3-Bromofuran 3-溴呋喃
CAS 22037-28-1 MFCD00005347
化学结构图
SMILES: BrC1CCOC1
化学属性
| Mol. Formula | C4H3BrO |
|---|---|
| Mol. Weight | 147 |
| Refractive index | 1.4950 to 1.4990 |
| Boiling Point | 103 |
| Density | 1.635 |
| Flash Point | 3°C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | 3-Bromofuran |
|---|---|
| CAS Number | 22037-28-1 |
| Synonym | Furan, 3-bromo- 3-furyl bromide 3-Bromfuran 3-bromofuran 3-溴呋喃 3-Furyl bromide 3-bromo-furan ?-Bromofuran |
| PubChem Substance ID | 87565021 |
| EC Number | 244-744-6 |
| Beilstein Registry Number | 105337 |
| MDL Number | MFCD00005347 |
| Reaxys-RN | 105337 |
| Alfabeta Name | BROMOFURAN 3- |
| Chemical Name Translation | 3-溴呋喃 |
| LabNetwork Molecule ID | LN00009409 |
| InChIKey | LXWLEQZDXOQZGW-UHFFFAOYSA-N |
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
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分类
- {SNA} Building Blocks, C4 to C7, Chemical Synthesis, Furans, Halogenated Heterocycles, Heterocyclic Building Blocks
- Heterocycles
- Pharmaceuticals
- Intermediates & Fine Chemicals
- {uni_hamburg} no charge; oxygen heterocycle; aromatic; 5ring; ether; 1fragment
- Aromatics
产品应用
- 3-Bromofuran is heterocyclic building block used in organic synthesis. 3-Bromofuran is one of the volatile metabolites discussed in studies for detecting and discriminating diseases of onion.
相关文献及参考
- Short: II/25C
- Precursor of 3-lithiofuran by treatment with n-BuLi at low temperatures. Isomerization to 2-lithiofuran tends to occur above -40o: Tetrahedron, 46, 1199 (1990). With LDA at -78o, selective 2-lithiation can be achieved to give 3-bromo-2-lithiofuran, which has been used in synthesis of phenethylthiazolylthiourea (PETT) analogues as potential HIV-1 reverse transcriptase inhibitors: J. Med. Chem., 39, 4261 (1996).
- Short: III/38B
- Short: II/14a
- Prithiviraj, B. et al.: Eur. J. Plant Pathol., 110, 371 (2004);
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P303+P361+P353
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R11 Highly flammable 非常易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
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