Formanilide 甲酰苯胺

CAS 103-70-8 MFCD00003276

化学结构图

103-70-8
SMILES: O=CNC1CCCCC1

化学属性

Mol. FormulaC7H7NO
Mol. Weight121.14
Density1.144 g/mL at 25 °C(lit.)
Boiling Point166°C at 14 mmHg
Melting Point46-48°C
Flash Point>110°(230°F)
TSCAYes
Refractive index1.578

别名和识别编码

Chemical NameFormanilide
MDL NumberMFCD00003276
CAS Number103-70-8
Synonym N-Phenylformamide {LY} N-Phenylformamide {} {LY} N-Phenylformamide {} {} {LY} N-Phenylformamide {} {} {} {LY} N-Phenylformamide {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-Phenylformamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87569853
Beilstein Registry Number12,230
EC Number203-136-0
Merck Number4238
Chemical Name Translation甲酰苯胺
Reaxys-RN906934
Wiswesser Line NotationVHMR
LabNetwork Molecule IDLN01105078
InChIInChI=1S/C7H7NO/c9-6-8-7-4-2-1-3-5-7/h1-6H,(H,8,9)
Canonical SMILESO=CNC1=CC=CC=C1
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分类

  • {SNA} Amides, Building Blocks, C2 to C7, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 用于有机合成。

相关文献及参考

  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixt

安全信息

WGK Germany2
RTECSBY1780000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen 0-10 0-10°C Store at room temperature {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored u
Signal word
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
GHS Symbol
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   XPHBAO U.S. Public Health Service, Public Health Bulletin.  (Washington, DC)
    Volume(issue)/page/year: 271,19,1941

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Amphibian - frog
DOSE/DURATION           : 800 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   XPHBAO U.S. Public Health Service, Public Health Bulletin.  (Washington, DC)
    Volume(issue)/page/year: 271,19,1941

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   XPHBAO U.S. Public Health Service, Public Health Bulletin.  (Washington, DC)
    Volume(issue)/page/year: 271,19,1941

其他信息

  • Acros Organics:N-苯基甲酰胺 Formanilide, 99+%(103-70-8)
  • 方法一:由苯胺与甲酸反应而得。将2.8kg苯胺,2kg甲苯,3L甲酸加入装有分馏柱的烧瓶中,加热脱水半小时,反应后蒸馏回收甲苯至110℃。冷却,滤出结晶,减压蒸馏得甲酰苯胺。
  • Alfa Aesar:正甲酰苯胺,98% Formanilide, 98%(103-70-8)
  • 外观性质:单斜棱柱结晶。20℃时水中溶解度为25.4g、L,25℃时为28.6g/L,易溶于乙醇,溶于乙醚。熔点:46-48 °C沸点:166 °C/14 mmHg密度:1.144闪点:113 °C
  • F:8
  • 下游产品:对三氟甲基苯胺 --> 对氨基二苯胺 --> N-甲基甲酰苯胺 --> 酞菁助剂 BSK --> 酞菁素助剂 BSM
  • 图谱信息:N-苯基甲酰胺 (103-70-8)核磁图( 13 CNMR) N-苯基甲酰胺 (103-70-8)质谱(MS) N-苯基甲酰胺 (103-70-8)红外图谱(IR1) N-苯基甲酰胺 (103-70-8)红外图谱(IR2) N-苯基甲酰胺 (103-70-8)红外图谱(IR3)
  • TCI Shanghai:N-甲酰苯胺 Formanilide,>;99.0%(GC)(103-70-8)
  • 20℃时水中溶解度为25.4g、L,25℃时为28.6g/L,易溶于乙醇,溶于乙醚。
  • Sigma Aldrich:103-70-8(sigmaaldrich)
  • MOL 文件:103-70-8.mol
  • 用途一:用于有机合成。

系列性分类