9-Fluorenone 9-芴酮

CAS 486-25-9 MFCD00001141

化学结构图

486-25-9
SMILES: O=C1c2ccccc2-c2ccccc21

化学属性

Mol. FormulaC13H8O
Mol. Weight180.20
Boiling Point341.5°C at 760 mmHg
Melting Point80-83°C
Density0.9
Flash Point163°(325°F)
TSCAYes
Solubility不溶
Appearance 黄色结晶。 易溶于乙醇和乙醚,不溶于水。

别名和识别编码

Chemical Name9-Fluorenone
MDL NumberMFCD00001141
PubChem Substance ID87569834
Beilstein Registry Number1636531
CAS Number486-25-9
EC Number207-630-7
Synonym Fluorenone {LY} Fluorenone {} {LY} Fluorenone {} {} {LY} Fluorenone {} {} {} {LY} Fluorenone {} {} {} {} {LY} Fluorenone {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {}
Reaxys-RN1636531
Alfabeta NameFLUORENONE H99---
Chemical Name Translation9-芴酮
Wiswesser Line NotationL B656 HVJ
LabNetwork Molecule IDLN00185200
InChIInChI=1S/C13H8O/c14-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)13/h1-8H
Canonical SMILESO=C(C1=C2C=CC=C1)C3=C2C=CC=C3
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; 13ring; ketone; 1fragment
  • {SNA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

产品应用

  • 是制多种精细化学品的原料,主要用于功能高分子方面,它还可用于医药、农药、染料。

相关文献及参考

  • Beilstein:7,465
  • Short: II/27B
  • Short: II/27C

安全信息

WGK Germany3
RTECSLL8925000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Warnings IRRITANT
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store a
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 300 mg/kg/26W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   7,453,1947

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCJOAU Pharmaceutical Chemistry Journal (English Translation).  Translation
   of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013)  No.1-
   1967-  Volume(issue)/page/year: 23,325,1989

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

其他信息

  • 海关编码:29143900
  • Sigma Aldrich:486-25-9(sigmaaldrich)
  • 有机合成中间体:9-芴酮是一种重要的有机合成中间体,可用于制造多种精细化学品,主要应用于合成高分子材料、双酚芴、芴基苯并恶嗪树脂、丙烯酸酯树脂、聚酯、聚碳酸酯及环氧树脂的改性剂。实验室中以芴为原料、二甲基亚砜为溶剂、氢氧化钠作催化剂、氧为氧化剂,采用塔式填料反应器进行氧化反应,反应液经冷却、过滤可得到含量为93%的粗芴酮,滤液经蒸馏可回收94%的溶剂及部分粗芴酮。粗芴酮再经定向结晶法精制可得到纯度为99.8%以上的黄色片状芴酮。
  • 9-芴酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30089781 芴酮 kg 2616元 2011/04/16 F0021 9-芴酮 9-Fluorenone 25G 250元 2011/04/16 F0021 9-芴酮 9-Fluorenone 500G 1880元
  • 不溶于水。
  • Hazard Note:Irritant
  • 图谱信息:9-芴酮(486-25-9)核磁图( 13 CNMR) 9-芴酮(486-25-9)红外图谱(IR2) 9-芴酮(486-25-9)红外图谱(IR1) 9-芴酮(486-25-9)质谱(MS)
  • 用途二:是制多种精细化学品的原料,主要用于功能高分子方面,它还可用于医药、农药、染料。
  • 下游产品:9-溴-9-苯基芴
  • 用途一:用作有机合成中间体
  • MSDS 信息:9-Fluorenone(486-25-9).msds
  • MOL 文件:486-25-9.mol
  • 检测方法:GC,NMR
  • Acros Organics:9-芴酮 9-Fluorenone, 99+%(486-25-9)
  • TCI Shanghai:9-芴酮 9-Fluorenone,>;98.0%(GC)(486-25-9)
  • Alfa Aesar:9-芴酮,98+% 9-Fluorenone, 98+%(486-25-9)

系列性分类


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