1,8-Diaminonaphthalene 1,8-二氨基萘

CAS 479-27-6 MFCD00004033

化学结构图

479-27-6
SMILES: Nc1cccc2cccc(N)c12

化学属性

Mol. FormulaC10H10N2
Mol. Weight158.20
Density1.234
Boiling Point352.1°C at 760 mmHg
Melting Point60-65°C
Flash Point195°(383°F)
TSCAYes
Solubility略溶于水
Appearance 浅红色结晶,微溶于水。
Refractive index1.6829

别名和识别编码

Chemical NameNaphthalene-1,8-diamine
Synonym Naphthalene-1,8-diamine {LY} Naphthalene-1,8-diamine {} {LY} Naphthalene-1,8-diamine {} {} {LY} Naphthalene-1,8-diamine {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Naphthalene-1,8-diamine {} {} {} {} {} {} {} {} {
CAS Number479-27-6
EC Number207-529-8
Beilstein Registry Number742841
MDL NumberMFCD00004033
PubChem Substance ID68067
Merck Number6372
Reaxys-RN742841
Chemical Name Translation1,8-二氨基萘
LabNetwork Molecule IDLN00193911
InChIInChI=1S/C10H10N2/c11-8-5-1-3-7-4-2-6-9(12)10(7)8/h1-6H,11-12H2
Canonical SMILESNC1=C2C(N)=CC=CC2=CC=C1
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {SNA} Detection, Wavelength Index, 发光化合物及其检测, 生化试剂, 荧光探针，标记，粒子和染色剂
  • {SA} Biochemicals and Reagents, Detection, Fluorescent Probes, Labels, Particles and Stains, Luminescent Compounds/Detection, Wavelength Index

产品应用

  • 主要作为中间体而用于一些染料的有机合成中.由于1,8-二氨基萘应用极为广泛而配成溶液稳定性较差。

相关文献及参考

  • Short: III/35D2
  • Beilstein:13,205
  • Short: III/35B

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P333+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H351 Suspected of causing cancer 怀疑致癌
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes Xn Xn,Xi
UN Number 2811
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 用途一:用于有机合成
  • 下游产品:溶剂橙 60 --> 溶剂红 135 --> 溶剂红 179
  • Sigma Aldrich:479-27-6(sigmaaldrich)
  • F:8
  • Alfa Aesar:1,8-二氨基萘,97% 1,8-Diaminonaphthalene, 97%(479-27-6)
  • 海关编码:29215940
  • TCI Shanghai:1,8-二氨基萘 1,8-Diaminonaphthalene,>;98.0%(T)(479-27-6)
  • 1,8-二氨基萘价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0102 1,8-二氨基萘 1,8-Diaminonaphthalene 25G 318元 2014/06/02 D0102 1,8-二氨基萘 1,8-Diaminonaphthalene 500G 2280元 2010/06/21 371180025 1,8-二氨基萘 1,8-Diaminonaphthalene 97% 2.5 KG 9982元
  • MOL 文件:479-27-6.mol
  • 图谱信息:1,8-二氨基萘(479-27-6)核磁图( 1 HNMR) 1,8-二氨基萘(479-27-6)核磁图( 13 CNMR) 1,8-二氨基萘(479-27-6)红外图谱(IR2) 1,8-二氨基萘(479-27-6)质谱(MS) 1,8-二氨基萘(479-27-6)红外图谱(IR1)
  • MSDS 信息:1,8-Diaminonaphthalene(479-27-6).msds
  • Hazard Note:Irritant
  • Acros Organics:1,8-二氨基萘 1,8-Diaminonaphthalene, 99%(479-27-6)
  • 用途二:主要作为中间体而用于一些染料的有机合成中.由于1,8-二氨基萘应用极为广泛而配成溶液稳定性较差。
  • 微溶于水，溶于醇和醚；微溶于氯仿。

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Fluorescent Probes, Labels, Particles and Stains - Biochemicals and Reagents
  4. Detection - Fluorescent Probes, Labels, Particles and Stains
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Luminescent Compounds/Detection - Biochemicals and Reagents
  4. Wavelength Index - Luminescent Compounds/Detection
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Fluorescent Probes, Labels, Particles and Stains
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Luminescent Compounds/Detection
  4. Fluorescent Probes, Labels, Particles and Stains

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