Tricyclohexyl phosphine 三环己基膦

CAS 2622-14-2 MFCD00003853

化学结构图

2622-14-2
SMILES: c1ccc(P(C2CCCCC2)C2CCCCC2)cc1

化学属性

TSCAYes
Boiling Point383.4°C at 760 mmHg
Mol. FormulaC18H33P
Mol. Weight280.43
Appearance white xtl. colorless to light yellow liq.
Stabilityair sensitive
Melting Point81-83°C
Density0.9
Flash Point40°F (toluene)
RedoxReduction

别名和识别编码

Chemical NameTricyclohexyl phosphine
EC Number220-069-2
Beilstein Registry Number957171
Synonym Tricyclohexylphosphine {LY} Tricyclohexylphosphine {} {LY} Tricyclohexylphosphine {} {} {LY} Tricyclohexylphosphine {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tricyclohexylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tricyclohe
PubChem Substance ID24869033
Chemical Name Translation三环己基膦
InChIKeyWLPUWLXVBWGYMZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00010018
MDL NumberMFCD00003853
CAS Number2622-14-2
Canonical SMILESP(C1CCCCC1)(C2CCCCC2)C3CCCCC3
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分类

  • {SNA} Catalysis, Basic Phosphine Ligands, Catalysis and Inorganic Chemistry,
  • {SNA} Basic Phosphine Ligands, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosphine Compounds, Phosphine Ligands, Related Palladacycles
  • {SNA} Related Palladacycles, Basic Phosphine Ligands, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosphine Compounds, Phosphine Ligands
  • {SNA} Basic Phosphine Lig
  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry,

产品应用

  • 金属催化剂。

相关文献及参考

  • Beilstein: 16,IV,947

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R48/20
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R36 Irritating to eyes 刺激眼睛
Precautionary statements
  • P301+P312
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335+H336
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Gloves
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen Air Sensitive {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under ni
Hazard Codes Xn F,Xn Xi Xi,Xn,F
Packing GroupIII
UN Number UN 2056 3/PG 2

其他信息

  • 存储注意事项:空气敏感;氮气保护
  • Alfa Aesar:三环己基膦,96% Tricyclohexylphosphine, 96%(2622-14-2)
  • TCI Shanghai:三环己基膦(约18%的甲苯溶液,约0.60mol/L)(含三环己基氧化膦) Tricyclohexylphosphine (contains Tricyclohexylphosphine Oxide) (ca. 18% in Toluene, ca. 0.60mol/L)(2622-14-2)
  • 敏感性:Air Sensitive
  • 下游产品:二氯二(三环己基瞵)钯
  • 上游原料:乙醚 --> 氯化铵 --> 镁 --> 三氯化磷 --> 溴代环己烷
  • MOL 文件:2622-14-2.mol
  • Acros Organics:三环己基膦 Tricyclohexyl phosphine, 97%(2622-14-2)
  • 三环己基膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A26197103 三环己基膦 25g 2860元 2010/06/21 421610010 三环己基膦 Tricyclohexylphosphine 97% 1 GR 363元 2010/06/21 421610050 三环己基膦 Tricyclohexylphosphine 97% 5 GR 1622元
  • 图谱信息:三环己基膦(2622-14-2)质谱(MS) 三环己基膦(2622-14-2)核磁图( 13 CNMR)
  • 用途一:作为配体，用于Buchwald, Suzuki等偶联反应中
  • 用途二:金属催化剂。
  • Sigma Aldrich:2622-14-2(sigmaaldrich)
  • MSDS 信息:Tricyclohexyl phosphine(2622-14-2).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling - Catalysis and Inorganic Chemistry
  4. Basic Phosphine Ligands - Cross-Coupling
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Mitsunobu Reaction
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling 交叉偶联
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus