Palladium(II) Chloride 氯化钯

CAS 7647-10-1 MFCD00003558

化学结构图

7647-10-1
SMILES: Cl[Pd]Cl

化学属性

Mol. FormulaPdCl2
Mol. Weight177.32
Density4
Melting Point678-680
TSCAYes
SolubilitySoluble in dilute mineral acids, aqueous metal halides
Appearance 红褐色结晶粉末，溶于水、盐酸、乙醇、丙酮和氢溴酸。
Stability易吸潮

别名和识别编码

Chemical NamePalladium(II) Chloride
CAS Number7647-10-1
Alfabeta NamePALLADIUMCHLORIDE II()
MDL NumberMFCD00003558
PubChem Substance ID24290
EC Number231-596-2
Merck Number6990
Synonym Palladium(II) chloride {LY} Palladium(II) chloride {} {LY} Palladium(II) chloride {} {} {LY} Palladium(II) chloride {} {} {} {LY} Palladium(II) chloride {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Palladium(II) chloride {} {} {} {} {} {} {} {}
Beilstein Registry Number2384789
Chemical Name Translation氯化钯
Wiswesser Line NotationPD G2
LabNetwork Molecule IDLN00170222
InChIInChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2
Canonical SMILESCl[Pd]Cl
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts,
  • {SNA} Catalysis and Inorganic Chemistry,
  • {Chemicalbook} 无机化工产
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Homogeneous Pd Catalysts, Materials Science, Metal and Ceramic Science, Palladium, Palladium Salts, Salts
  • {uni_hamb

产品应用

  • 1、点滴测定钯、汞、铊和碘，提纯稀有气味，氯化钯试纸检验一氧化碳、检定钴。
  • 2、催化剂，末端烯径（α-烯径）生成甲基酮的氧化催化。
  • 3、通过Wacker反应，在水溶液中用空气作氧化剂，使烯径氧化成醛。
  • 4、用于合成半导体含金属聚合体，该聚合体具有聚吡咯骨架，符合能量最小且接近平面。

相关文献及参考

  • For use in the microwave accelerated Heck coupling reaction of aryl halides in the ionic liquid 1-n-Butyl-3-methyl­imidazolium hexafluorophosphate, L19086, see: J. Org. Chem., 67, 6243 (2002).
  • In combination with benzoquinone as reoxidant, N-methylarylamines add to Michael acceptors to give enamines: J. Org. Chem., 46, 2561 (1981).
  • In the presence of triphenylphosphine and MeLi, a Pd(0) species is generated which catalyzes the coupling of organolithium reagents with aryl or vinyl halides. For tabulated results, see: Org. Synth. Coll., 7, 172 (1990):
  • Merck: 14,6990
  • Miki, K.; Nishino, F. et al. J. Am. Chem. Soc. 124 , 5260, (2004)
  • Short: III/20b
  • Terminal olefins can be oxygenated to ketones using a Cu(I) catalyst in the presence of a catalytic amount of PdCl2 (the Wacker process): Org. Synth. Coll., 7, 137 (1990). For an example in which the product is readily cyclized to give a useful terpenoid synthon, see: Org. Synth. Coll., 8, 208 (1993):

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes 6.1 C,Xi,T+ C,Xn T T+
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H303 May be harmfully swallowed 吞食可能有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECSRT3500000
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P317
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S27/28
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
UN Number 3288
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R25 Toxic if swallowed 吞咽有毒
  • R28 Very toxic if swallowed 吞咽极毒
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
Packing GroupIII
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class8 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 880 mg/kg/75W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Blood - leukemia
REFERENCE :
   JONUAI Journal of Nutrition.  (Subscription Dept., 9650 Rockville Pike,
   Bethesda, MD 20014) V.1-    1928-  Volume(issue)/page/year: 101,1431,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 10,63,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATSUDG Archives of Toxicology, Supplement.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  No.1-    1978-
   Volume(issue)/page/year: 13,357,1989

TYPE OF TEST

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 87 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ATSUDG Archives of Toxicology, Supplement.  (Springer-Verlag New York, Inc.,
   Service Center, 44 Hartz Way, Secaucus, NJ 07094)  No.1-    1978-
   Volume(issue)/page/year: 13,357,1989

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 18600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BSIBAC Bolletino della Societe Italiana di Biologia Sperimentale.  (Casa
   Editrice Idelson, Via A. de Gasperi, 55, 80133 Naples, Italy)  V.2- 1927- 
   Volume(issue)/page/year: 8,1154,1933

TYPE OF TEST            : LD5

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 600 umol/L
REFERENCE :
   IAAAAM International Archives of Allergy and Applied Immunology.  (S. Karger
   Pub., Inc., 79 Fifth Ave., New York, NY 10003)  V.1-    1950-
   Volume(issue)/page/year: 79,83,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 3546 ug/kg
SEX/DURATION            : male 30 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JRPFA4 Journal of Reproduction and Fertility.  (Biochemical Soc. Book Depot,
   POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK)  V.1-    1960-
   Volume(issue)/page/year: 7,21,1964

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intratesticular
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3546 ug/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JRPFA4 Journal of Reproduction and Fertility.  (Biochemical Soc. Book Depot,
   POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK)  V.1-    1960-
   Volume(issue)/page/year: 7,21,1964

