Bromobenzene 溴苯

CAS 108-86-1 MFCD00000055

化学结构图

108-86-1
SMILES: Brc1ccccc1

化学属性

Mol. FormulaC6H5Br
Mol. Weight157
Density1.491
Refractive index1.5590 to 1.5610
Autoignition Point1051 °F
Vapor Density5.41 (vs air)
Boiling Point156
Vapor Pressure10 mmHg ( 40 °C)
Melting Point-31
Flash Point51°C(lit.)
Solubility不溶于水，溶于甲醇、乙醚、丙酮、苯、四氯化碳等多数有机溶剂。
TSCAYes
Stability对光敏感
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameBromobenzene
CAS Number108-86-1
EC Number203-623-8
Beilstein Registry Number1236661
Reaxys-RN1236661
PubChem Substance ID87563476
MDL NumberMFCD00000055
Merck Number1406
Synonym Bromobenzol 溴苯;溴代苯;溴化苯;一溴苯;苯基溴 溴苯,99% Benzene,bromo- Bromobenzene, pure, 99% 溴化苯 bromo-benzene BENZENE BROMIDE monobromobenzene BROMOBENZENE extrapure BROMOBENZENE Brombenzen Bromobenzene 99+ % bromo-benzen Bromobenzene (1mg/ml in Methanol) [for Water Analysis] p-bromobenzene 一溴代苯 1-Bromobenzene BROMOBENZENE, REAGENTPLUS, >=99% PHENYL BROMIDE 一溴代苯B AKOS BBS-00004272 C6H5Br (bromobenzene) Phenylbromide; Monobromobenzene 溴代苯，溴化苯，一溴苯，苯基溴 NCI-C55492 一溴苯 溴代苯 phenyl br
Chemical Name Translation溴苯
Wiswesser Line NotationER
LabNetwork Molecule IDLN00194621
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分类

  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 拟除虫菊酯类杀虫剂
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SA} Aryl, Building Blocks, C6, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {SNA} Aryl, Building Blocks, C6, Chemical Synthesis, Essential Chemicals,

产品应用

  • 用作溶剂、分析试剂，用于有机合成等。

相关文献及参考

  • Short: II/25D
  • Merck:14,1406 Beilstein: 5,IV,670
  • Merck:14,1406
  • Short: II/27B

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R51/53
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
UN Number 2514
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
RTECSCY9000000
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 Xi,N Xi,N,F,T Xi;N
Packing GroupIII
Hazard Class3
Storage condition 密封避光保存。 2-8°C 储存温度2-8℃
Warnings 危化品目录(2015) 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 21 gm/m3/2H
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle contraction or spasticity
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 13(9),56,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 817 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 2,111,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2699 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 19(9),36,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2700 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle contraction or spasticity
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 250 mg/L
REFERENCE :
   JJIND8 JNCI, Journal of the National Cancer Institute.  (Washington, DC)
   V.61-79, 1978-87. For publisher information, see JNCIEQ.
   Volume(issue)/page/year: 62,873,1979

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 125 mg/kg/24H
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 2,111,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 500 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

Restrict -

其他信息

  • Alfa Aesar:溴苯,99% Bromobenzene, 99%(108-86-1)
  • TCI Shanghai:溴苯(1mg/ml的甲醇溶液)[用于水分析] Bromobenzene (1mg/ml in Methanol) [for Water Analysis](108-86-1)
  • 方法二:由苯与溴反应而得。先将铁粉和苯加入反应器，在搅拌下慢慢加入溴素，加完后于70-80℃保温反应1h，所得粗品用水及5%氢氧化钠溶液洗涤，静置分层，蒸馏、干燥、过滤，最后经常压分馏，取155-157℃馏分而得成品。
  • 方法一:其制备方法是用苯与溴反应，以铁粉为催化剂进行溴化，溴加完后在70～80℃保温反应1h，然后水洗、干燥、蒸馏而得产品。
  • 用途三:溴苯是精细化工品的原料，也是制备农药的基本原料。
  • 毒性分级:中毒
  • 急性毒性:口服- 大鼠 LD50: 2699 毫克/ 公斤; 口服- 小
  • {Chemical
  • 可燃性危险特性:遇明
  • MOL 文件:108-86-1.mol
  • 爆炸物危险特性:与空气混合可爆
  • 蒸气密度:5.41 (vs air)
  • 用途一:用于合成医药、农药、染料等
  • Acros Organics:溴苯 Bromobenzene, pure, 99%(108-86-1)
  • 下游产品:苯硅烷 --> 对三联苯 --> 溴灭菊酯 --> 三氯生 --> 四苯硼钠 --> 3-氯-2-甲基联苯 --> 2-甲氧基苯乙酮 --> 氯代(邻氯苯基)二苯基甲烷 --> (4R,5R)-2,2-二甲基-a,a,a',a'-四苯基-1,3-二氧戊环-4,5-二甲醇 --> 4-辛基苯甲醛 --> (4S,5S)-(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(二苯基甲醇) --> 丁苯 --> 尼美舒利 --> N-苯基邻氨基苯甲酸 --> 双苯溴丁酸 --> 溴氟菊酯 --> 二苯亚甲基甘氨酸乙酯 --> 4-溴苯磺酰胺 --> 2-苯基苄胺 --> 苯甲酰甲酸乙酯 --> 4-苯氧基苯酚 --> (2-氯苯基)二苯基甲醇 --> 多虑平 --> 1-溴-4-硝基苯 --> 二苯基(4-吡啶基)甲醇 --> 三苯基锡醋酸盐 --> 异丙基联苯膦,99% --> 2-苯基喹啉 --> (+/-)-3-苯基丁酸 --> 1-苯基咪唑 --> 烯丙苯 --> α,α-二苯基-γ-丁内酯 --> 苯基三乙氧基硅烷 --> 二苯基二硒醚
  • 图谱信息:溴苯(108-86-1)红外图谱(IR1) 溴苯(108-86-1)红外图谱(IR2) 溴苯(108-86-1)质谱(MS) 溴苯(108-86-1)核磁图( 13 CNMR) 溴苯(108-86-1)核磁图( 1 HNMR)
  • 溴苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81002518 溴代苯 500ml 75元 2011/08/23 81002528 溴代苯 500ml 73.5元 2011/08/23 xp400261 溴代苯 5ml 38元
  • MSDS 信息:溴苯(108-86-1).msds
  • 类别:易燃液体
  • 储运特性:包装完整、轻装轻放; 库房通风、远离明火、高温、与氧化剂分开存放
  • 挥发性有机化合物(VOCs)单组分标准液
  • 具有折光，有特殊苯的芳香气味。不溶于水，溶于甲醇、乙醚、丙酮、苯、四氯化碳等多数有机溶剂，有刺激性。
  • 外观性质:无色油状液体，具有苯的气
  • 用途四:有机合成原料。医药中间体。
  • 理化性质:溴苯又称苯基溴、一溴代苯，是苯在铁粉存在下被溴取代生成的一种苯卤素衍生物，与苯的氯化反应生产氯苯的化学反应原理相同。 图1为溴
  • 外观
  • 理化性质:溴苯又称苯基溴、一溴代苯，是苯在铁粉存在下
  • 用途二:用作溶剂、汽车燃料、有机合成原料、制药中间体等

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C6 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C6 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Bromo 溴化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. Alpha Sort - Volatiles/ Semivolatiles
  7. A-B - Alpha Sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BI - BZ - B
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C13 to C37+