Benzophenone hydrazone 二苯基甲酮腙

CAS 5350-57-2 MFCD00007624

化学结构图

5350-57-2
SMILES: NN=C(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC13H12N2
Mol. Weight196.25
Boiling Point225-230°C at 55 mmHg
Melting Point95-99°C
Density1.1
Flash Point146°C
TSCAYes
Appearance 白色结晶粉末
Danger-Level乙类

别名和识别编码

Chemical NameBenzophenone hydrazone
Synonym (Diphenylmethylene)hydrazine {LY} (Diphenylmethylene)hydrazine {} {LY} (Diphenylmethylene)hydrazine {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Diphenylmethylene)hydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Dip
Beilstein Registry Number1910177
PubChem Substance ID79304
CAS Number5350-57-2
EC Number226-321-8
MDL NumberMFCD00007624
Reaxys-RN1910177
Chemical Name Translation二苯基甲酮腙
InChIKeyQYCSNMDOZNUZIT-UHFFFAOYSA-N
LabNetwork Molecule IDLN00227009
InChIInChI=1S/C13H12N2/c14-15-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,14H2
Canonical SMILESN/N=C(C1=CC=CC=C1)/C2=CC=CC=C2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Hydrazones, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 用于有机合成

相关文献及参考

  • Short: III/20a
  • Short: IV/1a
  • Oxidation with e.g. HgO: Org. Synth. Coll., 3, 351 (1955), peracetic acid and tetramethylguanidine: J. Chem. Soc., Perkin 1, 2030 (1975), iodosobenzene diacetate: Synthesis, 513 (1985) or potassium monopersulfate: Tetrahedron Lett., 38, 1239 (1997), gives diphenyldiazomethane, a reagent for the protection of carboxylic acids by conversion to their benzhydryl esters. The protecting group can be cleaved by hydrogenolysis: Helv. Chim. Acta, 31, 439 (1938), or mild acid: J. Am. Chem. Soc., 87, 3969, 5469 (1965). See Appendix 6.
  • Beilstein:7,417

安全信息

WGK Germany3
RTECSPC4954487
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
UN Number UN2811
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R51/53
  • R25 Toxic if swallowed 吞咽有毒
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Signal word Warning
GHS Symbol
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
Packing GroupIII
Hazard Class6.1
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 上游原料:硫酸 --> 水合肼 --> 水合肼 --> 肼(无水) --> 二苯甲酮
  • 方法一:将二苯甲酮的无水乙醇溶液与无水肼回流反应10h,冷却析出二苯甲酮腙,产率87%。
  • Sigma Aldrich:5350-57-2(sigmaaldrich)
  • 用途二:用于有机合成。
  • 二苯甲酮腙价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1163 二苯甲酮腙 Benzophenone Hydrazone 500G 1410元 2014/06/02 B1163 二苯甲酮腙 Benzophenone Hydrazone 25G 195元 2010/06/21 105570050 二苯甲酮腙 Benzophenone hydrazone 98+% 5 GR 286元
  • MOL 文件:5350-57-2.mol
  • Acros Organics:二苯甲酮腙 Benzophenone hydrazone, 98+%(5350-57-2)
  • 下游产品:哒螨灵 --> N-乙酰对氨基酚 --> 1,1-二甲基肼 --> 碱性黄24 --> 3-甲基-2-苯并噻唑啉酮腙盐酸盐 --> 二苯基重氮甲烷 --> 吡唑硫磷 --> 二苯乙烯酮
  • TCI Shanghai:二苯甲酮腙 Benzophenone Hydrazone,>;96.0%(T)(5350-57-2)
  • 用途一:用作有机颜料、医药中间体
  • MSDS 信息:Benzophenone hydrazone(5350-57-2).msds
  • Alfa Aesar:二苯甲酮腙,98+% Benzophenone hydrazone, 98+%(5350-57-2)
  • 海关编码:29280090

系列性分类


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