4-(2-Aminoethyl)morpholine N-(2-氨基乙基)吗啉

CAS 2038-03-1 MFCD00006182

化学结构图

2038-03-1
SMILES: NCCN1CCOCC1

化学属性

Mol. FormulaC6H14N2O
Mol. Weight130.19
Density0.992
Refractive indexn20/D 1.476(lit.)
Flash Point76.3°C
TSCAYes
Boiling Point202.6°C at 760 mmHg
Melting Point24°C
Solubility可溶
pH:A

别名和识别编码

Chemical Name4-(2-Aminoethyl)morpholine
Synonym 2-Morpholinoethanamine {LY} 2-Morpholinoethanamine {} {LY} 2-Morpholinoethanamine {} {} {LY} 2-Morpholinoethanamine {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Morpholinoethanamine {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00006182
CAS Number2038-03-1
EC Number218-011-6
Beilstein Registry Number104378
PubChem Substance ID87562393
Reaxys-RN104378
Chemical Name TranslationN-(2-氨基乙基)吗啉
InChIKeyRWIVICVCHVMHMU-UHFFFAOYSA-N
Wiswesser Line NotationT6N DOTJ A2Z
LabNetwork Molecule IDLN00227212
InChIInChI=1S/C6H14N2O/c7-1-2-8-3-5-9-6-4-8/h1-7H2
Canonical SMILESNCCN1CCOCC1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; nitrogen heterocycle; alicycle; 6RingOnly; 6ring; ether; 1fragment
  • {SNA} Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines

产品应用

  • 有机合成中间体。

相关文献及参考

  • Short: EINECS
  • Beilstein: 27,IV,370
  • Short: III/38B

安全信息

Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R22 Harmful if swallowed 吞咽有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P303+P361+P353
  • P301+P330+P331
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P304+P340+P310
  • P301+P330+P331+P310
  • P305+P351+P338+P310
RTECSQD7350000
Packing GroupIII
UN Number UN 2735 8/PG 2 2923
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H303 May be harmfully swallowed 吞食可能有害
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes C C,T T;C
Hazard Class8/6.1
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2145 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 109,108,1957

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 300 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 26,269,1944

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 26,269,1944

其他信息

  • MOL 文件:2038-03-1.mol
  • 溶于水。
  • 图谱信息:N-(2-氨基乙基)吗啉(2038-03-1)红外图谱(IR1) N-(2-氨基乙基)吗啉(2038-03-1)核磁图( 13 CNMR) N-(2-氨基乙基)吗啉(2038-03-1)质谱(MS) N-(2-氨基乙基)吗啉(2038-03-1)红外图谱(IR2) N-(2-氨基乙基)吗啉(2038-03-1)核磁图( 1 HNMR)
  • 刺激数据:皮肤-兔子 10 毫克/24小时 中度; 眼睛-兔子 0.05 毫克/24小时 重度
  • 毒性分级:中毒
  • N-(2-氨基乙基)吗啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0883 4-(2-氨乙基)吗啉 4-(2-Aminoethyl)morpholine 25ML 384元 2014/06/02 A0883 4-(2-氨乙基)吗啉 4-(2-Aminoethyl)morpholine 500ML 2760元 2010/06/21 400751000 N-(2-氨基乙基)吗啉 4-(2-Aminoethyl)morpholine 99% 100 GR 1522元
  • Sigma Aldrich:2038-03-1(sigmaaldrich)
  • 类别:易燃液体
  • 急性毒性:口服-大鼠LD50:3000 毫克/公斤; 皮下-小鼠 LD50: 2145 毫克/公斤
  • Hazard Note:Toxic
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • Acros Organics:4-(2-氨乙基)吗啉 4-(2-Aminoethyl)morpholine, 99%(2038-03-1)
  • MSDS 信息:N-氨乙基吗啉(2038-03-1).msds
  • 储运特性:库房通风低温干燥
  • Alfa Aesar:4-(2-胺乙基)吗啉,98+% 4-(2-Aminoethyl)morpholine, 98+%(2038-03-1)
  • 可燃性危险特性:遇热, 火焰或强氧化剂易燃;燃烧产生有毒氮氧化物烟雾
  • 外观性质:无色液体或白色固体。
  • TCI Shanghai:N-(2-氨乙基)吗啉 4-(2-Aminoethyl)morpholine,>;97.0%(GC)(2038-03-1)

系列性分类


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