2,2,2-Trifluoroethylamine 2,2,2-三氟乙基胺

CAS 753-90-2 MFCD00008132

化学结构图

753-90-2
SMILES: NCC(F)(F)F

化学属性

Mol. FormulaC2H4F3N
Mol. Weight99
Boiling Point37°C
TSCAT
Density1.26
Refractive index1.3000 to 1.3020
Flash Point-17°C(lit.)
Vapor Pressure~7.6 psi ( 20 °C)
Appearance 无色透明液体，密度 1.24，沸点 37-38℃，折射率 1.3-1.302，闪点 -16℃

别名和识别编码

Chemical Name2,2,2-Trifluoroethylamine
CAS Number753-90-2
Alfabeta NameTRIFLUOROETHYLAMINE 222-,,
MDL NumberMFCD00008132
Synonym 1-trifluoro-2-amino-ethane 2,2,2-TRIFLUOROETHANAMINE 2,2,2-TRIFLUOROETHYLAMINE 2,2,2-Trifluoro-1-ethanamine 2,2,2-Trifluoroethanamine 2,2,2-Trifluoroethyl amine 2,2,2-Trifluoroethylamine, 99.50% 2,2,2-Trifluoroethylamine99% 2,2,2-trifluoro-ethanamin 2,2,2-trifluoro-ethylamine 2,2,2-trifluoroethylamine 2,2,2-三氟乙胺 2-氨基-1,1,1-三氟乙烷 2，2，2-三氟乙基胺 AURORA KA-7828 CF3CH2NH2 Ethanamine, 2,2,2-trifluoro- RARECHEM AL BW 0451 Trifluoroethylamine beta,beta,beta-Trifluoroethylamine trifluoroethylamine 三氟乙胺
EC Number212-041-3
Beilstein Registry Number1733204
PubChem Substance ID9773
Reaxys-RN1733204
Chemical Name Translation2,2,2-三氟乙基胺
InChIKeyKIPSRYDSZQRPEA-UHFFFAOYSA-N
Wiswesser Line NotationZ1XFFF
LabNetwork Molecule IDLN00008843
InChIInChI=1S/C2H4F3N/c3-2(4,5)1-6/h1,6H2
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分类

  • {SNA} Amines, Building Blocks, C2 to C5, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/24C
  • Highly effective catalyst for the isomerization of ß-unsaturated ketones to ɑß-unsaturated ketones: J. Am. Chem. Soc., 97, 952 (1975).
  • Beilstein: 4,IV,442
  • Short: II/24B

安全信息

Warnings IRRITANT-HARMFUL, FLAMMABLE, CORROSIVE
Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
  • R52/53
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSKS0175000
Packing GroupII
UN Number UN 2733 3/PG 2 UN2733 2733
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Hazard Codes F,C
Storage condition 0-10 0-10°C 2-8°C
Hazard Class3/8 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4170 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,606,1986

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >250 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 2,184,1950

其他信息

  • 上游原料:氢氧化钠 --> 盐酸 --> 乙醚 --> 氢化铝锂 --> 2,2,2-三氟乙酰胺
  • 检测方法:GC
  • F:3-10-13
  • TSCA:T
  • TCI Shanghai:2,2,2-三氟乙胺 2,2,2-Trifluoroethylamine,>;97.0%(GC)(753-90-2)
  • Acros Organics:2,2,2-三氟乙胺 2,2,2-Trifluoroethylamine, 99.50%(753-90-2)
  • Alfa Aesar:2,2,2-三氟乙胺,98% 2,2,2-Trifluoroethylamine, 98%(753-90-2)
  • 蒸气压:~7.6 psi ( 20 °C)
  • Hazard Note:Corrosive/Toxic/Flammable
  • MOL 文件:753-90-2.mol
  • 存储注意事项:氮气保护
  • Sigma Aldrich:753-90-2(sigmaaldrich)
  • 2，2，2-三氟乙基胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1169 2,2,2-三氟乙胺 2,2,2-Trifluoroethylamine 25G 3700元 2014/06/02 T1169 2,2,2-三氟乙胺 2,2,2-Trifluoroethylamine 5G 1130元 2010/06/21 303500500 2，2，2-三氟乙基胺 2,2,2-Trifluoroethylamine 99.5% 50 GR 11188元

系列性分类

  1. C2 to C5 - Amines
  1. C10 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C11 to C38