CAS 6232-88-8 MFCD00002567-4-Bromomethylbenzoic Acid 对溴甲基苯甲酸 -LabNovo

4-Bromomethylbenzoic Acid 对溴甲基苯甲酸

CAS 6232-88-8 MFCD00002567

化学结构图

SMILES: O=C(O)c1ccc(CBr)cc1

化学属性

Mol. Formula	C8H7BrO2
Mol. Weight	215.04
Melting Point	224-229 °C
Density	1.422
TSCA	Yes
Appearance	白灰片状结晶。
Boiling Point	252.95 °C at 760 mmHg

别名和识别编码

Chemical Name	4-Bromomethylbenzoic Acid
CAS Number	6232-88-8
Alfabeta Name	CARBOXYBENZYLBROMIDE 4-
MDL Number	MFCD00002567
Synonym	4-(Bromomethyl)benzoic acid {LY} 4-(Bromomethyl)benzoic acid {} {LY} 4-(Bromomethyl)benzoic acid {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-(Bromomethyl)benzoic acid {} {} {} {} {} {} {} {
Beilstein Registry Number	1862870
PubChem Substance ID	87563827
EC Number	228-343-3
Reaxys-RN	1862870
Chemical Name Translation	对溴甲基苯甲酸
InChIKey	CQQSQBRPAJSTFB-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00008697
Canonical SMILES	BrCC1=CC=C(C(O)=O)C=C1

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

安全信息

Warnings LACHRYMATOR, CORROSIVE

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

WGK Germany3

GHS Symbol

Signal word Warning

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤

Hazard Codes Xi Xi,C

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

UN Number 3261 UN3261

Packing GroupIII

Hazard Class8

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

方法一:将异丙基甲苯经氧化、溴化而得。1.异丙基甲苯氧化将硝酸和对异丙基甲苯加入反应锅中，慢慢升温，至80-90℃反应4h，90-95℃反应6h。冷却，上层酸水可以套用。下层固体物用水洗后，过滤。滤饼加甲苯，加热回流半小时。趁热过滤。滤液冷至室温以下。将结晶滤出，在100℃以下干燥，得对甲基苯甲酸，熔点180-181℃。收率50%以上。对甲基苯甲酸也可以由对二甲苯氧化而得。在环烷酸钴存在下，二甲苯用空气氧化，在110-115℃反应20h，冷至室温，过滤，滤饼用二甲苯洗涤，干燥即得。此法收率40%。2.溴化将对甲基苯甲酸加入反应锅与氯苯溶解，加入溴素慢慢加热回流。反应结束时，冷至70℃，排尽溴化氢，继续冷至室温以下，过滤，滤饼用氯苯洗涤，干燥，得对溴甲基苯甲酸。收率75%以上。用途：医药中间体。 #EndEditable "Content"
Alfa Aesar:4-(溴甲基)苯甲酸,97% 4-(Bromomethyl)benzoic acid, 97%(6232-88-8)
对溴甲基苯甲酸价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 B0845 4-(溴甲基)苯甲酸 4-(Bromomethyl)benzoic Acid 5G 339元 2014/06/02 B0845 4-(溴甲基)苯甲酸 4-(Bromomethyl)benzoic Acid 25G 989元 2010/06/21 170400500 对溴甲基苯甲酸 alpha-Bromo-p-toluic acid 97% 50 GR 3699元
Sigma Aldrich:6232-88-8(sigmaaldrich)
海关编码:29163900
Acros Organics:alpha-溴对甲苯酸 alpha-Bromo-p-toluic acid, 97%(6232-88-8)
下游产品:唑螨酯 --> 4-氨甲基苯甲酸 --> 4-溴甲基苯甲酰氯
Hazard Note:Irritant
MOL 文件:6232-88-8.mol
用途一:用作有机合成原料和医药中间体等
F:19-21
用途二:医药中间体。 #EndEditable "Content"
MSDS 信息:4-Bromomethylbenzoic acid(6232-88-8).msds
上游原料:对二甲苯 --> 对甲基苯甲酸 --> 环烷酸钴 --> 4-异丙基甲苯
TCI Shanghai:4-溴甲基苯甲酸 4-(Bromomethyl)benzoic Acid,>;95.0%(GC)(T)(6232-88-8)