Hexacarbonylmolybdenum 六羰基钼

CAS 13939-06-5 MFCD00003466

化学结构图

13939-06-5
SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mo]

化学属性

Mol. FormulaMo(CO)6
Mol. Weight264.00
Boiling Point156
Density1.960
Melting Point150
TSCAYes
Vapor Density9.1 (vs air)
Solubility不溶
Appearance white xtl.
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameHexacarbonylmolybdenum
Synonym Mo(CO)6 Hexacarbonylmolybdenum(0) 六羰基钼 羰化鉬 MOLYBDENUM HEXACARBONYL, SUBLIMED, 99.9& NSC 215198 Molybdenum carbonyl (Mo2(CO)12) Molybdäncarbonyl Molybdenumhexacarbonyl MOLYBDENUM ( Molybdenumcarbonyl(Mo(CO)6) Molybdänhexacarbonyl Hexacarbonylmolybdenum Molybdenum hexacarbonyl (Mo(CO)6) Molybdaenhexacarbonyl Molybdenumcarbonyl,98% MOLYBDENUM HEXACARBONYL Molybdaencarbonyl (OC-6-11)-Molybdenumcarbonyl Molybdenumhexacarbonyl(Mo(CO)6) Molybdenum hexacarbonyl MOLYBDENUM CARBONYL Molybdenum carbonyl (Mo(CO)6), (OC-6-11)- Molybdenumcarbonyl(Mo(CO)6),(OC-6-11)-
CAS Number13939-06-5
PubChem Substance ID329766468
EC Number237-713-3
MDL NumberMFCD00003466
Chemical Name Translation六羰基钼
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分类

  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Molybdenum, Vapor Deposition Precursors
  • {uni_hamburg} n
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Molybdenum
  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis,

相关文献及参考

  • Short: III/35D5
  • Short: II/25D
  • Catalyst and reagent in a variety of applications. Alternative to Octacarbonyl­dicobalt, 13060 for the Pauson-Khand [2 + 2 + 1] cycloaddition of an alkyne, an alkene and carbon monoxide to form a cyclopentenone: Tetrahedron Lett., 34, 4027 (1993); Org. Lett., 7, 431 (2005). For a brief survey of uses in synthesis, see: Synlett, 1195 (2005).
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安全信息

GHS Symbol
WGK Germany3
Hazard Codes T+ T+,Xi
Hazard statements
  • H300+H310+H330
  • H330 Fatal if inhaled 吸入致命
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P301+P310
Signal word
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
UN Number 3466
Risk Statements
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
Packing GroupII
Hazard Class6.1
Restrict -

其他信息

  • Sigma Aldrich:13939-06-5(sigmaaldrich)

系列性分类