N,N-Di(2-Aminoethyl)Ethylenediamine 三乙烯四胺
CAS 112-24-3 MFCD00008169
化学结构图
SMILES: NCCNCCNCCN
化学属性
| Mol. Formula | C6H18N4 |
|---|---|
| Mol. Weight | 146 |
| Refractive index | 1.4950 to 1.5010 |
| Boiling Point | 266-267 |
| Density | 0.982 |
| Melting Point | 12 |
| Flash Point | 143°C(lit.) |
| TSCA | Yes |
| Vapor Density | ~5 (vs air) |
| Vapor Pressure | <;0.01 mmHg ( 20 °C) |
| Solubility | 与水混溶，微溶于乙醚，溶于乙醇。 |
| Stability | 对湿度敏感 |
| pH | :A |
别名和识别编码
| Chemical Name | N,N-Di(2-Aminoethyl)Ethylenediamine |
|---|---|
| Synonym | 1,2 1,2-Ethanediamine, N,N'-bis(2-aminoethyl)- 1,4,7,10-Tetraazadecane 1,8-Diamino-3,6-diazaoctane 1,8-di 3,6-Diazaoctane-1,8-diamine 3,6-diazaoctamethylenediamine Araldite hardener HY 951 DEH 24 DEH 24 EPH 925 EPH 925 HY 951 LABOTEST-BB N,N'-Bis(2-aminoethyl)-1,2-ethanediamine N,N'-Bis(2-aminoethyl)ethylenediamine N,N'-Di(2-aminoethy N,N'-Di(2-aminoethyl)ethylenediamine N′-双(2-氨乙基地)亚乙基二胺,三乙四胺 N′-双(2-氨乙基地)亚乙基二胺; DEH 24; EPH 925 RT 1AX Trien Triäthylentetramin aralditehardenerhy951 trientine (INN) {} {} {Chemi {} {} {Chemicalb {} {} {un 三乙烯四胺, TECH. 60%, BALANCE BRANCHED AND CYCLIC TRIETHY 三乙烯四胺（TETA） 而缩三乙二胺 |
| CAS Number | 112-24-3 |
| PubChem Substance ID | 5565 |
| EC Number | 203-950-6 |
| Beilstein Registry Number | 605448 |
| MDL Number | MFCD00008169 |
| Reaxys-RN | 605448 |
| Merck Number | 9663 |
| Chemical Name Translation | 三乙烯四胺 |
| Wiswesser Line Notation | Z2M2M2Z |
| LabNetwork Molecule ID | LN00199546 |
| InChI | InChI=1S/C6H18N4/c7-1-3-9-5-6-10-4-2-8/h9-10H,1-8H2 |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
- Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines, T
- {uni_hamburg} no charge; 1fragment
- {SNA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, Nitrogen Compounds,
- {SNA} Bioactive Small Molecules, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines, T, 细胞生物学
产品应用
- 络合剂, 清洁剂, 软化剂, 染料合成, 橡胶促进剂, 气体脱水净化剂。
相关文献及参考
- Merck:14,9663 Beilstein:4,255
- Short: III/35B
- Merck:14,9663
- Short: III/38B
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H312 Harmful in contact with skin 皮肤接触有害
- H303 May be harmfully swallowed 吞食可能有害
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R21 Harmful in contact with skin 与皮肤接触有害
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R52/53
- S1/2 None 上锁保管并避免儿童触及；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 468 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/p
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 5500 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : KHZDAN Khigiena i Zdraveopazvane. Hygiene and Sanitation. (Hemus, Blvd. Russki 6, Sofia, Bulgaria) V.9- 1966- Volume(issue)/page/year: 22,179,1979
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1600 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : KHZDAN Khigiena i Zdraveopazvane. Hygiene and Sanitation. (Hemus, Blvd. Russki 6, Sofia, Bulgaria) V.9- 1966- Volume(issue)/page/year: 22,179,1979
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 350 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique. (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France) V.9- 1974- Volume(issue)/page/year: 19,425,1984
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rode
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 500 nmol/plate REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 88,165,1981
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 1 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 320,31,1994
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 100 ug/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 8(Suppl 7),1,1986
TYPE OF TEST : Unscheduled DNA synthesis TEST SYSTEM : Rodent - rat Liver DOSE/DURATION : 10 ug/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 320,31,1994
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 9130 mg/kg SEX/DURATION : female 1-22 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Specific Developmental Abnormalities - homeostasis Reproductive - Specific Developmental Abnormalities - other developmental abnormalities REFERENCE : LANCAO Lancet. (7 Adam St., London WC2N 6AD, UK) V.1- 1823- Volume(issue)/page/year: 1,1127,1982
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 8715 mg/kg SEX/DURATION : female 1-21 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Specific Developmental Abnormalities - homeostasis REFERENCE : PSEBAA Proceedings of the Society for Experimental Biology and Medicine. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1903/04- Volume(issue)/page/year: 173,598,1983
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 17430 mg/kg SEX/DURATION : female 1-21 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : PSEBAA Proceedings of the Society for Experimental Biology and Medicine. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1903/04- Volume(issue)/page/yea
其他信息
- Acros Organics:Triethylenetetramine, 60%(112-24-3)
- 用途一:用作合成树脂固化剂、添加剂、织物整理剂等
- Triethylenetetramine is a a selective Cu(II) chelator and crosslinker. Trientine is also used as a catalyst for N-terminal peptide bond hydrolysis via chelation between enzyme, substrate, and metal ion.
