2-Bromonaphthalene 2-溴代萘

CAS 580-13-2 MFCD00004051

化学结构图

580-13-2
SMILES: Brc1ccc2ccccc2c1

化学属性

Mol. FormulaC10H7Br
Mol. Weight207.07
Density1.605
Boiling Point281-282 °C at 760 mmHg
Melting Point52-55 °C
Flash Point112°(233°F)
TSCAYes
Solubility略溶于水
Appearance 无色晶体。 不溶于水,可溶于乙醇、乙醚、苯、氯仿。
Refractive index1.6382

别名和识别编码

Chemical Name2-Bromonaphthalene
CAS Number580-13-2
Alfabeta NameBROMONAPHTHALENE 2-
MDL NumberMFCD00004051
Synonym 2-Bromonaphthalene {LY} 2-Bromonaphthalene {} {LY} 2-Bromonaphthalene {} {} {LY} 2-Bromonaphthalene {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromonaphthalene {} {} {} {} {
EC Number209-452-5
Beilstein Registry Number1858110
PubChem Substance ID87563627
Reaxys-RN1858110
Merck Number1426
Chemical Name Translation2-溴代萘
LabNetwork Molecule IDLN00008498
InChIInChI=1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H
Canonical SMILESC1=C2C(=CC=C1Br)C=CC=C2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SNA} Aryl, B, Bioactive Small Molecules, Building Blocks, C9 to C12, Cell Biology, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {SNA} Aryl, B, Bioactive Small Molecules, Building Blocks, C9 to C12, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks, 细胞生物学
  • {SNA} Aryl, Building Blocks, C9 to C12, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

相关文献及参考

  • Short: II/27B
  • The Grignard reagent has been reacted with N-benzylproline methyl ester in the synthesis of oxazaborolidines (compare (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219) for use as chiral auxiliaries: J. Org. Chem., 56, 442 (1991).
  • {
  • Short: II/3

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36 Irritating to eyes 刺激眼睛
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn Xn,Xi,T
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number UN 1230 3/PG 2

其他信息

  • MOL 文件:580-13-2.mol
  • 用途二:用于染料的制备
  • MSDS 信息:2-Bromonaphthalene(580-13-2).msds
  • Sigma Aldrich:580-13-2(sigmaaldrich)
  • 用途三:有机合成和染料中间体。
  • Acros Organics:2-溴萘 2-Bromonaphthalene, 99%(580-13-2)
  • 2-溴代萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0619 2-溴萘 2-Bromonaphthalene 5G 151元 2014/06/02 B0619 2-溴萘 2-Bromonaphthalene 25G 525元 2010/06/21 179710250 2-溴代萘 2-Bromonaphthalene 99% 25 GR 1567元
  • TCI Shanghai:2-溴萘 2-Bromonaphthalene,>;98.0%(GC)(580-13-2)
  • 检测方法:HPLC
  • 方法一:由2-萘酚与溴反应而得。
  • 图谱信息:2-溴代萘(580-13-2)核磁图( 13 CNMR) 2-溴代萘(580-13-2)质谱(MS) 2-溴代萘(580-13-2)红外图谱(IR1) 2-溴代萘(580-13-2)核磁图( 1 HNMR) 2-溴代萘(580-13-2)红外图谱(IR2)
  • Alfa Aesar:2-溴萘,98+% 2-Bromonaphthalene, 98+%(580-13-2)
  • 下游产品:2-萘硫醇 --> 2-萘硼酸
  • 用途一:主要用作医药中间体
  • Hazard Note:Irritant
  • 海关编码:29036990

系列性分类


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