Aluminium Isopropoxide 异丙醇铝

CAS 555-31-7 MFCD00008870

化学结构图

555-31-7
SMILES: CC(C)O[AlH3](OC(C)C)OC(C)C

化学属性

Mol. FormulaC9H21AlO3
Mol. Weight204.25
Density1.035
Melting Point132.0 to 140.0 deg-C
Refractive index1.0346
TSCAYes
Boiling Point125-130
Solubility溶于乙醇、异丙醇、苯、甲苯、氯仿、四氯化碳和石油烃。
Flash Point46 ºC
Stability空气及湿度敏感
Appearance 吸湿性白色固体。 溶于乙醇、异丙醇、苯、甲苯、氯仿、四氯化碳和石油烃。

别名和识别编码

Chemical NameAluminium Isopropoxide
Synonym Isopropoxide (Aluminium) {LY} Isopropoxide (Aluminium) {} {LY} Isopropoxide (Aluminium) {} {} {LY} Isopropoxide (Aluminium) {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropoxide (Aluminium) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Isopropoxide (A
CAS Number555-31-7
PubChem Substance ID87561903
EC Number209-090-8
Beilstein Registry Number3910275
MDL NumberMFCD00008870
Reaxys-RN3910275
Merck Number347
Chemical Name Translation异丙醇铝
Wiswesser Line NotationOY1&1 3 &-AL-
LabNetwork Molecule IDLN00222065
InChIInChI=1S/3C3H7O.Al/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
Canonical SMILESCC(C)O[Al](OC(C)C)OC(C)C
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Acids, Acids & Bases, Aluminum, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Micro/NanoElectronics, Solution Deposition Precursors,
  • {SNA} Acids,
  • {SNA} Aluminum, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis
  • {SNA} Acids, Acids & Bases, Aluminum, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Micro/NanoElectronics, Solution Deposition Precursors, Synthetic Reagents, 材料科学
  • {SNA} Aluminum, Catalysis and Inorganic Chemistry, Chemical Synthesis, Lewis Acids, Synthetic Reagents

产品应用

  • 医药中间体、有机催化反应。

相关文献及参考

  • Merck:14,347 Beilstein: 1,IV,1468
  • Short: EINECS
  • Short: IV/18A
  • Short: IV/20B
  • Merck:14,347

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H228 Flammable solid 易燃固体
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 4.1 F
RTECSBD0975000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 1325 3181 UN 3181 4.1/PG 2 UN3181
Risk Statements
  • R11 Highly flammable 非常易燃
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27/28
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S8 Keep container dry 保持容器干燥；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {}
Packing GroupII
Hazard Class4.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 11300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

其他信息

  • 用途一:是异植物醇、睾丸素、黄体酮、炔孕酮等激素类药物的中间体，也是铝酸酯偶联剂的原料之一
  • TCI Shanghai:异丙醇铝 Aluminum Isopropoxide,>;98.0%(T)(555-31-7)
  • 海关编码:29051900
  • 毒性分级:低毒
  • 和水反应，溶于乙醇、异丙醇、苯、甲苯、氯仿和四氯化碳。易吸湿，遇水分解成氢氧化铝和异丙醇。
  • 急性毒性:口服-大鼠LD50: 11300 毫克/公斤
  • 储运特性:库房通风低温干燥
  • 用途三:用作脱水剂、催化剂和防水剂的原料。
  • 类别:有毒物品
  • Sigma Aldrich:555-31-7(sigmaaldrich)
  • 用途四:医药中间体、有机催化反应。 异植物醇、睾丸素、沃氏氧化物、黄体酮、雄烯二酮、炔孕酮等激素类医药中间体，橡塑加工用铝酸酯偶联剂的原料之一，油墨增稠剂－脂肪酸铝氧六环化合物AOC18的原料，也用途活性催化剂及载体，无机膜，适作还原剂、脱水剂、防水剂。
  • 图谱信息:异丙醇铝(555-31-7)红外图谱(IR2) 异丙醇铝(555-31-7)红外图谱(IR1) 异丙醇铝(555-31-7)质谱(MS)
  • 方法一:由异丙醇和铝在氧化铝催化下反应而得。原料消耗定额：异丙醇1255kg/t、铝166kg/t。
  • 上游原料:异丙醇 --> 铝
  • 职业标准:TWA 2 毫克（铝）/立方米
  • Alfa Aesar:异丙醇铝,99.99+%(金属主成分) Aluminum isopropoxide, 99.99+% (metals basis)(555-31-7)
  • MOL 文件:555-31-7.mol
  • 用途二:用作还原剂、强脱水剂
  • 灭火剂:干粉、泡沫、砂土、二氧化碳
  • TSCA:Yes
  • Acros Organics:异丙醇铝 Aluminium isopropoxide, 99.99%(555-31-7)
  • 防护措施:本品有毒。对大鼠的LD50为11.3g/kg。设备应密闭，操作人员应穿戴防护用具。车间应通风。
  • MSDS 信息:Aluminium isopropoxide(555-31-7).msds
  • 常规方法:用铁桶密封包装。防水、防潮。按有毒化学药品规定贮运。
  • 可燃性危险特性:可燃； 燃烧产生刺激烟雾
  • ，和水反应，溶于乙醇、异丙醇、苯、甲苯、氯仿和四氯化碳。易吸湿，遇水分解成氢氧化铝和异丙醇。
  • 异丙醇铝价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80003826 异丙醇铝;异丙基氧化铝;三异丙醇铝 100g 34.9元 2011/04/16 A0246 异丙氧基铝 Aluminum Isopropoxide 100G 160元 2011/04/16 A0246 异丙氧基铝 Aluminum Isopropoxide 500G 277元
  • 下游产品:酸性氧化铝 --> 聚乙二醇 --> 肉桂醇 --> 16,17-环氧黄体酮 --> 孕酮 --> 非那雄胺 --> 抑霉唑 --> 橙花醇 --> 硝酸咪康唑 --> 三唑醇 --> 钴钼加氢脱硫催化剂 --> 沃氏物 --> 甲睾酮 --> 重整催化剂(系列产品) --> 甲基苯甲醇 --> 铝酸酯偶联剂 --> 乙酰谷酰胺铝
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Aluminum - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Titanium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  4. Aluminum - Lewis Acids
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Aluminum - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Alkoxide
  2. Aluminum
  1. CVD & ALD Precursors
  1. CVD & ALD Precursors
  2. Aluminum
  1. Metal Alkoxides for CVD & ALD
  2. Aluminum
  1. CVD & ALD Precursors
  2. Aluminum
  1. Metal Alkoxides for CVD & ALD
  2. Aluminum

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