Chlorodiphenylphosphine 二苯基氯化膦

CAS 1079-66-9 MFCD00000529

化学结构图

1079-66-9
SMILES: ClP(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC12H10ClP
Mol. Weight220.64
Density1.194 g/mL at 25 °C
Refractive index1.6340 to 1.6370
Flash Point138°C(lit.)
TSCAYes
Boiling Point215°C/57mmHg(lit.)
Melting Point14-16°
Vapor Density7.8 (vs air)
Solubility起反应 VIOLENTLY
Stability对空气和湿度敏感
Appearance yellow liq.
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameChlorodiphenylphosphine
Synonym Chlorodiphenylphosphine {LY} Chlorodiphenylphosphine {} {LY} Chlorodiphenylphosphine {} {} {LY} Chlorodiphenylphosphine {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00000529
CAS Number1079-66-9
EC Number214-093-2
Beilstein Registry Number16,763
PubChem Substance ID66180
Reaxys-RN512032
Chemical Name Translation二苯基氯化膦
LabNetwork Molecule IDLN00225723
InChIInChI=1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
Canonical SMILESClP(C1=CC=CC=C1)C2=CC=CC=C2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors

产品应用

  • 合成中锂化反应引入二苯基磷。

相关文献及参考

  • Short: EINECS
  • Short: III/20b
  • Beilstein:16,763
  • Reacts with Li metal in liquid ammonia to give the Li diphenylphosphide: Tetrahedron Lett., 21, 3535 (1980). Reaction with vinyl lithium intermediates from the reaction of alkyllithiums with sulfonylhydrazones (see p-Toluenesulfonyl­ hydrazide, A13529) gives vinylphosphines: Tetrahedron Lett., 22, 4619 (1981).

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S8 Keep container dry 保持容器干燥；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S25 Avoid contact with eyes 避免眼睛接触；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupII
UN Number UN3265 3265 UN 3265 8/PG 2
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air & Moisture Sensitive N/A℃ Store at R.T. {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY}
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
Hazard Class8
Restrict -

其他信息

  • 图谱信息:二苯基氯化膦(1079-66-9)红外图谱(IR1) 二苯基氯化膦(1079-66-9)质谱(MS) 二苯基氯化膦(1079-66-9)核磁图( 13 CNMR) 二苯基氯化膦(1079-66-9)核磁图( 1 HNMR)
  • 海关编码:29310095
  • Sigma Aldrich:1079-66-9(sigmaaldrich)
  • 检测方法:GC
  • 外观性质:无色透明液体。 折光率n20/D：1.636沸点:320 °C密度：1.229 闪点：112 °C
  • F:1-9-19
  • 敏感性:Air & Moisture Sensitive
  • Alfa Aesar:二苯基氯化膦,98+% Chlorodiphenylphosphine, 98+%(1079-66-9)
  • MOL 文件:1079-66-9.mol
  • 蒸气密度:7.8 (vs air)
  • 用途一:合成中锂化反应引入二苯基磷。
  • 二苯基氯化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0597 二苯基氯化膦 Chlorodiphenylphosphine 25G 205元 2014/06/02 C0597 二苯基氯化膦 Chlorodiphenylphosphine 500G 1800元 2010/06/21 109130250 二苯基氯化膦 Chlorodiphenylphosphine 95%, tech. 25 ML 663元
  • TCI Shanghai:二苯基氯化膦 Chlorodiphenylphosphine,>;97.0%(T)(1079-66-9)
  • 下游产品:二苯基膦 --> 1,1'-双(二苯基膦)二茂铁 --> 4,5-双二苯基膦-9,9-二甲基氧杂蒽 --> (R)-(-)-1-[(S)-2-二苯基磷二茂铁乙基-二叔丁基磷 --> 双(2-二苯基磷苯基)醚
  • Acros Organics:二苯基氯化膦 Chlorodiphenylphosphine, tech., 95%(1079-66-9)
  • MSDS 信息:Chlorodiphenylphosphine(1079-66-9).msds
  • TSCA:Yes

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Titration - Analytical Reagents
  4. Karl Fischer Titration HYDRANAL® Reagents for Water Determination
  5. Volumetric Reagents for Volumetric Karl Fischer Titration
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Phosphite Ligands
  1. Phosphine
  2. Phosphorus

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