Phenylphosphonic dichloride 苯膦酰二氯

CAS 824-72-6 MFCD00002070

化学结构图

824-72-6
SMILES: O=P(Cl)(Cl)c1ccccc1

化学属性

Mol. FormulaC6H5Cl2OP
Mol. Weight194.98
Density1.375
Refractive index1.5580 to 1.5610
Boiling Point258
Melting Point3
Flash Point153°C(lit.)
TSCAYes
Solubility起反应
Appearance colorless to light yellow liq.
Stabilityair sensitive, moisture sensitive
pH:A

别名和识别编码

Chemical NamePhenylphosphonic dichloride
Synonym Phenylphosphonic Dichloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00002070
CAS Number824-72-6
EC Number212-534-3
Beilstein Registry Number16,804
PubChem Substance ID69990
Chemical Name Translation苯膦酰二氯
Reaxys-RN1072240
LabNetwork Molecule IDLN00195348
InChIInChI=1S/C6H5Cl2OP/c7-10(8,9)6-4-2-1-3-5-6/h1-5H
Canonical SMILESO=P(C1=CC=CC=C1)(Cl)Cl
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors

相关文献及参考

  • Short: II/25D
  • Short: III/20b

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S8 Keep container dry 保持容器干燥；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P403+P233
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 3265
Storage condition 4 4℃ N/A No Data Available Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes C
Hazard Class8
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • Alfa Aesar:苯基二氯化磷,90+% Phenylphosphonic dichloride, 90+%(824-72-6)
  • 苯膦酰二氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0334 苯基膦酰二氯 Phenylphosphonic Dichloride 500ML 2160元 2014/06/02 P0334 苯基膦酰二氯 Phenylphosphonic Dichloride 25ML 253元 2010/06/21 130802500 苯膦酰二氯 Phenylphosphonic dichloride 97% 250 ML 1145元
  • 海关编码:29310095
  • TCI Shanghai:苯基膦酰二氯 Phenylphosphonic Dichloride,>;98.0%(GC)(T)(824-72-6)
  • Sigma Aldrich:824-72-6(sigmaaldrich)
  • 图谱信息:苯膦酰二氯(824-72-6)质谱(MS) 苯膦酰二氯(824-72-6)Raman光谱 苯膦酰二氯(824-72-6)核磁图( 1 HNMR) 苯膦酰二氯(824-72-6)核磁图( 13 CNMR) 苯膦酰二氯(824-72-6)红外图谱(IR1)
  • MSDS 信息:苯膦酰二氯(824-72-6).msds
  • 方法一:由苯硫代二氯化磷氧化得到。
  • 下游产品:1,3-二氯异喹啉 --> 2,6-二氨基-4-氯吡啶 --> (6-甲氧基甲酰氨基-4-氯吡啶-2-基)氨基甲酸甲酯 --> 4-氯吡啶-2,6-二碳酰肼 --> 4-氯吡啶-2,6-二羧酸甲酯 --> 对联苯磺酰氯 --> 苯膦酸 --> 4-氯吡啶-2,6-二羧酸
  • 外观性质:无色至亮黄色液体, 有微弱的果香味。
  • MOL 文件:824-72-6.mol
  • Acros Organics:苯基二氯氧磷 Phenylphosphonic dichloride, 97%(824-72-6)
  • 检测方法:GC,NMR
  • 敏感性:Moisture Sensitive
  • 用途一:用于生产苯膦酸和苯膦酸二甲酯。该品与对苯二酚进行脱氯化氢缩合，生成阻燃性含磷聚合物以及用作聚酯的热稳定剂；在吡啶存在下与辛醇反应生成苯膦酸辛酯，可用作低挥发性增塑剂。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Phosphite Ligands
  1. Functional Group 官能团索引
  2. phosphonic acid derivative

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