Zirconium N-Propoxide 正丙醇锆

CAS 23519-77-9 MFCD00015307

化学结构图

23519-77-9
SMILES: CCCO[Zr](OCCC)(OCCC)OCCC

化学属性

Mol. FormulaC12H28O4Zr
Mol. Weight327.58
Refractive indexn20/D 1.451
Boiling Point208 °C/0.1 mmHg
Density1.044 g/mL at 25 °C
Flash Point28°C(lit.)
TSCAYes
SolubilityHydrolyzes in water
Stability对湿度敏感
Appearance yellow liq.

别名和识别编码

Chemical NameZirconium N-Propoxide
Synonym 四丙醇锆盐 正丙醇锆 溶液 四正丙基锆酸酯 丙醇锆(IV) (约70%的1-丁醇溶液) Tetra-n-propyl zirconate
CAS Number23519-77-9
PubChem Substance ID87561339
Beilstein Registry Number3679533
MDL NumberMFCD00015307
Reaxys-RN3935210
EC Number245-711-9
Chemical Name Translation正丙醇锆
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Zirconium
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Solution Deposition Precursors, Zirconium, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors, Zirconium

产品应用

  • 常用于制备氧化锆(ZrO2)的前体。

相关文献及参考

  • Beilstein: 1,IV,1420
  • 2. Heine, M.C.; et al. Com. Flame 144 (4) , 809-820, (2006)

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P308+P313
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P303+P361+P353
  • P403+P233
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P304+P340
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310+P331
  • P304+P340+P312
Signal word Danger {} {} {} {} {TCI}
UN Number UN1274 1274 UN1993
Risk Statements
  • R10 Flammable 易燃
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Storage condition Moisture Sensitive 对湿度敏感,密封保存。 充氩保存
Packing GroupIII
Hazard Class3

系列性分类


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