2-Aminophenol 2-氨基苯酚

CAS 95-55-6 MFCD00007690

化学结构图

95-55-6
SMILES: NC1CCCCC1O

化学属性

Mol. FormulaC6H7NO
Mol. Weight109
Melting Point170-175
Density1.328
Flash Point>175°(347°F)
TSCAYes
Boiling Point150
Solubility17 G/L (20 ºC)
Stability对光和空气敏感

别名和识别编码

Chemical Name2-Aminophenol
CAS Number95-55-6
EC Number202-431-1
Beilstein Registry Number1903393
MDL NumberMFCD00007690
PubChem Substance ID5801
Reaxys-RN606075
Merck Number461
Synonym 2-Aminophenol {LY} 2-Aminophenol 2-HYDROXYANILINE 2-Hydroxyaniline 2-Hydroxyaniline H 2-amino-pheno 2-hydroxybenzenamine 2-氨基-1-羟基苯 2-氨基苯酚;2-氨基-1-羟基苯;2-羟基苯胺 2-氨荃苯酚 o-hydroxyphenylamine BASF ursol 3GA Benzene, 1hydroxy-2-amine- Benzofur GG Durene LABOTEST-BB LTBB000484 Nako Yellow 3GA OAP Pelagol Grey GG Phenol, o-amino- Zoba 3GA benzofurgg {} {LY} 2-Aminophenol {} {} {LY} 2-Aminophenol {} {} {} {LY} 2-Aminophenol {} {} {} {} {} {} {} {} {LY} 2-Aminophenol {} {} {} {} {} {LY} 2-Aminophenol {} {} {} {} {} {} {LY} 2-Aminophenol {} {} {} {} {} {} {} {LY} 2-Aminophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Aminophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation2-氨基苯酚
Wiswesser Line NotationZR BQ
LabNetwork Molecule IDLN00192922
InChIInChI=1S/C6H7NO/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2
Canonical SMILESNC1=C(O)C=CC=C1
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分类

  • {SNA} A, A-B,
  • A, A-B, AM to AQ, Alpha sort, Alphabetic, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography, Environmental Standards, Pe

产品应用

  • 有机合成和染料中间体。用于生产酸性媒介蓝R；硫化黄棕；荧光增白剂EBF等。也是金；银的检定试剂。该品被皮肤吸收会引起皮炎，引起高铁血红蛋白症和哮喘。

相关文献及参考

  • Short: II/27B
  • Merck: 14,461 Beilstein: 13,IV,805
  • Short: II/3
  • Merck: 14,461

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes 6.1 Xn Xn,C
RTECSSJ4950000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P333+P313+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P308+P313
  • P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S20/22
  • S68
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
UN Number 2512
Packing GroupIII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 131,151,1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - quail
DOSE/DURATION           : 316 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 34,307,1971

{hazard_com

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 37 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKYUA6 Yakkyoku.  Pharmacy.  (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo,
   Japan)  V.1-    1950-  Volume(issue)/page/year: 32,1093,1981

TYPE OF TEST            : LD50 -

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 20 ug/well
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 133,161,1984

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 19 umol/L
REFERENCE :
   CRTOEC Chemical Research in Toxicology.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB 57/36, West End Station, Washington, DC
   20037)  V.1-    1988-  Volume(issue)/page/year: 4,151,1991

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 150 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Specific Developmental Abnormalities - Central Nervous System
   Reproductive - Specific Developmental Abnormalities - eye/ear
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   63,264,1982

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - hamster
DOSE                    : 150 mg/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - body wall
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   63,264,1982

