9-Fluorenone 9-芴酮

CAS 486-25-9 MFCD00001141

化学结构图

486-25-9
SMILES: O=C1c2ccccc2-c2ccccc21

化学属性

Mol. FormulaC13H8O
Mol. Weight180.20
Boiling Point341.5°C at 760 mmHg
Melting Point80-83°C
Density0.9
Flash Point163°(325°F)
TSCAYes
Solubility不溶
Appearance 黄色结晶。 易溶于乙醇和乙醚，不溶于水。

别名和识别编码

Chemical Name9-Fluorenone
MDL NumberMFCD00001141
PubChem Substance ID87569834
Beilstein Registry Number1636531
CAS Number486-25-9
EC Number207-630-7
Synonym Fluorenone {LY} Fluorenone {} {LY} Fluorenone {} {} {LY} Fluorenone {} {} {} {LY} Fluorenone {} {} {} {} {LY} Fluorenone {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Fluorenone {} {} {} {} {} {} {} {} {} {} {} {} {}
Reaxys-RN1636531
Alfabeta NameFLUORENONE H99---
Chemical Name Translation9-芴酮
Wiswesser Line NotationL B656 HVJ
LabNetwork Molecule IDLN00185200
InChIInChI=1S/C13H8O/c14-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)13/h1-8H
Canonical SMILESO=C(C1=C2C=CC=C1)C3=C2C=CC=C3
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; 13ring; ketone; 1fragment
  • {SNA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

产品应用

  • 是制多种精细化学品的原料，主要用于功能高分子方面，它还可用于医药、农药、染料。

相关文献及参考

  • Beilstein:7,465
  • Short: II/27B
  • Short: II/27C

安全信息

WGK Germany3
RTECSLL8925000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Warnings IRRITANT
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} { {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 300 mg/kg/26W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   7,453,1947

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCJOAU Pharmaceutical Chemistry Journal (English Translation).  Translation
   of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013)  No.1-
   1967-  Volume(issue)/page/year: 23,325,1989

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

其他信息

  • 海关编码:29143900
  • Sigma Aldrich:486-25-9(sigmaaldrich)
  • 有机合成中间体:9-芴酮是一种重要的有机合成中间体，可用于制造多种精细化学品，主要应用于合成高分子材料、双酚芴、芴基苯并恶嗪树脂、丙烯酸酯树脂、聚酯、聚碳酸酯及环氧树脂的改性剂。实验室中以芴为原料、二甲基亚砜为溶剂、氢氧化钠作催化剂、氧为氧化剂，采用塔式填料反应器进行氧化反应，反应液经冷却、过滤可得到含量为93%的粗芴酮，滤液经蒸馏可回收94%的溶剂及部分粗芴酮。粗芴酮再经定向结晶法精制可得到纯度为99.8%以上的黄色片状芴酮。
  • 9-芴酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30089781 芴酮 kg 2616元 2011/04/16 F0021 9-芴酮 9-Fluorenone 25G 250元 2011/04/16 F0021 9-芴酮 9-Fluorenone 500G 1880元
  • 不溶于水。
  • Hazard Note:Irritant
  • 图谱信息:9-芴酮(486-25-9)核磁图( 13 CNMR) 9-芴酮(486-25-9)红外图谱(IR2) 9-芴酮(486-25-9)红外图谱(IR1) 9-芴酮(486-25-9)质谱(MS)
  • 用途二:是制多种精细化学品的原料，主要用于功能高分子方面，它还可用于医药、农药、染料。
  • 下游产品:9-溴-9-苯基芴
  • 用途一:用作有机合成中间体
  • MSDS 信息:9-Fluorenone(486-25-9).msds
  • MOL 文件:486-25-9.mol
  • 检测方法:GC,NMR
  • Acros Organics:9-芴酮 9-Fluorenone, 99+%(486-25-9)
  • TCI Shanghai:9-芴酮 9-Fluorenone,>;98.0%(GC)(486-25-9)
  • Alfa Aesar:9-芴酮,98+% 9-Fluorenone, 98+%(486-25-9)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C13 to C14 - Ketones
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. S - Alphabetic
  5. SN - SZ - S
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Fluorenes & Fluorenones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C11 to C12
  1. Materials Science 材料科学
  2. Photopolymerization Initiators
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Enzymes, Inhibitors, and Substrates
  4. Metabolomics
  5. Metabolic Pathways
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Metabolomics
  4. Metabolic Pathways
  5. Electron Transport and Cellular Respiration

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