其他信息

  • 用途一:用于制备特种催化剂、分子筛；配制非导体材料镀层；制作气敏元件等。
  • 用途二:主要用于制造特种产品催化剂、分子筛，配制非导体材料镀层用的表面活化剂，制作气体敏感元件等
  • F:3
  • 上游原料:乙醇 --> 二氯甲烷 --> 甲苯 --> 钯 --> 乙腈 --> 海绵钯
  • 图谱信息:氯化钯(7647-10-1)红外图谱(IR1)
  • 下游产品:醋酸钯 --> 乙酸乙烯酯 --> 四(三苯基膦)钯 --> 乙醛 --> 丙醛 --> 二苯基乙炔 --> 二氯[1,1'-双(耳叔丁基膦)二茂铁钯(II) ]PALLADIUM(II) --> 3-氨基苯甲酸 --> 三(二亚苄基丙酮)二钯-氯仿加合物 --> 6-羟基吲哚 --> 5-羟基-2-戊酮 --> 乙烯基正丁醚 --> [1,1'-双(二苯基膦基)二茂铁]二氯化钯 --> 双三苯基磷二氯化钯 --> 6-苄氧基吲哚 --> 二(三叔丁基膦)钯 --> 二氯二(三环己基瞵)钯 --> 双(二亚芐基丙酮)钯 --> 聚2,6-二甲基-1,4-苯醚负载钯催化剂 --> 三(二亚苄基丙酮)二钯 --> N,N,N',N'-四甲基-2-丁烯-1,4-二胺 --> 达尔卓潘 --> 2-甲基四氢呋喃 --> [1,1'-双(二苯基膦)二茂铁]二氯化钯二氯甲烷络合物 --> 二(乙酰丙酮)钯(II) --> 1,2-二(二苯基膦基)乙烷二氯化钯(II) --> (1,5-环辛二烯)二氯化钯(II) --> 二(氰基苯)二氯化钯 --> 双(乙腈)氯化钯(II) --> 硫酸沙丁胺醇
  • 贵金属催化剂:贵金属催化剂是指一种能改变化学反应速度而本身又不参与反应最终产物的贵金属材料。1831年英国菲利普斯(philips)提出以铂为催化剂的接触法制造硫酸，到1875年该法实现工业化，这是贵金属催化剂的最早工业应用。几乎所有的贵金属都可用作催化剂，但常用的是铂、钯、铑、银、钌等，其中尤以铂、铑应用最广。按催化反应类别，贵金属催化剂可分为均相催化用和多相催化用两大类。均相催化用催化剂通常为可溶性化合物(盐或络合物)，如氯化钯、氯化铑、醋酸钯、羰基铑、三苯膦羰基铑等。多相催化用催化剂为不溶性固体物，其主要形态为金属丝网态和多孔无机载体负载金属态。金属
  • 用途四:主要用作乙烯法制乙醛的催化剂和其他钯系催化剂。制造分子筛，配制非导体材料镀层用的表面活化剂。用于制造气体敏感元件等。
  • TCI Shanghai:氯化钯 Palladium(II) Chloride,>;98.0%(T)(7647-10-1)
  • MOL 文件:7647-10-1.mol
  • 用途三:用作分析试剂
  • 海关编码:28439090
  • MSDS 信息:Palladium (II) chloride(7647-10-1).msds
  • 用途五:1、点滴测定钯、汞、铊和碘，提纯稀有气味，氯化钯试纸检验一氧化碳、检定钴。2、催化剂，末端烯径（α-烯径）生成甲基酮的氧化催化。3、通过Wacker反应，在水溶液中用空气作氧化剂，使烯径氧化成醛。4、用于合成半导体含金属聚合体，该聚合体具有聚吡咯骨架，符合能量最小且接近平面。
  • 概述:氯化钯又名氯化亚钯，是一种常用的贵金属催化剂，分子式PaCl2，外观为棕红色针状晶体或粉末，易潮解，相对密度4.0 (18℃)，熔点500℃(分解)，溶于水、乙醇、氢溴酸和丙酮。在氯化氨、碘化钾、氨水溶液中分解并析出钯。用作分析试剂，如测定微量钯、汞、铊、碘等。氯化钯试纸用于检验一氧化碳。还用于搜寻地下埋藏煤气管道的裂缝、农业植物资源的研究、触媒钯的制取、电镀钟表零件和照相术等。通过熔融二氯化钯水合物使其失去部分氯而得氯化钯成品。
  • 参考质量标准:国家标准GB 8185—87 指标名称 指标 一级品 二级品 外观 棕色结晶 钯(Pd)/%≥ 59.0 58.0 铁(Fe)/%≤ 0.01 0.02 硝酸盐(以NO3
  • 方法一:将钯粉加入盛有盐酸的反应器中，在搅拌下通入空气进行氧化反应，生成氯化钯溶液，经溶液提纯、过滤、蒸发浓缩、冷却结晶、离心分离、干燥，制得氯化钯成品。其 Pd+2HCl+0.5O2→PdC12+H2O

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Palladium Catalysis 钯催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Palladium Catalysis 钯催化剂
  4. Homogeneous Pd Catalysts - Palladium
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Others - Inorganic Salts
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIA - DIC - D
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Crystal Grade Inorganics 晶体级无机物
  4. Palladium - Crystal Grade Inorganics
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Palladium Salts - Salts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Palladium 钯催化剂
  5. Heterogeneous Pd Catalysts
  1. Catalysts
  2. Palladium
  1. Catalysts
  2. 96-4650 Palladium Kit
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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