Triphenylamine 三苯胺

CAS 603-34-9 MFCD00003020

化学结构图

603-34-9
SMILES: C1CCC(N(C2CCCCC2)C2CCCCC2)CC1

化学属性

Mol. FormulaC18H15N
Mol. Weight245.33
Density1.112
Melting Point124-128°C
TSCAYes
Boiling Point365°C at 760 mmHg
Solubility不溶
Flash Point365°C

别名和识别编码

Chemical NameTriphenylamine
Synonym Triphenylamine {LY} Triphenylamine {} {LY} Triphenylamine {} {} {LY} Triphenylamine {} {} {} {LY} Triphenylamine {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number603-34-9
EC Number210-035-5
Beilstein Registry Number2050487
MDL NumberMFCD00003020
PubChem Substance ID11775
Reaxys-RN2050487
Chemical Name Translation三苯胺
Wiswesser Line NotationRNR&R
LabNetwork Molecule IDLN00190757
InChIInChI=1S/C18H15N/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
Canonical SMILESN(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
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分类

  • {SNA} Amines, Building Blocks, C15 to C19, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 用于新型电致发光材料、特种染料和医药的合成。

相关文献及参考

  • Short: II/3
  • Short: III/5b
  • Beilstein:12(3)292
  • Short: IV/18B
  • Short: IV/16

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
RTECSYK2680000
Hazard statements
  • H303 May be harmfully swallowed 吞食可能有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 6,1658,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conf

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >6400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 6,1658,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 6,1658,1991

{hazard_

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 毒性分级:中毒
  • 用途二:用于新型电致发光材料、特种染料和医药的合成。
  • MOL 文件:603-34-9.mol
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • 爆炸物危险特性:粉尘与空气混合有火源可爆炸
  • Hazard Note:Irritant
  • 不溶于水。
  • Alfa Aesar:三苯基胺,98% Triphenylamine, 98%(603-34-9)
  • 类别:有毒物质
  • 急性毒性:口服- 大鼠 LD50: 3200 毫克/ 公斤; 口服- 小鼠 LD50: 1600 毫克/ 公斤
  • 海关编码:29214980
  • TCI Shanghai:三苯胺 Triphenylamine,>;98.0%(GC)(603-34-9)
  • Acros Organics:三苯胺 Triphenylamine, 99+%(603-34-9)
  • 检测方法:HPLC
  • 可燃性危险特性:可燃; 火场分解有毒氮氧化物气体
  • 用途一:用于有机合成
  • 下游产品:
  • 储运特性:库房低温, 通风, 干燥
  • 图谱信息:三苯胺(603-34-9)红外图谱(IR1) 三苯胺(603-34-9)质谱(MS) 三苯胺(603-34-9)红外图谱(IR2) 三苯胺(603-34-9)核磁图( 1 HNMR) 三苯胺(603-34-9)红外图谱(IR3) 三苯胺(603-34-9)核磁图( 13 CNMR)
  • Sigma Aldrich:603-34-9(sigmaaldrich)
  • 职业标准:TWA 5 毫克/立方米; STEL 10 毫克/立方米
  • 三苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0507 三苯胺 Triphenylamine 25G 527元 2014/06/02 T0507 三苯胺 Triphenylamine 250G 2730元 2010/06/21 140311000 三苯胺 Triphenylamine 99+% 100 GR 1543元
  • MSDS 信息:N,N-diphenylbenzenamine(603-34-9).msds

系列性分类

  1. C14 to C16 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  1. Functional Group 官能团索引
  2. tertiary aromatic amine (triarylamine)

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