Triphenylsilyl chloride 三苯基氯硅烷

CAS 76-86-8 MFCD00000496

化学结构图

76-86-8
SMILES: Cl[Si](c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. Formula(C6H5)3SiCl
Mol. Weight295
Melting Point91-96
Flash Point>200°(392°F)
TSCAYes
Boiling Point378
Stability对湿度敏感
Solubilityacetone: 0.1 g/mL, clear
Density1.14
pH:A

别名和识别编码

Chemical NameTriphenylsilyl chloride
Synonym triphenyl-chloro-silane TRIPHENLCHLOROSILANE Chlortriphenylsilan 一氯三苯基硅烷 三苯氯矽烷 triphenylchlorosilane chlorotriphenylsilane TRIPHENYLCHLOROSILANE 三苯基氯硅烷 氯三苯基硅烷 TSL 8061 silane, chlorotriphenyl- Triphenylchlorosilane,97% 氯化三苯基硅烷 TPSCl Chlorotriphenylsilane triphenylchlorosilicane Triphenylchlorosilane Triphenylsilicon chloride Triphenylchlorosilane,96% 三苯基烷基氯 Triphenylsilyl chloride 氯化三苯基硅烷,三苯基烷基氯 Chloro-triphenyl-silane Triphenylsilylchlorid silane,chlorotriphenyl- Triphenylchlorsoilane TriphenylchlorosilaneTPSCl TPSCl Triphenylchlorosilane TPSCl, Triphenylchlorosilane Triphenyltrichlorosilane Chlorotriphenylsilane; Triphenylchlorosilane TPSCL TRIPHENYLSILICON CHLORIDE Triphenylchlorosilane(Chlorotriphenylsilane) chlorotriphenyl-silan TRIPHENYLSILYL CHLORIDE Triphenylchlorsilan Silane, chlorotriphenyl- 三苯基氯硅烷, 97% Triphenylchlorosilane (TPSCl) 2,4,6-三异丙基苯磺酰氯
MDL NumberMFCD00000496
CAS Number76-86-8
PubChem Substance ID6458
Beilstein Registry Number1820487
EC Number200-989-0
Reaxys-RN1820487
Chemical Name Translation三苯基氯硅烷
InChIKeyMNKYQPOFRKPUAE-UHFFFAOYSA-N
Wiswesser Line NotationG-SI-R&R&R
LabNetwork Molecule IDLN00222616
InChIInChI=1S/C18H15ClSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents

产品应用

  • 硅烷化试剂。制药和有机合成中间体。

相关文献及参考

  • Short: III/35C4
  • Short: III/35F
  • Silylating agent: J. Chem. Soc., 3403 (1963); see Appendix 4. The stability of the bulky triphenylsilyl (TPS) ethers to basic hydrolysis is similar to TMS, but they are about 400x more stable to acid hydrolysis. Suitable conditions for their cleavage include: ethanolic NaOH; AcOH - water - THF at 70o: Chem. Lett., 1499 (1979); and TBAF: J. Am .Chem. Soc., 108, 3827 (1986).
  • Beilstein:16(3)1208

安全信息

WGK Germany1
GHS Symbol
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSVV2720000
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Packing GroupII
UN Number 1759 3261 UN 3261 8/PG 2 UN3261
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
Storage condition Moisture Sensitive 0-10 充氩密封干燥保存。 0-10°C Refrigerator
Hazard Codes 8 C
Hazard Class8
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04717

Restrict 危险品

其他信息

  • 海关编码:29310095
  • Alfa Aesar:三苯基氯硅烷,97% Chlorotriphenylsilane, 97%(76-86-8)
  • 三苯基氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0939 三苯基氯硅烷 Triphenylchlorosilane 5G 168元 2014/06/02 T0939 三苯基氯硅烷 Triphenylchlorosilane 25G 532元 2010/06/21 151251000 三苯基氯硅烷 Chlorotriphenylsilane 95% 100 GR 2462元
  • 急性毒性:静注- 小鼠 LD50: 56 毫克/ 公斤
  • TCI Shanghai:三苯基氯硅烷 Triphenylchlorosilane,>;95.0%(GC)(76-86-8)
  • MOL 文件:76-86-8.mol
  • 对湿敏感。溶于丙酮，在水中分解。有腐蚀性。
  • 灭火剂:砂土、干石粉、二氧化碳
  • F:10-21
  • 用途三:硅烷化试剂。制药和有机合成中间体。
  • TSCA:Yes
  • 类别:腐蚀物品
  • 可燃性危险特性:可燃; 遇水或受热分解有毒氯化物气体
  • MSDS 信息:三苯基氯硅烷(76-86-8).msds
  • 用途二:制药和有机合成中间体。
  • 储运特性:库房通风低温干燥; 与氧化剂、碱类、潮湿物分开存放
  • Acros Organics:三苯基氯硅烷 Chlorotriphenylsilane, 95%(76-86-8)
  • Sigma Aldrich:76-86-8(sigmaaldrich)
  • 用途一:用于制药及有机合成
  • 毒性分级:高毒
  • 图谱信息:三苯基氯硅烷(76-86-8)核磁图( 1 HNMR) 三苯基氯硅烷(76-86-8)红外图谱(IR2) 三苯基氯硅烷(76-86-8)核磁图( 13 CNMR) 三苯基氯硅烷(76-86-8)红外图谱(IR1) 三苯基氯硅烷(76-86-8)质谱(MS)
  • 外观性质:白色固体, 易水解。
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Silicon-Based - Protecting and Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物

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