1-Iodopropane 1-碘丙烷

CAS 107-08-4 MFCD00001095

化学结构图

107-08-4
SMILES: CCCI

化学属性

Mol. FormulaC3H7I
Mol. Weight170
Refractive index1.5000 to 1.5110
Density1.74
Boiling Point101-102
Vapor Pressure43 mmHg ( 25 °C)
Melting Point-101
Flash Point44°C(lit.)
TSCAYes
Solubility微溶于水,可混溶于乙醇、乙醚。
Stability对光线、空气敏感

别名和识别编码

Chemical Name1-Iodopropane
MDL NumberMFCD00001095
CAS Number107-08-4
Synonym 1-Iodopropane 1-Iodopropane, stabilized, 99% 1-Iodpropan 1-iodo-propan 1-propyl iodide 1-碘丙烷 1-碘丙烷, 98+% C3H7I (1-iodo-propane) PROPYL IODIDE Propane,1-iodo- Propyl iodide n-PROPYL IODIDE extrapure n-Propyl iodide n-Propyljodid propyl iodide 丙基碘 正丙基碘 碘代丙烷 碘代正丙烷,碘代丙烷,丙基碘,正丙基碘
EC Number203-460-2
Beilstein Registry Number1,113
PubChem Substance ID87571472
Merck Number7862
Reaxys-RN505937
Chemical Name Translation1-碘丙烷
Wiswesser Line NotationI3
LabNetwork Molecule IDLN00010234
InChIInChI=1S/C3H7I/c1-2-3-4/h2-3H2,1H3
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 溶剂。有机合成。

相关文献及参考

  • Short: II/19c
  • Short: II/14a
  • Merck:14,7862 Beilstein:1,113
  • Merck:14,7862
  • Short: II/19b

安全信息

WGK Germany3
RTECSTZ4100000
GHS Symbol
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H332
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 2392 UN 2392 3/PG 3
Risk Statements
  • R10 Flammable 易燃
  • R20 Harmful by inhalation 吸入有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R52/53
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Storage condition Light Sensitive 对光敏感 Flammables area 充氩保存
Hazard Codes 3
Hazard Class3
Warnings 危化品目录(2015)
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3000 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   35,1411,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 595 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,103,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 73 gm/m3/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAVUAI Fiziologicheski Aktivnye Veshchestva.  Physiologically Active
   Substances.  (Izdatel'stvo Naukova Dumka, Kiev, USSR)  No.1-    1966-
   Volume(issue)/page/year: 7,35,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 297 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,103,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NIIRDN Drugs in Japan (Ethical Drugs).  (Yakugyo Jiho Co., Ltd., Tokyo,
   Japan)  Volume(issue)/page/year: -,1039,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 per

Restrict 危险品

其他信息

  • 海关编码:29033080
  • 毒性分级:中毒
  • 用途二:用作溶剂、分析化学试剂、有机合成原料。
  • 方法一:由正丙醇与三碘化磷反应而得。先将赤磷与正丙醇混合,在水浴上加热至80℃,再加入碘片,保持温度85-95℃,反应2h。经分馏得粗品,再经洗涤、干燥后分馏,收集102-103.5℃馏分即得1-碘丙烷。
  • Hazard Note:Irritant
  • 急性毒性:腹腔- 大鼠 LD50: 650 毫克/ 公斤; 口服- 小鼠 LD50:>;1800 毫克/ 公斤
  • 类别:有毒物品
  • 灭火剂:泡沫、雾状水、干粉、砂土
  • 蒸气压:43 mm Hg ( 25 °C)
  • 外观性质:无色至黄色液体。
  • TCI Shanghai:1-碘丙烷(含稳定剂铜屑) 1-Iodopropane (stabilized with Copper chip),>;98.0%(GC)(107-08-4)
  • 图谱信息:1-碘代丙烷(107-08-4)核磁图( 1 HNMR) 1-碘代丙烷(107-08-4)红外图谱(IR1) 1-碘代丙烷(107-08-4)核磁图( 13 CNMR) 1-碘代丙烷(107-08-4)质谱(MS)
  • MSDS 信息:丙基碘(107-08-4).msds
  • 能与乙醇;乙醚混溶,20℃时在100g水中能溶解0.11g。见光颜色变深。遇明火;高热,能燃烧,受高热放出有毒气体,能与氧化剂发生反应。
  • 可燃性危险特性:明火、高热可燃放出有毒碘化物气体; 与氧化剂反应
  • 用途一:用作溶剂,也用于有机合成
  • 敏感性:Light Sensitive
  • 1-碘代丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80111326 碘代正丙烷 100ml 195元 2011/04/16 I0068 1-碘丙烷(含稳定剂铜屑) 1-Iodopropane (stabilized with Copper chip) 25G 196元 2011/04/16 I0068 1-碘丙烷(含稳定剂铜屑) 1-Iodopropane (stabilized with Copper chip) 500G 1340元
  • Alfa Aesar:1-碘丙烷,98+%,stab.withcopper 1-Iodopropane, 98+%, stab. with copper(107-08-4)
  • Acros Organics:1-碘丙烷 1-Iodopropane, stabilized, 99%(107-08-4)
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • Sigma Aldrich:107-08-4(sigmaaldrich)
  • MOL 文件:107-08-4.mol
  • 下游产品:
  • 上游原料:碘
  • F:8

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