Germanium(Iv) Ethoxide 乙氧基锗

CAS 14165-55-0 MFCD00015121

化学结构图

14165-55-0
SMILES: CCO[Ge](OCC)(OCC)OCC

化学属性

Refractive indexn20/D 1.407(lit.)
Flash Point49°(121°F)
SolubilitySoluble in anhydrous alcohol and benzene. Hydrolyzes in water
TSCAYes
Mol. FormulaC8
Mol. Weight253
Density1.14
Stabilitymoisture sensitive
Boiling Point185.5°C
Melting Point-81°C
Appearance colorless liq.

别名和识别编码

Chemical NameGermanium(Iv) Ethoxide
Synonym Germanium tetraethoxideTetraethoxygermane Tetraethoxygermanium Germanium(IV) ethoxide, 99.95+% metals basis germanic acid tetraethyl ester germanium(4+) ethanolate 乙氧基锗, 99.995% (METALS BASIS) Germanium tetraethoxide GermaniumethoxideTetraethoxygermane ethanol,germanium(4+)salt 四乙氧基锗 TETRAETHOXYGERMANE Germanium(IV)ethoxide, 99.95+% Germanium (IV) ethoxide (99.99+%-Ge) PURATREM Germanium (IV) ethoxide germanicacidtetraethylester Germanium(IV) ethoxide GERMANIUM ETHYLATE Ethanol, germanium(4+) salt tetraethylorthogermanate Germanium(IV) ethylate GERMANIUM ETHOXIDE TETRAETHYOXYGERMANE 四乙氧基铭 Germanium(IV) ethylate~Tetraethoxygermanium GERMANIUM(IV) ETHOXIDE Germaniumethoxidemetalsbasiscolorlessliq tetraethyl orthogermanate GERMANIUM TETRAETHOXIDE 乙氧基锗 Ethyl alcohol germanium(4+) salt; Ethyl germanate(IV); Ethyl orthogermanate TETRAETHOXYGERMANIUM TETRAMETHOXYGERMANIUM GermaniumEthylsulfate Germanium(IV)-ethylat Tetraethoxy germane
PubChem Substance ID24860619
Beilstein Registry Number3661173
EC Number238-007-8
Chemical Name Translation乙氧基锗
MDL NumberMFCD00015121
CAS Number14165-55-0
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Germanium, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Germanium, Germanium Catalysts, Micro/NanoElectronics, Solution Deposition Precursors,
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Germanium, Germanium Catalysts, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • Catalysis and Inorganic Chemistry, Chemical Synthesis, Germanium, Materials Science, Micro/NanoElectronics,

相关文献及参考

  • 1. Mat. Res. Soc. Symp. Proc. 73 , 443, (1986)
  • 2. Non-Cryst. Solids 168 , 195, (1994)
  • Beil. 1 ,IV,1308
  • FT-NMR 1 (3), 743:A / RegBook 1 (2), 3055:A / Structure Index 1 , 484:D:3
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: IV/16 Title: Surface tension of pure liquids and binary mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/16 Year: 1997 Keyword: organic compounds; surface tension; liquids; mixtures ISBN: 3-540-63276-X ISBN: 978-3-540-63276-4 Internet Resource: DOI:10.1007/b60566 RefComment: VII, 439 pages.
  • Short: IV/18A Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organometallic and Organononmetallic Liquids, Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: La

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes T,Xi T Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
UN Number UN 1993 3/PG 3 UN1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Storage condition Moisture Sensitive
Packing GroupIII
Hazard Class3

其他信息

  • 四乙氧基铭价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 43052 乙氧基锗, 99.995% (metals basis) Germanium(IV) ethoxide, 99.995% (metals basis) 1g 364元 2010/05/25 14679 乙氧基锗, 97% Germanium(IV) ethoxide, 97% 5g 932元 2010/05/25 14679 乙氧基锗, 97% Germanium(IV) ethoxide, 97% 25g 3696元
  • MOL 文件:14165-55-0.mol
  • Sigma Aldrich:14165-55-0(sigmaaldrich)
  • Alfa Aesar:乙氧基锗,99.995%(metalsbasis) Germanium(IV) ethoxide, 99.995% (metals basis)(14165-55-0)
  • 敏感性:Moisture Sensitive
  • F:10-21
  • TSCA:Yes

系列性分类