Restrict 危险品

其他信息

  • Acros Organics:邻氨基苯酚 2-Aminophenol, 99%(95-55-6)
  • 色指数:76520
  • 毒性分级:中毒
  • 灭火剂:干粉、泡沫、砂土, 二氧化碳, 雾状水
  • 方法二:以邻硝基酚为原料，用硫化钠还原或用氢气还原而得；也可由邻硝基氯苯经水解、还原制得。1.硫化钠还原法2.催化加氢法
  • 急性毒性:口服-大鼠LD50: 1300 毫克/公斤; 口服-小鼠LD50: 1250 毫克/公斤
  • 能升华。1g溶于23ml乙醇。易溶于乙醚，极微溶于苯。水中溶解度: 17 g/l(20°C) ，有刺激性。
  • 用途五:有机合成和染料中间体。用于生产酸性媒介蓝R；硫化黄棕；荧光增白剂EBF等。也是金；银的检定试剂。该品被皮肤吸收会引起皮炎，引起高铁血红蛋白症和哮喘。
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物烟雾
  • 类别:有毒物品
  • 海关编码:29222900
  • 下游产品:4-乙烯基吡啶 --> 8-羟基喹啉 --> 荧光增白剂 185 --> 5-甲氧基甲基-2,3-吡啶二羧酸 --> 恶唑禾草灵 --> 伏杀磷 --> 8-羟基喹啉铜 --> 2-氯苯并恶唑 --> 媒介蓝 13 --> 活性蓝104 --> 吡诺克辛 --> 直接红 BWS --> 8-羟基喹哪啶 --> 活性蓝X-R --> 乙二醛缩双(邻氨基苯酚) --> 2-苯并唑啉酮 --> 荧光增白剂 367 --> 邻乙酰氨基酚
  • 用途三:邻氯基苯酚是除草剂噁唑禾草灵和杀虫剂伏杀硫磷的原料，也是染料中间体。
  • 用途四:有机合成和染料中间体。用于生产酸性媒介蓝R、硫化黄棕、荧光增白剂EBF等。也是金、银的检定试剂。该品被皮肤吸收会引起皮炎，引起高铁血红蛋白症和哮喘。
  • Alfa Aesar:2-氨基苯酚,99% 2-Aminophenol, 99%(95-55-6)
  • 上游原料:硫化钠 --> 邻氯硝基苯 --> 2-硝基苯酚
  • 图谱信息:2-氨基苯酚(95-55-6)质谱(MS) 2-氨基苯酚(95-55-6)红外图谱(IR1) 2-氨基苯酚(95-55-6)核磁图( 1 HNMR) 2-氨基苯酚(95-55-6)核磁图( 13 CNMR)
  • 外观性质:白色或浅灰色结晶粉末。
  • 用途一:用作分析试剂及重氮染料和硫化染料的中间体
  • MOL 文件:95-55-6.mol
  • F:8-10-23
  • 2-氨基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80005226 2-氨基酚;邻氨基酚;2-羟基苯胺;2-氨基-1-羟基苯 100g 70元 2011/04/16 A0335 2-氨基苯酚 2-Aminophenol 25G 178元 2011/04/16 A0335 2-氨基苯酚 2-Aminophenol 500G 1020元
  • TCI Shanghai:2-氨基苯酚 2-Aminophenol,>;98.0%(GC)(T)(95-55-6)
  • 用途二:用作染料和医药的重要中间体
  • 储运特性:库房通风低温干燥
  • 刺激数据:眼睛-兔子100 毫克 轻度
  • 方法一:其制备方法是在反应釜内加入邻硝基苯酚和硫化钠，反应温度120～125℃，反应时间12h，并不断搅拌，还原完毕，冷却，加盐酸酸化至pH＝6～7，此时邻氨基酚和硫磺均析出，冷至室温，过滤、水洗、滤干得粗品，用乙醇重结晶得成品。
  • Sigma Aldrich:95-55-6(sigmaaldrich)
  • MSDS 信息:2-氨基苯酚(95-55-6).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Protected Alcohols/Phenols - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Amines - Chemical Class
  5. Aromatics - Amines
  1. Life Science 生命科学
  2. Antibodies (Primary & Secondary) 抗体
  3. Primary Antibodies, Including Antibodies for Cell Biology & Neuroscience
  4. Cell Biology Primary Antibodies
  5. Antibodies for Cell Cycle - Antibodies for Cell Biology
  6. Antibodies to Check Point Proteins - Antibodies for Cell Cycle
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers

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