Sodium periodate 高碘酸钠

CAS 7790-28-5 MFCD00003534

化学结构图

7790-28-5
SMILES: [Na+].[O-][I+3]([O-])([O-])[O-]

化学属性

Mol. FormulaNaIO4
Mol. Weight214
Melting Point300
Density3.66
SolubilitySoluble in water (144 mg/ml at 25 °C), sulfuric, nitric, and acetic acids
TSCAYes
Stability对光敏感
Boiling Point300°C
RedoxReduction

别名和识别编码

Chemical NameSodium periodate
Synonym IONAM Natrium-meta-periodat Natriummetaperjodat Natriumperiodat Natriumtetroxoiodat(VII) Periodicacid,sodiumsalt SODIUM (META)PERIODATE, ACS SODIUM M-PERIODATE ACS REAGENT SODIUM META PERIODTAE ( SODIUM PERIODATE ) SODIUM METAPERIODATE SODIUM PERIODATE, 10 WT. % ON SILICA GEL SODIUM TETRAOXOIODATE (VII) Sodium (meta)periodate Sodium Periodate meta Sodium metaperiodate Sodium periodate SodiumMetaperiodateGr metaperiodate sodiummetaperidate sodiummetaperiodate(sodiumperiodate) 偏过碘酸钠 高碘酸钠
CAS Number7790-28-5
PubChem Substance ID23667635
EC Number232-197-6
MDL NumberMFCD00003534
Merck Number14,8640
Beilstein Registry Number2384789
Chemical Name Translation高碘酸钠
Wiswesser Line NotationNA I-O3-Q
LabNetwork Molecule IDLN00193181
InChIInChI=1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
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分类

  • {Chemicalbook} 无机化工产品: 无机盐: Ci碘
  • {SNA} Chemical Synthesis, Core Bioreagents, Detection of Biotin Labeled Glycoproteins on Western Blots, Essential Chemicals, Glycoprotein Detection, Hypervalent Iodine, Life Science Reagents for Immunohistochemistry (IHC), Oxidizing Agents, Research Essentials, Salts,
  • {SNA} Chemical Synthesis, Detection of Biotin Labeled Glycoproteins on Western Blots, Essential Chemicals, Glycoprotein Detection, Hypervalent Iodine, Oxidizing Agents, Research Essentials, Salts, Sodium Salts, Synthetic Reagents, 分子生物学, 糖生物学, 翻译后修饰, 蛋白质组学
  • {SNA} Chemical Synthesis,

产品应用

  • 通过二醇的裂解和氢醌的氧化生成醌。

相关文献及参考

  • For review of use in the cleavage of 1,2-diols to carbonyl compounds, see: Synthesis, 229 (1974). For application to the high-yield, racemization-free preparation of the useful intermediate isopropylidene-D-glyceraldehyde, see: Synth. Commun., 18, 337 (1988). See also: Org. Synth. Coll., 9, 450, 454 (1998).
  • Short: III/20a
  • Alkyl halides, on heating with NaIO4 in DMF, can be oxidized to aldehydes or ketones: Tetrahedron Lett., 44, 1375 (2003). For use, in the presence of Dibenzo-18-crown-6, A13133, in the oxidative decarboxylation of arylacetic acids to benzaldehydes and of phenacyl bromides to benzoic acids, see: Indian J. Chem. B, 35B, 151 (1996).
  • Useful for selective oxidation of sulfides to sulfoxides; see, for example: Org. Synth. Coll., 9, 63 (1998).
  • For use in the in situ regeneration of RuO4, see Ruthenium(III)­ chloride hydrate, 11043.
  • Merck: 14,8640
  • This reaction can be extended to the cleavage of alkenes, by use in conjunction with a reagent for the hydroxylation of alkenes, which can be regenerated by reoxidation by periodate. For use in combination with KMnO4 (Lemieux-von Rudloff reagent), see: Can. J. Chem., 33, 1701, 1710 (1955), for cleavage of a steroidal enone, see: Org. Synth. Coll., 6, 690 (1988). The combination with OsO4 is known as the Lemieux-Johnson reagent: J. Org. Chem., 21, 478 (1956); Synthesis, 45 (1989).

