Methylphenyl sulphoxide 甲基苯基亚砜

CAS 1193-82-4 MFCD00002088

化学结构图

1193-82-4
SMILES: CS(=O)c1ccccc1

化学属性

Mol. FormulaC7H8OS
Mol. Weight140.20
Refractive indexn20/D 1.5775(lit.)
Boiling Point271.2°C at 760 mmHg
Melting Point26-29 °C
Flash Point86°(186°F)
TSCANo

别名和识别编码

Chemical NameMethylphenyl sulphoxide
CAS Number1193-82-4
PubChem Substance ID14516
EC Number214-781-2
Beilstein Registry Number1904976
MDL NumberMFCD00002088
Reaxys-RN1904976
Synonym (Methylsulfinyl)benzene {LY} (Methylsulfinyl)benzene methyl phenyl sulfoxide {} {LY} (Methylsulfinyl)benzene {} {} {LY} (Methylsulfinyl)benzene {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Methylsulfinyl)benzene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation甲基苯基亚砜
InChIKeyJXTGICXCHWMCPM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00244403
InChIInChI=1S/C7H8OS/c1-9(8)7-5-3-2-4-6-7/h2-6H,1H3
Canonical SMILESO=S(C1=CC=CC=C1)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfoxides, Sulfur Compounds

相关文献及参考

  • Addition of the lithio-derivative to ketones followed by treatment with KO-t-Bu leads to allylic alcohols by sigmatropic rearrangement of the intermediate allyl sulfoxide: Synthesis, 640 (1980):
  • Beil. 6 ,IV,1467
  • For the fluoro-Pummerer rearrangement to fluoromethyl phenyl sulfide, see: Diethyl­aminosulfur trifluoride, A11992.

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {}
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
Risk Statements

其他信息

  • Acros Organics:甲基苯基亚砜 Methyl phenyl sulfoxide, 98%(1193-82-4)
  • 甲基苯基亚砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1148 甲基苯基亚砜 Methyl Phenyl Sulfoxide 5G 429元 2014/06/02 M1148 甲基苯基亚砜 Methyl Phenyl Sulfoxide 25G 1160元 2010/06/21 352120250 甲基苯基亚砜 Methyl phenyl sulfoxide 98% 25 GR 1413元
  • MOL 文件:1193-82-4.mol
  • TCI Shanghai:甲基苯基亚砜 Methyl Phenyl Sulfoxide,>;98.0%(GC)(1193-82-4)
  • 敏感性:Hygroscopic
  • 图谱信息:甲基苯基亚砜(1193-82-4)质谱(MS) 甲基苯基亚砜(1193-82-4)红外图谱(IR1)
  • Sigma Aldrich:1193-82-4(sigmaaldrich)
  • Alfa Aesar:苯亚砜甲酯,98+% Methyl phenyl sulfoxide, 98+%(1193-82-4)

系列性分类


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