl-pi-cyclopentadienyl- Tricarbonyl(η5-cyclopentadienyl)manganese(I) Tricarbonyl(h5-cyclopentadienyl)manganese Tricarbonyl-p-cyclopentadienylmanganese Cyclopentadienyl-manganese-tricarbonyl tricarbonyl(η cyclopentadienyl)manganese Tricarbonyl(η5-2,4-cyclopentadien-1-yl)manganese Cyclopentadienyltricarbonylmanganese |
| Chemical Name Translation | 三羰基环戊二烯合锰 |
| Wiswesser Line Notation | L5J A-MN-VHVHVH |
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分类
- {uni_hamburg} no charge; metal-organic; other heterocycle; carbocycle; alicycle; fused rings; 3ring; 4ring; 5ring; 6ring; metal carbonyl; 1fragment; zwitterion
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Manganese, Materials Science, Micro/NanoElectronics, Vapor Deposition Precursors
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Manganese, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学
相关文献及参考
- Beil. 16 ,IV,1777
- Corp MSDS 1 (1), 983:A / FT-IR 2 (3), 4582:D / FT-NMR 1 (3), 779:B / RegBook 1 (2), 3135:C / Sax 6 , 842 / Structure Index 1 , 495:D:7
- Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
- Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic
安全信息
GHS Symbol
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P310
- H300 Fatal if swallowed 吞食致命
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R28 Very toxic if swallowed 吞咽极毒
- R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 710 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#11285
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 14 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - chronic pulmonary edema Lungs, Thorax, or Respiration - dyspnea REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 34,341,1985
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 22 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 34,341,1985
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 120 mg/m3/2H TOXIC EFFECTS : Vascular - BP lowering not characterized in autonomic section Blood - hemorrhage Lungs, Thorax, or Respiration - other changes REFERENCE : HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 30(4-6),40,1965
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