3-Bromoquinoline 3-溴喹啉

CAS 5332-24-1 MFCD00006767

化学结构图

5332-24-1
SMILES: Brc1cnc2ccccc2c1

化学属性

Mol. FormulaC9H6BrN
Mol. Weight208.05
Refractive index1.6630 to 1.6660
Boiling Point275.7°C at 760 mmHg
Density1.533
Melting Point13-15°C
Flash Point110°C
TSCAYes
pH:A

别名和识别编码

Chemical Name3-Bromoquinoline
CAS Number5332-24-1
Synonym 3-Bromoquinoline {LY} 3-Bromoquinoline {} {LY} 3-Bromoquinoline {} {} {LY} 3-Bromoquinoline {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromoquinoline {} {} {} {} {} {} {} {} {}
PubChem Substance ID21413
EC Number226-237-1
Beilstein Registry Number112939
MDL NumberMFCD00006767
Reaxys-RN112939
Chemical Name Translation3-溴喹啉
InChIKeyZGIKWINFUGEQEO-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008075
InChIInChI=1S/C9H6BrN/c10-8-5-7-3-1-2-4-9(7)11-6-8/h1-6H
Canonical SMILESBrC1=CC2=CC=CC=C2N=C1
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分类

  • {uni_hamburg} no charge; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 1fragment
  • Building Blocks, C8 to C10, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Quinolines
  • {SNA} Building Blocks, C8 to C10, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Quinolines

相关文献及参考

  • Short: EINECS
  • Beilstein:20,363
  • Short: III/20b
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 3-溴喹啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010192 3-溴喹啉 5g 300元 2011/04/16 B1013 3-溴喹啉 3-Bromoquinoline 500G 8920元 2011/04/16 B1013 3-溴喹啉 3-Bromoquinoline 25G 895元
  • MOL 文件:5332-24-1.mol
  • 用途和制备方法:3-溴喹啉与混酸作用生成3-溴-5-硝基喹啉，与高锰酸钾加热被氧化为5-溴-2，3-吡啶二甲酸。 6-溴喹啉与硝酸加热生成6-溴-8-硝基喹啉，与高锰酸钾作用被氧化为2，3- 吡啶二甲酸。 由2-羟基喹啉与五溴化磷作用制得2-溴喹啉。 由喹啉过溴化物于180℃加热制得3-溴喹啉。 由4-羟基喹啉与五溴化磷加热，或由4-氨基喹啉经重氮化反应制得4-溴喹啉。 5-溴喹啉由间溴苯胺、甘油、间溴硝基苯及浓硫酸加热，或由5-氨基喹啉经重氮化反应制取。 由对溴苯胺与甘油、浓硫酸、对溴硝基苯加热制得6-溴喹啉。 由7-氨基喹啉经重氮化反应制得7-溴喹啉。 8-溴喹啉由邻溴苯胺、甘油、浓硫酸及邻溴硝基苯加热制得。 用途：作有机合成试剂。
  • MSDS 信息:3-Bromoquinoline(5332-24-1).msds
  • TCI Shanghai:3-溴喹啉 3-Bromoquinoline,>;98.0%(GC)(T)(5332-24-1)
  • Alfa Aesar:3-溴喹啉,98% 3-Bromoquinoline, 98%(5332-24-1)
  • 用途一:用于制药
  • Sigma Aldrich:5332-24-1(sigmaaldrich)
  • 检测方法:GC,NMR
  • 下游产品:5-氨基烟酸 --> 3-喹啉甲醛 --> 喹啉-3-硼酸 --> 3-氨基喹啉 --> 3-溴喹啉-8-磺酸
  • 图谱信息:3-溴喹啉(5332-24-1)核磁图( 13 CNMR) 3-溴喹啉(5332-24-1)核磁图( 1 HNMR) 3-溴喹啉(5332-24-1)质谱(MS) 3-溴喹啉(5332-24-1)红外图谱(IR1)
  • Acros Organics:3-溴喹啉 3-Bromoquinoline, 98%(5332-24-1)
  • 溴喹啉:有七种位置异构体，其主要物性列表如下： 名称 熔点(℃) 沸点(℃) 溶解性 2-溴喹啉 48～49 溶于乙醚、氯仿、苯 3-溴喹啉 12～15 274～276、 95(66.66Pa) 4-溴喹啉 29～30 270(分解) 易溶于稀酸 5-溴喹啉 52(针状晶体) 280 　 6-溴喹啉 24 278 7-溴喹啉 52(针状晶体) 290 8-溴喹啉 80 165～166 (2399.79Pa)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Isoquinolines 异喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinaldines 奎纳丁
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinazolines 喹唑啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinolines 喹啉
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Quinolines 喹啉
  5. C8 to C10 - Quinolines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Quinolines - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Quinazolines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quinolines 喹啉