Isocyanic Acid Cyclohexyl Ester 环己基异氰酸脂

CAS 3173-53-3 MFCD00003840

化学结构图

3173-53-3
SMILES: O=C=NC1CCCCC1

化学属性

Mol. FormulaC7H11NO
Mol. Weight125
Density0.98
Refractive index1.4540 to 1.4570
Flash Point48°C(lit.)
TSCAYes
Boiling Point168-170
Melting Pointca -80°
Vapor Pressure1.83 psi ( 20 °C)
Solubility分解
Appearance 淡黄色液体,有刺激性气味,相对密度0.980,沸点168-170℃,闪点35℃,能与水反应.

别名和识别编码

Chemical NameIsocyanic Acid Cyclohexyl Ester
Synonym CYCLOHEXYL ISOCYANATE CYCLOHEXYL ISOCYANATE 98% Cyclohexane, isocyanato- Cyclohexyl #niso-cyanate Cyclohexyl ester of isocyanic acid Cyclohexyl isocyanate Cyclohexylisocyanate Cyclohexylisocyanate,98% ISOCYANIC ACID CYCLOHEXYL ESTER Isocyanato-cyclohexane Isocyanatocyclohexane Isocyanatocyclohexane Isocyanic acid cyclohexyl ester CHI Isocyanic acid, cyclohexyl ester Isocyanic acid,cyelohexyl ester Isocyansäurecyclohexylester NSC 87419 chi cyclohexane,isocyanato- cyclohexyl cyclohexylisocyanate cyclohexylisocyanate(isocyanatocyclohexane) isocyanato-cyclohexan isocyanatocyclohexane nsc87419 异氰酸环己酯 异氰酸环已
MDL NumberMFCD00003840
CAS Number3173-53-3
EC Number221-639-3
Beilstein Registry Number507983
PubChem Substance ID18502
Chemical Name Translation环己基异氰酸脂
Reaxys-RN507983
LabNetwork Molecule IDLN00177595
InChIInChI=1S/C7H11NO/c9-6-8-7-4-2-1-3-5-7/h7H,1-5H2
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {Chemicalbook} 农药中间体: 除草剂中间体: 除草剂中间体
  • {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; isocyanate; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Isocyanates, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 环己基异氰酸酯是除草剂环嗪酮的中间体,可用作合成医药或农药的中间体。

相关文献及参考

  • Short: EINECS
  • Short: III/35E
  • Beilstein:12(2)12
  • Short: II/14a

安全信息

Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S29 Do not empty into drains 不要排入下水道;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R10 Flammable 易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R26 Very toxic by inhalation 吸入极毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R42 May cause sensitisation by inhalation 吸入会产生过敏反应
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R51/53
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
  • P301+P312
  • P301+P312+P330
  • P301+P330+P331
  • P302+P352
  • P302+P352+P312+P362+P364
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P304+P341
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P342+P311
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSNQ8650000
Packing GroupI
UN Number 2488
Storage condition 0-10°C Flammables area Moisture Sensitive
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 T+ T+,N
Hazard Class6.1/3
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04502

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 13 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCISP* National Cancer Institute Screening Program Data Summary,
   Developmental Therapeutics Program. (Bethesda, MD 20205)
   Volume(issue)/page/year: JAN1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 150 ug/plate
REFERENCE :
   ABCHA6 Agricultural and Biological Chemistry.  (Maruzen Co. Ltd., POB 5050,
   Tokyo International, Tokyo 100-31, Japan)  V.25-    1961-
   Volume(issue)/page/year: 44,3017,1980

其他信息

  • 图谱信息:环己基异氰酸酯(3173-53-3)质谱(MS) 环己基异氰酸酯(3173-53-3)Raman光谱 环己基异氰酸酯(3173-53-3)红外图谱(IR2) 环己基异氰酸酯(3173-53-3)红外图谱(IR1)
  • 用途二:环己基异氰酸酯是除草剂环嗪酮的中间体。
  • F:10-19-21
  • 下游产品:噻螨酮 --> 环嗪酮
  • 爆炸物危险特性:蒸气与空气混合可爆
  • 方法一:其制备方法是将环己胺与光气反应,先生成盐酸盐,再加热通光气,得到产品。
  • 上游原料:光气(无法供) --> 环己胺
  • 水中分解,溶于乙醚。
  • Acros Organics:环己基异氰酸脂 Cyclohexyl isocyanate, 98+%(3173-53-3)
  • MSDS 信息:Isocyanatocyclohexane(3173-53-3).msds
  • 类别:有毒物品
  • 用途一:用作合成医药或农药的中间体
  • TCI Shanghai:环己基异氰酸酯 Cyclohexyl Isocyanate,>;98.0%(GC)(3173-53-3)
  • 海关编码:29291090
  • MOL 文件:3173-53-3.mol
  • 用途三:环己基异氰酸酯是除草剂环嗪酮的中间体,可用作合成医药或农药的中间体。
  • Alfa Aesar:异氰酸环已酯,98% Cyclohexyl isocyanate, 98%(3173-53-3)
  • Sigma Aldrich:3173-53-3(sigmaaldrich)
  • 毒性分级:高毒
  • 储运特性:库房通风低温干燥; 与氧化剂, 酸类, 食品分开储运
  • 急性毒性:腹注-小鼠 LD50: 13 毫克/公斤
  • 可燃性危险特性:可燃; 燃烧产生有毒氧化氮气体
  • 环己基异氰酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0122 异氰酸环己酯 Cyclohexyl Isocyanate 500G 650元 2014/06/02 I0122 异氰酸环己酯 Cyclohexyl Isocyanate 25G 89元 2010/06/21 111315000 环己基异氰酸酯 Cyclohexyl isocyanate 98+% 500 GR 765元
  • 灭火剂:干粉, 砂土, 泡沫, 二氧化碳
  • 敏感性:Moisture Sensitive
  • 蒸气压:1.83 psi ( 20 °C)

系列性分类