1-Bromonaphthalene 1-溴萘

CAS 90-11-9 MFCD00003868

化学结构图

90-11-9
SMILES: Brc1cccc2ccccc12

化学属性

Mol. FormulaC10H7Br
Mol. Weight207.07
Density1.48
Refractive index1.6550 to 1.6600
Boiling Point133-134°C at 760 mmHg
Melting Point-2--1°C
Flash Point110°C
TSCAYes
Solubility略溶于水
Stability对光敏感
Appearance 无色或微黄色液体。 不溶于水，能与醇、醚、苯和氯仿混溶。
pH:A

别名和识别编码

Chemical Name1-Bromonaphthalene
CAS Number90-11-9
EC Number201-965-2
Beilstein Registry Number5,547
MDL NumberMFCD00003868
Synonym 1-Bromonaphthalene {LY} 1-Bromonaphthalene {} {LY} 1-Bromonaphthalene {} {} {LY} 1-Bromonaphthalene {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Brom
PubChem Substance ID87563626
Merck Number1425
Chemical Name Translation1-溴萘
Reaxys-RN1906414
Wiswesser Line NotationL66J BE
LabNetwork Molecule IDLN00195982
InChIInChI=1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
Canonical SMILESBrC1=C2C=CC=CC2=CC=C1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SNA} Aryl, Building Blocks, C9 to C12, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 有机合成原料，分析试剂，用作冷冻剂以及分子量大的物质的溶剂。也是干燥物品的热载体。亦可用于折射率测定。

相关文献及参考

  • Short: II/27B
  • Merck: 14,1425 Beilstein:5,547
  • Short: II/3
  • Merck: 14,1425

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSQJ1545000
Hazard Codes Xn Xn,Xi
Storage condition 2-8°C {LY} 2-8°C {} { {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature
Packing GroupIII
Hazard Class6.1(b)
UN Number 2810 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 810 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(12),52,1976

其他信息

  • MSDS 信息:alpha-Bromonaphthalene(90-11-9).msds
  • 检测方法:GC
  • 急性毒性:腹腔- 小鼠 LD50: 810 毫克/ 公斤
  • 图谱信息:1-溴化萘(90-11-9)核磁图( 1 HNMR) 1-溴化萘(90-11-9)Raman光谱 1-溴化萘(90-11-9)质谱(MS) 1-溴化萘(90-11-9)红外图谱(IR2) 1-溴化萘(90-11-9)红外图谱(IR1) 1-溴化萘(90-11-9)核磁图( 13 CNMR)
  • 用途一:用作有机合成原料，用作冷冻剂以及分子量大的物质的溶剂，也是干燥物品的热载体
  • 用途二:用于折光率的测定、染料及有机化合物的合成， 也用作干燥物的传热介质
  • 上游原料:溴 --> 四氯化碳
  • 毒性分级:中毒
  • MOL 文件:90-11-9.mol
  • 类别:易燃液体
  • 灭火剂:干粉、泡沫、砂土、水
  • 海关编码:29036990
  • Acros Organics:1-溴萘 1-Bromonaphthalene, 96%(90-11-9)
  • 储运特性:库房通风低温干燥
  • Sigma Aldrich:90-11-9(sigmaaldrich)
  • 下游产品:N,N'-二苯基-N,N'-(1-萘基)-1,1'-联苯-4,4'-二胺 --> 1-萘甲酸 --> 1-奈硫酚 --> 1-萘硼酸 --> 1-萘甲腈
  • TCI Shanghai:1-溴萘 1-Bromonaphthalene,>;95.0%(GC)(90-11-9)
  • 蒸馏后能保持无色，但久置后变黑色。能与醇、醚、四氯化碳相混溶，微溶于水。能随水蒸汽挥发。
  • color:slightly yellow to deep brownish-yellow
  • Alfa Aesar:1-溴萘,97% 1-Bromonaphthalene, 97%(90-11-9)
  • F:8
  • 方法一:由萘与溴反应而得。在反应锅中加入四氯化碳和萘，搅拌加热，在45℃慢慢加入溴素。加完后于70-80℃保温反应3-4h。蒸馏回收四氯化碳，将反应物洗涤、减压蒸馏、再洗涤、过滤、干燥而得成品。
  • 用途三:有机合成原料，分析试剂，用作冷冻剂以及分子量大的物质的溶剂。也是干燥物品的热载体。亦可用于折射率测定。
  • 可燃性危险特性:易燃; 燃烧产生有毒溴化物气体
  • 1-溴化萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30027428 1-溴代萘 500ml 178元 2011/04/16 B0618 1-溴萘 1-Bromonaphthalene 500G 1140元 2011/04/16 B0618 1-溴萘 1-Bromonaphthalene 25G 153元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  6. C9 to C12 - Aryl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳香卤代烃
  6. C8