4-Amino-2,6-dichlorophenol 4-氨基-2,6-二氯苯酚

CAS 5930-28-9 MFCD00007875

化学结构图

5930-28-9
SMILES: Nc1cc(Cl)c(O)c(Cl)c1

化学属性

Mol. FormulaC6H5Cl2NO
Mol. Weight178.01
Melting Point164-168°C
TSCAYes
Density1.56
Appearance 本品为无色固体，m.p.167～170℃，不溶于水，溶于苯、甲苯等溶剂。
Boiling Point303.6°C at 760 mmHg

别名和识别编码

Chemical Name4-Amino-2,6-dichlorophenol2,6-二氯-4-氨基苯酚
MDL NumberMFCD00007875
PubChem Substance ID80037
CAS Number5930-28-9
EC Number227-671-4
Beilstein Registry Number13,512
Reaxys-RN2361665
Synonym 4-Amino-2,6-dichlorophenol {LY} 4-Amino-2,6-dichlorophenol 4-amino-2,6-dichlorophenol {} {LY} 4-Amino-2,6-dichlorophenol {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-2,6-dichlorophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation4-氨基-2,6-二氯苯酚
LabNetwork Molecule IDLN00224742
InChIInChI=1S/C6H5Cl2NO/c7-4-1-3(9)2-5(8)6(4)10/h1-2,10H,9H2
Canonical SMILESOC1=C(Cl)C=C(N)C=C1Cl
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分类

  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {Chemicalbook} 农药中间体: 杀虫剂中间体: 苯甲酰脲类杀虫剂

产品应用

  • 农药、染料、医药中间体。

相关文献及参考

  • Short: EINECS
  • Beilstein:13,512
  • Short: III/20b

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
RTECSSJ5774500
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 用途三:农药、染料、医药中间体。
  • MSDS 信息:4-Amino-2,6-dichlorophenol(5930-28-9).msds
  • TCI Shanghai:2,6-二氯-4-氨基苯酚 4-Amino-2,6-dichlorophenol,>;97.0%(T)(5930-28-9)
  • 用途二:2，6-二氯-4-氨基苯酚又名 3，5-二氯-4-羟基苯胺，用于合成氟铃脲的中间体 3，5-二氯-4-(1，1，2，2-四氟乙氧基) 苯胺，或合成氟啶脲的中间体 4-(3-氯-5-三氟甲基吡啶-2-氧基)-3，5-二氯苯胺。
  • 下游产品:3,5-二氯-4-(1,1,2,2-四氟乙氧基)苯胺
  • 2,6-二氯-4-氨基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0878 4-氨基-2,6-二氯苯酚 4-Amino-2,6-dichlorophenol 25G 656元 2010/06/21 103481000 2,6-二氯-4-氨基苯酚 4-Amino-2,6-dichlorophenol 98% 100 GR 2294元 2010/06/21 103480250 2,6-二氯-4-氨基苯酚 4-Amino-2,6-dichlorophenol 98% 25 GR 702元
  • 用途一:用作农药氟铃脲中间体
  • Alfa Aesar:4-氨基-2,6-二氯苯酚,97% 4-Amino-2,6-dichlorophenol, 97%(5930-28-9)
  • MOL 文件:5930-28-9.mol
  • Acros Organics:4-氨基-2,6-二氯苯酚 4-Amino-2,6-dichlorophenol, 98%(5930-28-9)
  • 上游原料:二乙二醇 --> 2,6-二氯-4-硝基苯酚
  • 方法一:其制备方法是用 2，6-二氯对硝基苯酚在钯/碳存在下，以二甘醇甲醚为溶剂，可得到高产率的产品。反应方程式如图：
  • Sigma Aldrich:5930-28-9(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Phenols 酚类
  6. C6 to C8 - Phenols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers

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