CAS 589-87-7 MFCD00001051-1-Bromo-4-iodobenzene 对溴碘苯 -LabNovo

1-Bromo-4-iodobenzene 对溴碘苯

CAS 589-87-7 MFCD00001051

化学结构图

SMILES: Brc1ccc(I)cc1

化学属性

Mol. Formula	C6H4BrI
Mol. Weight	282.90
Boiling Point	244.8°C at 760 mmHg
Melting Point	89-91°C
TSCA	T
Density	2.215
Stability	对光敏感
Flash Point	120-122°C/14mm

别名和识别编码

Chemical Name	1-Bromo-4-iodobenzene
CAS Number	589-87-7
Alfabeta Name	BROMOIODOBENZENE 14---
MDL Number	MFCD00001051
Synonym	4-Bromoiodobenzene {LY} 4-Bromoiodobenzene {} {LY} 4-Bromoiodobenzene {} {} {LY} 4-Bromoiodobenzene {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Bromoiodobenzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number	209-662-7
Beilstein Registry Number	1904545
PubChem Substance ID	11522
Reaxys-RN	1904545
Chemical Name Translation	对溴碘苯
InChIKey	UCCUXODGPMAHRL-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00173889
InChI	InChI=1S/C6H4BrI/c7-5-1-3-6(8)4-2-5/h1-4H
Canonical SMILES	IC1=CC=C(Br)C=C1

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产品应用

含水丙酮中无铜 Sonogashira 偶联反应的底物。也可用于 β,β-二溴苯乙烯的合成。

安全信息

Warnings IRRITANT, LIGHT SENSITIVE, IRRITANT-HARMFUL

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37 Wear suitable gloves 戴适当手套；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P302+P350
P302+P352
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Light Sensitive Store at room temperature {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Codes Xi

其他信息

TCI Shanghai:1-溴-4-碘苯 1-Bromo-4-iodobenzene,>;98.0%(GC)(589-87-7)
Acros Organics:对溴碘苯 1-Bromo-4-iodobenzene, 98%(589-87-7)
用途一:用于有机合成
下游产品:
合成方法:以工业品对溴苯胺为原料,经重氮化、碘代合成了对溴碘苯。较佳的合成条件:先将0.02mol对溴苯胺溶解在质量分数为20%的硫酸介质中,与0.021molNaNO2在-10℃下反应生成对溴苯基重氮硫酸盐,然后在溶液中加入氯仿与0.021molKI进行碘代反应,经简单后处理得到对溴碘苯粗产品(其中对溴碘苯HPLC纯度为98.4%),提纯后总收率达80%,较改进前提高了15%。产物经IR和1HNMR进行了结构表征。改进后的方法大大提高了粗产品的纯度,避免了过柱子带来的麻烦,操作简便安全,过程易于控制,成本较低,更适于对溴碘苯的制备。单位：黑龙江大学化学化工与材料学院作者：郭敬白雪峰吕宏飞
TSCA:T
MOL 文件:589-87-7.mol
Sigma Aldrich:589-87-7(sigmaaldrich)
海关编码:29036990
图谱信息:对溴碘苯(589-87-7)红外图谱(IR1) 对溴碘苯(589-87-7)质谱(MS) 对溴碘苯(589-87-7)核磁图( 13 CNMR) 对溴碘苯(589-87-7)核磁图( 1 HNMR) 对溴碘苯(589-87-7)红外图谱(IR3) 对溴碘苯(589-87-7)红外图谱(IR2)
敏感性:Light Sensitive
对溴碘苯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010298 对溴碘苯 100g 650元 2011/04/16 B0604 1-溴-4-碘苯 1-Bromo-4-iodobenzene 25G 855元 2011/04/16 B0604 1-溴-4-碘苯 1-Bromo-4-iodobenzene 250G 5250元
Hazard Note:Harmful/Light Sensitive
MSDS 信息:p-Bromoiodobenzene(589-87-7).msds
Alfa Aesar:1-溴-4-碘苯,98% 1-Bromo-4-iodobenzene, 98%(589-87-7)