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分类

• {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others
• {uni_hamburg} no charge; 1fragment
• {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Other Organosilicon

产品应用

• 用于高分子有机硅化合物的合成

相关文献及参考

• Has also been used, in the presence of a catalyst such as p-TsOH, I2, Br2 or TfOH, as a silylating agent for alcohols, phenols and carboxylic acids: Tetrahedron Lett., 21, 835 (1980); J. Org. Chem., 46, 5212 (1981). The advantage over more conventional silylation methods is that the only by-product is the neutral gas propene.
• Reactions with electrophiles illustrate the ß-effect (see Appendix 4); e.g. acid chlorides with a Lewis acid give allyl ketones: J. Organomet. Chem., 85, 149 (1975):
• Short: III/35C4
• More recent studies have shown that TMS cyclopentanes are also formed in these reactions via a competing [3+2] cycloaddition mechanism: Tetrahedron, 49, 9955 (1993). Chemoselective addition to aldehydes can be accomplished in the presence of a ketone, using Scandium(III)­ trifluoromethanesulfonate hydrate, 40566 as catalyst: Synthesis, 1822 (1998).
• In the presence of F-, functions as an allyl anion equivalent, affording homoallylic alcohols from carbonyl compounds: Tetrahedron Lett., 3043 (1978), and adding to a variety of Michael acceptors: Tetrahedron Lett., 25, 3213 (1984); J. Org. Chem., 51, 1745 (1986). For a review of reactivity in the presence of Lewis acids and F-, see: J. Prakt. Chem./ Chem. Ztg., 336, 375 (1994).
• Similarly, carbonyl compounds are converted to homoallylic alcohols: J. Organomet. Chem., 69, C15 (1974). In the TiCl4 promoted reaction with enones, behaves as an allyl anion equivalent, giving the product of conjugate addition (Hosomi-Sakurai reaction): J. Am. Chem. Soc., 99, 1673 (1977); 105, 2354 (1983); Org. Synth. Coll., 7, 443 (1990):
• Merck: 14,10335
• Short: III/35F
• Merck: 14,10335 Beilstein:4(3)1854

安全信息

GHS Symbol

其他信息

• 下游产品:
• 海关编码:29310095
• 用途二:用于高分子有机硅化合物的合成
• 图谱信息:烯丙基三甲基硅烷(762-72-1)核磁图( 1 HNMR) 烯丙基三甲基硅烷(762-72-1)红外图谱(IR1) 烯丙基三甲基硅烷(762-72-1)核磁图( 13 CNMR)
• MOL 文件:762-72-1.mol
• MSDS 信息:Allyltrimethylsilane(762-72-1).msds
• 烯丙基三甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0729 烯丙基三甲基硅烷 Allyltrimethylsilane 250ML 3320元 2014/06/02 A0729 烯丙基三甲基硅烷 Allyltrimethylsilane 25ML 594元 2010/06/21 349990100 烯丙基三甲基硅烷 Allyltrimethylsilane 97% 10 ML 353元
• Acros Organics:烯丙基三甲基硅烷 Allyltrimethylsilane, 97%(762-72-1)
• 烯丙基三甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A0729 烯丙基三甲基硅烷 Allyltrimethylsilane 250ML 3970元 2011/04/16 A0729 烯丙基三甲基硅烷 Allyltrimethylsilane 25ML 779元 2010/06/21 349990100 烯丙基三甲基硅烷 Allyltrimethylsilane 97% 10 ML 353元
• 用途一:用于高分子有机硅化合物的合成。
• 方法一:由三甲基氯硅烷和烯丙基溴化镁反应而得。
• TCI Shanghai:烯丙基三甲基硅烷 Allyltrimethylsilane,>;98.0%(GC)(762-72-1)
• Alfa Aesar:烯丙基三甲基硅烷,99% Allyltrimethylsilane, 98+%(762-72-1)
• 上游原料:三甲基氯硅烷 --> 3-溴丙烯
• Sigma Aldrich:762-72-1(sigmaaldrich)
• 能与有机溶剂混合，不溶于水。
• TSCA:Yes