4-Amino-3-Hydrazino-5-Mercapto-1,2,4-Triazole 4-氨基-3-肼基-5-巯基-1,2,4-三唑

CAS 1750-12-5 MFCD00003098

化学结构图

1750-12-5
SMILES: NNc1n[nH]c(=S)n1N

化学属性

Mol. FormulaC2H6N6S
Mol. Weight146.17
Density2.31
Melting Point228-230°C
TSCAYes
Appearance 白色粉末,熔点 230-231℃
Boiling Point275.0±23.0°C at 760 mmHg

别名和识别编码

Chemical Name4-Amino-3-Hydrazino-5-Mercapto-1,2,4-Triazole
CAS Number1750-12-5
Alfabeta NameAMINOHYDRAZINOTRIAZOLETHIOL H4541243--------,,
MDL NumberMFCD00003098
Synonym AHMT {LY} AHMT {} {LY} AHMT {} {} {LY} AHMT {} {} {} {LY} AHMT {} {} {} {} {LY} AHMT {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} AHMT {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number217-135-8
Beilstein Registry Number134867
PubChem Substance ID2723946
Reaxys-RN610670
Chemical Name Translation4-氨基-3-肼基-5-巯基-1,2,4-三唑
InChIKeyRDIMQHBOTMWMJA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00165181
InChIInChI=1S/C2H6N6S/c3-5-1-6-7-2(9)8(1)4/h3-4H2,(H,5,6)(H,7,9)
Canonical SMILESS=C(N/1N)NNC1=N\N
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分类

  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 5ring; 1fragment
  • Heterocycles
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Triazoles
  • Aldehyde Labeling Reagents
  • Sulfur & Selenium Compounds

产品应用

  • 测定甲醛和其它反应性化学品的专一试剂。HPLC中衍生中性单糖。

相关文献及参考

  • Del Nozal, M.J. et al.: J. Liq. Chromatography, 16, 1105 (1993),
  • Reagent for the detection and classification of aldehydes: Chem. Commun., 1719 (1970); J. Chem. Educ., 55, 206 (1978). The reagent gives no color reaction with ketones.
  • Dickinson, R.G. and Jacobsen,N.W. : Chem. Commun., 1719, (1970),
  • Beilstein:26,217
  • Short: EINECS
  • Short: III/10a

安全信息

Warnings IRRITANT
Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
Packing GroupIII
UN Number UN1325 1325
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H228 Flammable solid 易燃固体
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Hazard Class4.1
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • MSDS 信息:Purpald(1750-12-5).msds
  • Alfa Aesar:4-氨基-3-肼基-5-巯基-1,2,4-三唑,99+% 4-Amino-3-hydrazino-5-mercapto-1,2,4-triazole, 99+%(1750-12-5)
  • TCI Shanghai:4-氨基-3-肼基-5-巯基-1,2,4-三唑[用于醛的测定] 4-Amino-3-hydrazino-5-mercapto-1,2,4-triazole [for Determination of Aldehydes],>;95.0%(T)(1750-12-5)
  • 用途一:测定甲醛和其它反应性化学品的专一试剂。HPLC中衍生中性单糖。
  • Sigma Aldrich:1750-12-5(sigmaaldrich)
  • MOL 文件:1750-12-5.mol
  • 4-氨基-3-肼基-5-巯基-1,2,4-三氮唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw020001 4-氨基-3-肼基-5-巯基-1,2,4-三氮唑 AMHT(2-8℃) 5g 120元 2011/08/23 K0809501 4-氨基-3-联氨-5-巯基-1.2.4-三唑 10g 730元 2011/04/16 A0956 4-氨基-3-肼基-5-巯基-1,2,4-三唑[用于醛的测定] 4-Amino-3-hydrazino-5-mercapto-1,2,4-triazole [for Determination of Aldehydes] 5G 437元
  • 上游原料:氧氯化硫 --> 碘甲烷 --> 哌嗪 --> 3-羟甲基哌啶 --> 1-甲基哌啶-3-甲醇
  • 图谱信息:4-氨基-3-肼基-5-巯基-1,2,4-三氮唑(1750-12-5)红外图谱(IR2) 4-氨基-3-肼基-5-巯基-1,2,4-三氮唑(1750-12-5)红外图谱(IR1) 4-氨基-3-肼基-5-巯基-1,2,4-三氮唑(1750-12-5)核磁图( 13 CNMR) 4-氨基-3-肼基-5-巯基-1,2,4-三氮唑(1750-12-5)质谱(MS)

系列性分类