- 浅黄色粘稠液体，有氨的气味，强碱性，在空气中能吸收二氧化碳，能溶于水、醇和酸。低毒，半数致死量(大鼠，经口)2500mg/kg。有腐蚀性。
- 用途二:用作络合试剂、碱性气体脱水剂、染料中间体、树脂的溶剂和橡胶促进剂
- TCI Shanghai:三亚乙基四胺 Triethylenetetramine,>;70.0%(GC)(112-24-3)
- 上游原料:氢氧化铵 --> 乙二胺 --> 1,2-二氯乙烷 --> 二氯乙烷 --> 二乙烯三胺 --> 多乙烯多胺 --> 四亚乙基五胺
- MOL 文件:112-24-3.mol
- 常规方法:参见“二亚乙基三胺”。
- 三乙烯四胺价格(试剂级):更新日期 产品编号 产品名称 包装 价
- 外观性质:无色或微黄色粘稠液体。
- 用途四:络合剂, 清洁剂, 软化剂, 染料合成, 橡胶促进剂, 气体脱水净化剂。
- 蒸气密度:~5 (vs air)
- MSDS 信息:三乙四胺(112-24-3).msds
- 凝固点:12℃
- 图谱信息:三乙烯四胺(112-24-3)Raman光谱 三乙烯四胺(112-24-3)核磁图( 1 HNMR) 三乙烯四胺(112-24-3)红外图谱(IR1) 三乙烯四胺(112-24-3)核磁图( 13 CNMR)
- 蒸气压:<;0.01 mm Hg ( 20 °C)
- 方法一:其生产方法为二氯乙烷氨化法。将1,2-二氯乙烷和氨水送入管式反应器中于150-250℃温度和392.3kPa压力下进行热压氨化反应。反应液以碱中和，得到混合游离胺，经浓缩同时除去氯化钠，然后将粗品减压蒸馏，截取195-215℃之间的馏分，即得成品。此法同时联产乙二胺、二亚乙基三胺、四亚乙基五胺和多亚乙基多胺，可通过控制精馏塔温度蒸馏胺类混合液，截取不同馏分进行分离而得。
- Sigma Aldrich:112-24-3(sigmaaldrich)
- 下游产品:二乙烯三胺 --> 三乙烯二胺 --> 1,1,4,7,10,10-六甲基三亚乙基四胺 --> 阻垢剂 TETHMP,三乙四胺六甲叉磷酸 --> 盐酸三乙烯四胺
- 敏感性:Moisture Sensitive
- 防护措施:本品为强碱腐蚀性液体。刺激皮肤、粘膜、眼睛和呼吸道，能引起皮肤过敏、支气管哮喘等症状。长期接触会引起白细胞球减少、血压降低、支气管扩张等。每个-CH2NH2的致死量相当于0.5mg/kg。应避免直接与人体接触。溅及皮肤时，迅速用水或硼酸溶液冲洗，再涂以硼酸软膏。发现中毒，应立即脱离现场，呼吸新鲜空气或送医院诊治。
- Alfa Aesar:三乙烯四胺,tech.60%,balancebranchedandcyclictriethylenetetramines Triethylenetetramine, tech. 60%, balance branched and cyclic triethylenetetramines(112-24-3)
- 用途三:除作溶剂外，还用于制造环氧树脂固化剂、橡胶助剂、乳化剂、表面活性剂、润滑油添加剂、燃料油清净分散剂、气体净化剂、无氰电镀扩散剂、光亮剂、去垢剂、软化剂、金属螯合剂以及合成聚酰胺树脂和离子交换树脂等。
- 海关编码:29212900
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