2-Aminobenzenethiol 2-氨基苯硫醇

CAS 137-07-5 MFCD00007702

化学结构图

137-07-5
SMILES: Nc1ccccc1S

化学属性

Mol. FormulaC6H7NS
Mol. Weight125.19
Density1.17
Refractive index1.6400 to 1.6450
Boiling Point
Melting PointNo Data Available
Flash Point79.44°C
TSCAYes
Solubility不溶
Stability对空气敏感

别名和识别编码

Chemical Name2-Aminobenzenethiol
CAS Number137-07-5
Synonym 2-Aminothiophenol 90% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number205-277-3
Beilstein Registry Number606076
MDL NumberMFCD00007702
PubChem Substance ID87561922
Reaxys-RN606076
Chemical Name Translation2-氨基苯硫醇
InChIKeyVRVRGVPWCUEOGV-UHFFFAOYSA-N
Wiswesser Line NotationZR BSH
LabNetwork Molecule IDLN00008094
Canonical SMILESSC1=CC=CC=C1N
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分类

  • Sulfur & Selenium Compounds
  • Aromatics
  • Amines
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; thiol; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiols/Mercaptans

产品应用

  • 磷地尔的中间体。

相关文献及参考

  • Beilstein:13(2)198
  • Short: III/35D2
  • Sies, H., et al.: Eur. J. Biochem., 215, 213 (1993),
  • Short: II/27B
  • Reacts with carboxylic acid chlorides in N-methylpyrrolidinone to give 2-substituted benzothiazoles: Synth. Commun., 20, 3379 (1990), and with substituted benzonitriles in the presence of sodium hydride to give 2-arylbenzothiazoles: Heterocycles, 38, 1001 (1994).
  • Meotti, F., et al.: Environ. Res., 94, 276 (2004),

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R50/53
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSDC0600000
Packing GroupIII
UN Number 1760 3267
Storage condition -20 -20°C -20℃ Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes 8 C,N
Hazard Class8
Warnings 危化品目录(2015) 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Blood - methemoglobinemia-carboxyhemoglobin
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,90,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02532

Restrict 危险品

其他信息

  • 2-氨基苯硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0267 2-氨基苯硫酚 2-Aminobenzenethiol 500ML 1600元 2014/06/02 A0267 2-氨基苯硫酚 2-Aminobenzenethiol 25ML 284元 2010/06/21 153901000 2-氨基苯硫醇 2-Aminothiophenol 98% 100 GR 449元
  • Hazard Note:Corrosive/Stench
  • 储运特性:库房通风低温干燥; 与食品、酸类、氧化剂分开储运
  • 2-氨基苯硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A0267 2-氨基苯硫酚 2-Aminobenzenethiol 500ML 1310元 2011/04/16 A0267 2-氨基苯硫酚 2-Aminobenzenethiol 25ML 234元 2010/06/21 153901000 2-氨基苯硫醇 2-Aminothiophenol 98% 100 GR 449元
  • 敏感性:Stench
  • 灭火剂:泡沫、干粉、二氧化碳
  • 类别:有毒物品
  • Alfa Aesar:2-氨基硫代苯酚,98% 2-Aminothiophenol, 98%(137-07-5)
  • 下游产品:2-巯基苯并噻唑 --> C545T --> 香豆素 6 --> 1,3-苯并噻唑-2-羰酰氯 --> 溶剂黄 98 --> 2-(4-甲基苯基)苯并噻唑 --> 盐酸地尔硫卓 --> 溶剂橙 63 --> 1,3-苯并噻唑-2-羧酸乙酯
  • 海关编码:29309070
  • 不溶于水，溶于大多数有机溶剂。
  • 上游原料:硫化钠 --> 邻氯硝基苯 --> 二硫化钼
  • 急性毒性:口服-大鼠 LDL0: 500 毫克/ 公斤; 腹腔- 小鼠 LD50: 25 毫克/ 公斤
  • F:9-13-23
  • MSDS 信息:邻氨基苯硫酚(137-07-5).msds
  • MOL 文件:137-07-5.mol
  • 方法一:用邻硝基氯苯与硫化钠反应，生成的二硫化物经还原制得该品。
  • 毒性分级:高毒
  • TCI Shanghai:2-氨基苯硫酚 2-Aminobenzenethiol,>;95.0%(GC)(137-07-5)
  • 用途一:磷地尔的中间体。
  • Sigma Aldrich:137-07-5(sigmaaldrich)
  • 图谱信息:2-氨基苯硫醇(137-07-5)核磁图( 13 CNMR) 2-氨基苯硫醇(137-07-5)质谱(MS) 2-氨基苯硫醇(137-07-5)红外图谱(IR1) 2-氨基苯硫醇(137-07-5)核磁图( 1 HNMR)
  • Acros Organics:邻氨基硫代苯酚 2-Aminothiophenol, 98%(137-07-5)
  • 外观性质:淡黄色液体或固体，有恶臭味。
  • 可燃性危险特性:明火可燃; 遇热放出有毒氧化硫、氧化氮气体

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiols/Mercaptans - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiol/Mercaptan Salts
  1. Analytical & Chromatography 分析化学与色谱
  2. Labeling Reagents for HPLC

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