4-Biphenylcarboxylic Acid 4-苯基苯甲酸

CAS 92-92-2 MFCD00002553

化学结构图

92-92-2
SMILES: O=C(O)c1ccc(-c2ccccc2)cc1

化学属性

Mol. FormulaC13H10O2
Mol. Weight198.2173
Density1.284
Melting Point220-225°C
TSCAYes
Appearance 无色针状结晶。熔点228℃。易溶于醇和醚，不溶于水。
Boiling Point372.6°C at 760 mmHg

别名和识别编码

Chemical Name4-Biphenylcarboxylic Acid
MDL NumberMFCD00002553
CAS Number92-92-2
EC Number202-203-1
Beilstein Registry Number973519
Synonym [1,1'-Biphenyl]-4-carboxylic acid {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-4-carboxylic acid
PubChem Substance ID87575076
Chemical Name Translation4-苯基苯甲酸
Reaxys-RN973519
InChIKeyNNJMFJSKMRYHSR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00202936
Canonical SMILESO=C(C1=CC=C(C2=CC=CC=C2)C=C1)O
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分类

  • {SNA} B, Bioactive Small Molecules, Building Blocks, C13 to C42+, Carbonyl Compounds, Carboxylic Acids, Cell Biology, Chemical Synthesis, Organic Building Blocks
  • {SNA} B, Bioactive Small Molecules, Building Blocks, C13 to C42+, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks,
  • {SNA} Building Blocks, C13 to C42+, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
  • {SNA} B, Building Blocks, C13 to C42+, Carbonyl Compounds,

产品应用

  • 该品为极谱分析试剂，也是有机合成的中间体。

相关文献及参考

  • Beilstein:9,671

安全信息

Signal word Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R51 Toxic to aquatic organisms 对水生生物有毒
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
RTECSDV1925100
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xn Xi
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1 gm/kg
SEX/DURATION            : female 7-16 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
   Reproductive - Specific Developmental Abnormalities - body wall
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 39,537,1989

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Alfa Aesar:4-联苯基羧酸,98% Biphenyl-4-carboxylic acid, 98%(92-92-2)
  • 海关编码:29163900
  • 方法一:由联苯与氯乙酰反应后用高锰酸钾氧化而得。将联苯溶解在苯中，搅拌下缓缓加入无水三氯化铝，在微沸情况下滴加氯乙酰。加毕，继续保温搅拌2h。回收苯至尽，趁热将反应物倒入冰水中结晶。取结晶与高锰酸钾于90℃以下反应，过滤，用盐酸中和至pH为2，得粗品。再经乙醇重结晶、酸碱沉淀精制得到4-苯基苯甲酸。
  • 易溶于醇和醚，不溶于水。
  • MOL 文件:92-92-2.mol
  • 上游原料:三氯化铝 --> 高锰酸钾 --> 联苯
  • MSDS 信息:4-Biphenylcarboxylic acid(92-92-2).msds
  • Hazard Note:Irritant
  • 用途一:用于有机合成
  • 下游产品:2-(4'-叔丁苯基)-5-(4'-联苯基)-1,3,4-恶二唑 --> 4-氨基联苯酚酯 --> 4-苄氨基-7-硝基苯并-2-氧杂-1,3-二唑 --> 2-(4-联苯基)-5-苯基恶二唑 --> 联苯-4-甲酰氯 --> 还原黄 33
  • TCI Shanghai:4-苯基苯甲酸 4-Phenylbenzoic Acid,>;95.0%(GC)(92-92-2)
  • 4-苯基苯甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0961 4-苯基苯甲酸 4-Phenylbenzoic Acid 25G 344元 2014/06/02 P0961 4-苯基苯甲酸 4-Phenylbenzoic Acid 500G 3600元 2010/06/21 106285000 4-苯基苯甲酸 4-Biphenylcarboxylic acid 99% 500 GR 3766元
  • Acros Organics:4-联苯基甲酸 4-Biphenylcarboxylic acid, 99%(92-92-2)
  • 检测方法:HPLC,NMR
  • 图谱信息:4-苯基苯甲酸(92-92-2)质谱(MS) 4-苯基苯甲酸(92-92-2)核磁图( 1 HNMR) 4-苯基苯甲酸(92-92-2)红外图谱(IR2) 4-苯基苯甲酸(92-92-2)红外图谱(IR1)
  • 用途二:该品为极谱分析试剂，也是有机合成的中间体。
  • Sigma Aldrich:92-92-2(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acids - Carbonyl Compounds
  6. C13 to C42+ - Carboxylic Acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic acids

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