Triphenylsilane 三苯基硅烷

CAS 789-25-3 MFCD00003003

化学结构图

789-25-3
SMILES: c1ccc([SiH](c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC18H16Si
Mol. Weight260.41
Density1.422
Flash Point76.1°C
TSCAYes
Boiling Point152°C at 760 mmHg
Melting Point43-45 °C
Solubility起反应
Appearance 白色结晶粉末，熔点 43-46℃，沸点 152℃，闪点 76℃，与水起反应

别名和识别编码

Chemical NameTriphenylsilane
Synonym Triphenylsilane {LY} Triphenylsilane {} {LY} Triphenylsilane {} {} {LY} Triphenylsilane {} {} {} {LY} Triphenylsilane {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylsilane {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00003003
CAS Number789-25-3
EC Number212-333-0
Beilstein Registry Number978182
PubChem Substance ID6327682
Chemical Name Translation三苯基硅烷
Reaxys-RN978182
InChIKeyAKQNYQDSIDKVJZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00197731
Canonical SMILESC1=CC=C(C=C1)[SiH](C2=CC=CC=C2)C3=CC=CC=C3
InChIInChI=1S/C18H15Si/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
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分类

  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others, Reduction, Silanes, Synthetic Reagents
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Other Organosilicon, Reduction, Silanes, Synthetic Reagents
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive

安全信息

Signal word Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P317
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition 2-8°C {LY} 2-8°C Air Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi

其他信息

  • Sigma Aldrich:789-25-3(sigmaaldrich)
  • Acros Organics:Triphenylsilane, 99+%(789-25-3)
  • 三苯基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0661 三苯硅烷 Triphenylsilane 25G 733元 2010/06/21 164820250 三苯基硅烷 Triphenylsilane 99+% 25 GR 1025元 2010/05/25 A11605 三苯基硅烷, 99% Triphenylsilane, 99% 50g 998元
  • 海关编码:29310095
  • MOL 文件:789-25-3.mol
  • MSDS 信息:Triphenylsilane(789-25-3).msds
  • 敏感性:Air Sensitive
  • 图谱信息:三苯基硅烷(789-25-3)质谱(MS) 三苯基硅烷(789-25-3)核磁图( 1 HNMR) 三苯基硅烷(789-25-3)红外图谱(IR1) 三苯基硅烷(789-25-3)核磁图( 13 CNMR) 三苯基硅烷(789-25-3)红外图谱(IR2)
  • TCI Shanghai:三苯硅烷 Triphenylsilane,>;96.0%(GC)(789-25-3)
  • 检测方法:GC,NMR
  • Alfa Aesar:三苯基硅烷,99% Triphenylsilane, 99%(789-25-3)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Others - Organosilicon
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Silanes - Reduction
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  4. Silanes 硅烷
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物