N,N’-Dimethylethylenediamine N,N’-二甲基乙二胺

CAS 110-70-3 MFCD00008290

化学结构图

110-70-3
SMILES: CNCCNC

化学属性

Mol. FormulaC4H12N2
Mol. Weight88.15
Refractive index1.4270 to 1.4310
Boiling Point120°C at 760 mmHg
Density0.819
Flash Point26°C
TSCAYes
Melting Point1.63 °C

别名和识别编码

Chemical NameN,N’-Dimethylethylenediamine
CAS Number110-70-3
Alfabeta NameDIMETHYLETHYLENEDIAMINE NN-,'
MDL NumberMFCD00008290
Synonym N,N'-Dimethylethylenediamine {LY} N,N'-Dimethylethylenediamine {} {LY} N,N'-Dimethylethylenediamine {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID8070
EC Number203-793-3
Beilstein Registry Number878142
Reaxys-RN878142
Chemical Name TranslationN,N’-二甲基乙二胺
Wiswesser Line Notation1M2M1
LabNetwork Molecule IDLN00110554
InChIKeyKVKFRMCSXWQSNT-UHFFFAOYSA-N
InChIInChI=1S/C4H12N2/c1-5-3-4-6-2/h5-6H,3-4H2,1-2H3
Canonical SMILESCNCCNC
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines

相关文献及参考

  • Reagent for protection of aldehyde groups as 2-substituted-1,3-dimethylimidazolidines, e.g. by azeotropic dehydration with benzene. The derivatives are stable to n-BuLi and LDA, and can be cleaved by acid hydrolysis, or in high yield by quaternization with MeI and mild hydrolysis: Tetrahedron, 41, 3803 (1985). With aromatic aldehydes, the imidazolidine derivatives are activated to ortho-lithiation, providing a route to o-substituted benzaldehydes: J. Org. Chem., 44, 2004 (1979).
  • Short: EINECS
  • Beilstein:4,250
  • Short: III/38B

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
RTECSKV4250000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2734 UN 2734 8/PG 2
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive Flammables area {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing GroupII
Hazard Class8/3 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique.
   (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France)
   V.9-    1974-  Volume(issue)/page/year: 17,235,1982

其他信息

  • 用途二:N,N'-二甲基乙二胺（110-70-3）用于生产头孢替安的中间体1-(2-二甲基氨基乙基)-5-巯基四唑。以甲基丙烯酸甲酯和N,N-二甲基乙二胺（110-70-3）为主要原料、二月桂酸二丁基锡为催化剂,合成了一种新型功能单体甲基丙烯酰胺乙基二甲基胺。同时也是合成萘酚萘磺酸酯的原料药。
  • 检测方法:GC
  • MOL 文件:110-70-3.mol
  • 下游产品:2-甲酰基-呋喃-2-甲酸
  • 图谱信息:N,N'-二甲基乙二胺(110-70-3)核磁图( 1 HNMR) N,N'-二甲基乙二胺(110-70-3)核磁图( 13 CNMR) N,N'-二甲基乙二胺(110-70-3)质谱(MS) N,N'-二甲基乙二胺(110-70-3)红外图谱(IR1)
  • MSDS 信息:N,N'-Dimethyl-1,2-ethanediamine(110-70-3).msds
  • TCI Shanghai:N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine,>;97.0%(GC)(T)(110-70-3)
  • 微溶于水，溶于有机溶剂。
  • Alfa Aesar:N,N'-二甲基乙二胺,95% N,N'-Dimethylethylenediamine, 95%(110-70-3)
  • Acros Organics:N,N'-二甲基乙烯基二胺 N,N'-Dimethylethylenediamine, tech., 85%(110-70-3)
  • N,N'-二甲基乙二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0720 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine 5ML 370元 2014/06/02 D0720 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine 25ML 1130元 2010/06/21 116191000 N,N'-二甲基乙二胺 N,N'-Dimethylethylenediamine , tech., 85% 100 GR 2633元
  • 存储注意事项:氮气保护
  • 外观:无色透明液体
  • 用途一:用于有机合成或用作医药中间体
  • Sigma Aldrich:110-70-3(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Potassium - Inorganic Salts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Hydrazides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes
  1. Chemical Synthesis 化学合成
  2. Others
  1. Chemical Synthesis 化学合成
  2. Others

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