Silver Diethyldithiocarbamate 二乙基二硫代氨基甲酸银

CAS 1470-61-7 MFCD00004929

化学结构图

1470-61-7
SMILES: CCN(CC)C(=S)S[Ag]

化学属性

Mol. FormulaC5H10AgNS2
Mol. Weight256.14
Melting Point172-175 °C
TSCAYes
Density1.422
Stability对光敏感

别名和识别编码

Chemical NameSilver Diethyldithiocarbamate
MDL NumberMFCD00004929
CAS Number1470-61-7
EC Number216-003-7
Synonym Silver diethyldithiocarbamate {LY} Silver diethyldithiocarbamate {} {LY} Silver diethyldithiocarbamate {} {} {LY} Silver diethyldithiocarbamate {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver diethyldithiocarbamate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number3718150
PubChem Substance ID3034078
Reaxys-RN3718150
Chemical Name Translation二乙基二硫代氨基甲酸银
InChIInChI=1S/C5H11NS2.Ag/c1-3-6(4-2)5(7)8;/h3-4H2,1-2H3,(H,7,8);/q;+1/p-1
LabNetwork Molecule IDLN00193703
Canonical SMILESCCN(CC)C(S[Ag])=S
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分类

  • {SNA} Analytical Reagents for General Use, Electron Spin Resonance (ESR/EPR) Spectroscopy, Essential Chemicals, Puriss p.a. ACS, Q-S, Puriss p.a. ACS, Research Essentials, Salts, Silver Salts,
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Research Essentials, Salts,

产品应用

  • 用作光度法测定微量砷的显色剂。也用于锑的光度测定。
  • 和Fe2+结合检测大脑、肾、肝和其它组织中的NO，同时直接测量NO和 pO2 ；作为铜的螯合剂，还用于依靠ESR定量分析生物材料里的铜；砷试剂也是超氧化物歧化酶, 抗坏血酸氧化酶和其它酶的抑制剂。抑制巨噬细胞NO合成酶

相关文献及参考

  • Beilstein:4,121

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P317
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Hazard Codes Xi

其他信息

  • 对湿空气和光敏感。不溶于水。易溶于吡啶和三氯甲烷，难溶于乙醇、丙醇和苯。在一定条件下，与砷化氢反应形成红色产物。
  • 用途二:用作光度法测定微量砷的显色剂。也用于锑的光度测定。和Fe2+结合检测大脑、肾、肝和其它组织中的NO，同时直接测量NO和 pO2 ；作为铜的螯合剂，还用于依靠ESR定量分析生物材料里的铜；砷试剂也是超氧化物歧化酶, 抗坏血酸氧化酶和其它酶的抑制剂。抑制巨噬细胞NO合成酶
  • F:8
  • Acros Organics:二乙基二硫代氨基甲酸银 Diethyldithiocarbamic acid, silver salt, p.a., 99%(1470-61-7)
  • MOL 文件:1470-61-7.mol
  • Sigma Aldrich:1470-61-7(sigmaaldrich)
  • 用途一:用作测砷试剂
  • 二乙基二硫代氨基甲酸银价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30058362 二乙基二硫代氨基甲酸银盐;二乙氨基二硫代甲酸银; 砷试剂 5g 30元 2011/08/23 30058363 二乙基二硫代氨基甲酸银盐;二乙氨基二硫代甲酸银; 砷试剂 5g 30元 2011/08/23 30058361 二乙基二硫代氨基甲酸银盐;二乙氨基二硫代甲酸银; 砷试剂 5g 46元
  • TCI Shanghai:二乙基二硫代氨基甲酸银[用于分析砷] Silver N,N-Diethyldithiocarbamate [for As analysis],>;98.0%(T)(1470-61-7)
  • 外观性质:浅黄色结晶性粉末。对湿空气和光敏感。不溶于水。易溶于吡啶和三氯甲烷，难溶于乙醇、丙醇和苯。在一定条件下，与砷化氢反应形成红色产物。熔点：172-175℃
  • Alfa Aesar:二乙基二硫代氨基甲酸银,ACS Silver diethyldithiocarbamate, ACS(1470-61-7)
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Silver 银
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. ACS Grade - Inorganic Salts, Solutions and Reagents
  1. Life Science 生命科学
  2. Hematology and Histology 血液学和组织学
  3. Stains and Dyes - Hematology and Histology
  4. Stains & Dyes, A to Z - Stains and Dyes
  5. S - Stains & Dyes, A to Z
  1. Analytical & Chromatography 分析化学与色谱
  2. Routine Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Selenium
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Functional Group 官能团索引
  2. thiocarbamic acid