1,1,2,2,3,3,4,4,4-Nonafluorobutane-1-sulfonyl fluoride 全氟丁基磺酰氟

CAS 375-72-4 MFCD00007422

化学结构图

375-72-4
SMILES: O=S(=O)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

化学属性

Mol. FormulaC4F10O2S
Mol. Weight302.09
Density1.682
Boiling Point185.4°C at 760 mmHg
Refractive indexn20/D 1.3(lit.)
Flash Point77.9°C
TSCAYes
Melting Point-110 °C
Stability对湿度敏感
Appearance 无色透明液体。

别名和识别编码

Chemical Name1,1,2,2,3,3,4,4,4-Nonafluorobutane-1-sulfonyl fluoride
CAS Number375-72-4
EC Number206-792-6
Beilstein Registry Number1813589
MDL NumberMFCD00007422
PubChem Substance ID67814
Synonym Perfluorobutylsulfonyl fluoride {LY} Perfluorobutylsulfonyl fluoride {} {LY} Perfluorobutylsulfonyl fluoride {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation全氟丁基磺酰氟
Reaxys-RN1813589
InChIKeyLUYQYZLEHLTPBH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00225116
InChIInChI=1S/C4F10O2S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16
Canonical SMILESO=S(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)(F)=O
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分类

  • {SNA} Building Blocks, Chemical Synthesis, F-Tagged, Fluorinated Building Blocks, Mono-Functionalized Sulfonyl Fluorides, Organic Building Blocks, Organic Fluorinated Building Blocks, SuFEx: The Next Click Reaction, Sulfonyl Halides, Sulfur Compounds
  • {SNA} Building Blocks, Chemical Synthesis, F-Tagged, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Sulfonyl Fluorides, Sulfonyl Halides, Sulfur Compounds
  • {SNA} Building Blocks, Building Blocks for SuFEx: The Next Click Reaction, Chemical Synthesis, F-Tagged, Fluorinated Building Blocks,
  • {SNA} Building Blocks, B

相关文献及参考

  • Nonaflates of phenols, which are stable to flash chromatography, are attractive precursors for coupling reactions, with alkyl- and arylzinc halides, arylboronic acids (Suzuki) and arylstannanes (Stille), catalyzed by Pd(0) under mild conditions: J. Org. Chem., 63, 203 (1998). Silyl enol ethers, with catalytic TBAF in the presence of molecular sieves, are converted to enol nonaflates which undergo Heck couplings, e.g with styrenes to give 1,3-dienes: Synlett, 1141 (1997).
  • Reagent for formation of nonafluorobutanesulfonates (nonaflates) of OH groups (compare Trifluoromethanesulfonic anhydride, A11767), e.g. with triethylamine in ether: Synthesis, 293 (1973); Liebigs Ann. Chem., 20 (1973).

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Packing GroupII
UN Number 3265 UN 3265 8/PG 2 UN3265
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes 8 C
Hazard Class8

其他信息

  • MSDS 信息:Nonafluorobutanesulfonyl fluoride(375-72-4).msds
  • 图谱信息:全氟丁基磺酰氟(375-72-4)质谱(MS) 全氟丁基磺酰氟(375-72-4)红外图谱(IR1)
  • Acros Organics:全氟丁烷磺酰氟 Perfluoro-1-butanesulfonyl fluoride, 92%(375-72-4)
  • 全氟丁基磺酰氟价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1098 全氟丁烷磺酰氟 Perfluorobutanesulfonyl Fluoride 250G 4950元 2014/06/02 P1098 全氟丁烷磺酰氟 Perfluorobutanesulfonyl Fluoride 25G 826元 2010/06/21 312341000 全氟丁基磺酰氟 Perfluoro-1-butanesulfonyl fluoride 92% 100 GR 2202元
  • Alfa Aesar:九氟丁烷磺酰氟,90+% Nonafluorobutanesulfonyl fluoride, 90+%(375-72-4)
  • Sigma Aldrich:375-72-4(sigmaaldrich)
  • TCI Shanghai:全氟丁烷磺酰氟 Perfluorobutanesulfonyl Fluoride,>;90.0%(GC)(375-72-4)
  • MOL 文件:375-72-4.mol
  • 用途二:用于合成氟碳表面活性剂、含氟农药、染料、聚碳酸酯加工处理分散剂等
  • F:10-21
  • 用途一:用来合成多种含氟特种表面活性剂
  • Hazard Note:Corrosive
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonium/Sulfoxonium Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Functional Group 官能团索引
  2. orthocarboxylic acid derivative
  1. sulfonyl halide