N,N’-Dimethylethylenediamine N,N’-二甲基乙二胺

CAS 110-70-3 MFCD00008290

化学结构图

110-70-3
SMILES: CNCCNC

化学属性

Mol. FormulaC4H12N2
Mol. Weight88.15
Refractive index1.4270 to 1.4310
Boiling Point120°C at 760 mmHg
Density0.819
Flash Point26°C
TSCAYes
Melting Point1.63 °C

别名和识别编码

Chemical NameN,N’-Dimethylethylenediamine
CAS Number110-70-3
Alfabeta NameDIMETHYLETHYLENEDIAMINE NN-,'
MDL NumberMFCD00008290
Synonym N,N'-Dimethylethylenediamine {LY} N,N'-Dimethylethylenediamine {} {LY} N,N'-Dimethylethylenediamine {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID8070
EC Number203-793-3
Beilstein Registry Number878142
Reaxys-RN878142
Chemical Name TranslationN,N’-二甲基乙二胺
Wiswesser Line Notation1M2M1
LabNetwork Molecule IDLN00110554
InChIKeyKVKFRMCSXWQSNT-UHFFFAOYSA-N
InChIInChI=1S/C4H12N2/c1-5-3-4-6-2/h5-6H,3-4H2,1-2H3
Canonical SMILESCNCCNC
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines

相关文献及参考

  • Reagent for protection of aldehyde groups as 2-substituted-1,3-dimethylimidazolidines, e.g. by azeotropic dehydration with benzene. The derivatives are stable to n-BuLi and LDA, and can be cleaved by acid hydrolysis, or in high yield by quaternization with MeI and mild hydrolysis: Tetrahedron, 41, 3803 (1985). With aromatic aldehydes, the imidazolidine derivatives are activated to ortho-lithiation, providing a route to o-substituted benzaldehydes: J. Org. Chem., 44, 2004 (1979).
  • Short: EINECS
  • Beilstein:4,250
  • Short: III/38B

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
RTECSKV4250000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2734 UN 2734 8/PG 2
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive Flammables area {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing GroupII
Hazard Class8/3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique.
   (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France)
   V.9-    1974-  Volume(issue)/page/year: 17,235,1982

其他信息

  • 用途二:N,N'-二甲基乙二胺(110-70-3)用于生产头孢替安的中间体1-(2-二甲基氨基乙基)-5-巯基四唑。以甲基丙烯酸甲酯和N,N-二甲基乙二胺(110-70-3)为主要原料、二月桂酸二丁基锡为催化剂,合成了一种新型功能单体甲基丙烯酰胺乙基二甲基胺。同时也是合成萘酚萘磺酸酯的原料药。
  • 检测方法:GC
  • MOL 文件:110-70-3.mol
  • 下游产品:2-甲酰基-呋喃-2-甲酸
  • 图谱信息:N,N'-二甲基乙二胺(110-70-3)核磁图( 1 HNMR) N,N'-二甲基乙二胺(110-70-3)核磁图( 13 CNMR) N,N'-二甲基乙二胺(110-70-3)质谱(MS) N,N'-二甲基乙二胺(110-70-3)红外图谱(IR1)
  • MSDS 信息:N,N'-Dimethyl-1,2-ethanediamine(110-70-3).msds
  • TCI Shanghai:N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine,>;97.0%(GC)(T)(110-70-3)
  • 微溶于水,溶于有机溶剂。
  • Alfa Aesar:N,N'-二甲基乙二胺,95% N,N'-Dimethylethylenediamine, 95%(110-70-3)
  • Acros Organics:N,N'-二甲基乙烯基二胺 N,N'-Dimethylethylenediamine, tech., 85%(110-70-3)
  • N,N'-二甲基乙二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0720 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine 5ML 370元 2014/06/02 D0720 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine 25ML 1130元 2010/06/21 116191000 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine , tech., 85% 100 GR 2633元
  • 存储注意事项:氮气保护
  • 外观:无色透明液体
  • 用途一:用于有机合成或用作医药中间体
  • Sigma Aldrich:110-70-3(sigmaaldrich)

系列性分类


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