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 5.1 O,T,C,N O;Xn
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H271 May cause fire or explosion; strong oxidizer 可能会引起火宅或爆炸；强氧化剂。
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
  • H301 Toxic if swallowed 吞食有毒
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSSD4550000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340+P310
  • P305+P351+P338
  • P370+P378
  • P371+P380+P375
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S17 Keep away from combustible material 远离可燃物料；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
UN Number 3087 UN1479
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
Storage condition Hygroscopic 密封避光保存。 充氩保存
Packing GroupII
Hazard Class5.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 58 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261, 1835-1965.  For publisher information, see CRASEV.
    Volume(issue)/page/year: 257,791,1963

Restrict 危险品

其他信息

  • 类别:氧化剂
  • 方法一:氯气氧化法 将碘在水介质中，通入氯气进行氧化生成高碘酸，经分离杂质后，加入氢氧化钠溶液中和至Ph2～3，生成高碘酸钠溶液，再经提纯、分离杂质、蒸发浓缩、冷却结晶、离心分离
  • 爆炸物危险特性:与还原剂、硫、磷等混合受热、撞击、摩擦可爆
  • 外观性质:无色结晶或白色晶状粉末。
  • 上游原料:氯化钠 --> 碘 --> 高碘酸 --> 碘
  • 参考质量标准:专业标准ZB/TG 12008—88 指标名称 指标 优等品 一等品 合格品 外观 白色 白色 微带黄色 高碘酸钠(NaIO4)/%≥ 99.0 99.0 98 锰(Mn)/%≤ 0.0002 0.0003 0.0005 重金属(以Pb计)/%≤ 0.002 0.002 0.002 氯化物和溴化物(以Cl - 计)/%≤ 0.03 0.06 0.1 澄清度试验 合格 合格 合格
  • 图谱信息:高碘酸钠(7790-28-5)红外图谱(IR1)
  • 可燃性危险特性:燃烧产生有毒
  • MSDS 信息:高碘酸钠(7790-28-5).msds
  • 储
  • 高碘酸钠价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80117316 偏高碘酸钠 100g 112元 2011/08/23 80117326 偏高碘酸钠 100g 57.8元 2011/08/23 KR3032301 高碘酸钠;偏高碘酸钠 100g 1663元
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 1.83g/0℃;5.6g/10℃;10.3g/20℃;19.9g/30℃;30.4g/40℃
  • 敏感性:Hygroscopic
  • 用途二:用作普通分析试剂及色谱分析试剂
  • 毒性:对皮肤和眼睛有刺激作用，应防止与皮肤和眼睛接触。如不慎溅到皮肤上要用肥皂水洗掉；若溅人眼睛内要立即用大量水冲洗15 mln，并请医生诊治。应注意防尘。 操作时要穿戴工作服、乳胶手套、密闭防护眼镜、口罩等劳保防护用具。生产设备要密闭，通风应良好。
  • 用途三:可用作氧化剂。用于陶瓷片纸、印花布、印片纸等丝网印花的制版工艺；在印刷版制造过程中，用于从印刷版底层除去不溶的聚乙烯醇层。还用于食品工业和制药业。
  • 储运特性:库
  • 海关编码:28299080
  • Acros Organics:高碘酸钠 Sodium periodate, for analysis, 99%(7790-28-5)
  • 下游产品:
  • MOL 文件:7790-28-5.mol
  • Alfa Aesar:偏高碘酸钠,ACS,99.8-100.3% Sodium metaperiodate, ACS, 99.8-100.3%(7790-28-5)
  • 毒性分级:高毒
  • 灭火剂:雾状水、砂土、泡沫
  • F:8
  • 用途一:用作氧化剂，用于陶瓷片纸、印花布等丝网印花的制版工艺，还用于食品工业和制药
  • Sodium periodate is a strong oxidizing hypervalent iodine compound, able to facilitate a large scope of oxidation transformations in organic synthesis. Saccharide rings and bonds can be oxidatively cleaved under mild conditions using Sodium periodate.
  • 300℃溶解并分解，溶于水、硫酸、硝酸和醋酸，不溶于氢氧化钠溶液和乙醇。
  • 用途四:医药工业的重要原料，还是作普通分析试剂及色谱分析试剂。
  • 急性毒性:腹腔- 小鼠 LD50: 58 毫克/ 公斤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Sodium - Catalysis and Inorganic Chemistry
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Chromates - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Hypervalent Iodine - Oxidation
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Sodium Salts 钠盐
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  5. Q-S, Puriss p.a. ACS - Puriss p.a. ACS
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Post-Translational Modification - Proteomics
  4. Glycobiology - Post-Translational Modification
  5. Glycoprotein Detection - Glycobiology
  6. Detection of Biotin Labeled Glycoproteins on Western Blots - Glycoprotein Detection
  1. Analytical & Chromatography 分析化学与色谱
  2. Routine Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Glycobiology
  4. Glycoprotein Detection
  5. Colorimetric Detection of PAGE and Western Blots
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Post-Translational Modification
  5. Glycobiology
  6. Glycan Labeling and Analysis