Triisopropyl borate 硼酸三异丙酯

CAS 5419-55-6 MFCD00008872

化学结构图

5419-55-6
SMILES: CC(C)OB(OC(C)C)OC(C)C

化学属性

Mol. FormulaC9H21BO3
Mol. Weight188.07
Boiling Point139-141
TSCAT
Refractive index1.3750 to 1.3780
Density0.815
Flash Point28°C(lit.)
Melting Point-59°C
Vapor Pressure76 mmHg ( 75 °C)
Solubility分解
Stability易吸潮
Danger-Level甲类

别名和识别编码

Chemical NameTriisopropyl borate
CAS Number5419-55-6
Alfabeta NameTRIISOPROPYLBORATE
MDL NumberMFCD00008872
Synonym BORIC ACID TRIISOPROPYL ESTER BORON ISOPROPOXIDE Boric acid (H3BO3), triisopropyl ester Boric acid (H3BO3), tris(1-methylethyl) ester Boric acid triisopropyl ester, Triisopropoxyborane, Boron isopropoxide Boric acid triisopropyl ester~Isopropyl borate Boric acid, tris(1-methylethyl) ester Isopropyl borate, ((C3H7O)3B) TRIISOPROPYL BORATE Tri-isopropylborate Triisopropox Triisopropoxy borane Triisopropoxyborane Triisopropyl Borate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID21531
EC Number226-529-9
Beilstein Registry Number1,363
Reaxys-RN1701469
Chemical Name Translation硼酸三异丙酯
InChIKeyNHDIQVFFNDKAQU-UHFFFAOYSA-N
Wiswesser Line Notation1Y1&OBOY1&1&OY1&1
LabNetwork Molecule IDLN00115407
InChIInChI=1S/C9H21BO3/c1-7(2)11-10(12-8(3)4)13-9(5)6/h7-9H,1-6H3
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分类

  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organoborates, Organometallic Reagents
  • {SNA} Boron, Boronic Acids and Derivatives, CVD and ALD Precursors by Metal, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Micro/NanoElectronics, Organoborates, Organometallic Reagents, Vapor Deposition Precursors, 材料科学
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Boron, Boron
  • {SNA} Boron, Boronic Acids and Derivatives, CVD and ALD Precursors by Metal, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organoborates, Organometallic Reagents, Vapor Deposition Precursors

产品应用

  • 用作溶剂、半导体硼扩散源。

相关文献及参考

  • Reagent for preparation of boronates from Grignard or organolithium reagents, often giving higher yields than other trialkyl borates: Organometallics, 2, 1316 (1983); Tetrahedron Lett ., 29, 2631 (1988).
  • Short: IV/18A
  • Short: III/38A
  • Short: IV/20B
  • Short: IV/16
  • Beilstein:1,363

安全信息

Warnings 危化品目录(2015) IRRITANT, FLAMMABLE
GHS Symbol
WGK Germany2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 F
RTECSED5950000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P211 Do not spray on an open flame or other ignition source.? 不要喷洒在明火或其他点火源。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 2616
Risk Statements
  • R11 Highly flammable 非常易燃
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S7 Keep container tightly closed 保存在严格密闭容器中；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Storage condition +4°C 4 4℃ Flammables area Moisture Sensitive 易吸潮，密闭保存。
Packing GroupII
Hazard Class3 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00382

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

Restrict 危险品

其他信息

  • 可燃性危险特性:易燃
  • 毒性分级:中毒
  • 硼酸三异丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010062 硼酸三异丙酯 100ml 165元 2011/04/16 B0521 硼酸三异丙酯 Triisopropyl Borate 25ML 192元 2011/04/16 B0521 硼酸三异丙酯 Triisopropyl Borate 500ML 1470元
  • MOL 文件:5419-55-6.mol
  • 无色液体,水中分解，溶于乙醇、乙醚和苯。
  • MSDS 信息:硼酸(三)异丙酯(5419-55-6).msds
  • 检测方法:GC,NMR
  • 下游产品:异喹啉-4-硼酸-2,2-二甲基丙二醇-1,3环酯 --> 2-(三氟甲氧基)苯硼酸 --> 2-甲基-5-吡啶硼酸 --> 5-甲醛基呋喃-2-硼酸 --> 3-氰嘧啶-4-硼酸,95% --> 5-嘧啶硼酸 --> 4-氰基吡啶-3-硼酸 --> 2-(甲氧基羰基)苯硼酸 --> 3-氯-4-吡啶硼酸(一水合物) --> 2-氰吡啶-3-硼酸,95% --> 3-噻吩硼酸 --> 5-甲基噻酚-2-硼酸 --> 5-甲基吡啶-3-硼酸 --> 3-甲氧基羰基苯硼酸 --> 2-异丙基苯硼酸 --> 4-羟基苯硼酸 --> 3-氯-5-氟苯硼酸 --> 3-甲氧基苯硼酸 --> 5-氟-2-甲氧基苯硼酸 --> 2-苯氧基苯硼酸 --> 2-甲氧基苯基硼酸 --> 2-乙氧基吡啶-5-硼酸 --> 2-甲氧基-5-吡啶硼酸 --> 2-氰基苯硼酸 --> 2,6-二氟苯硼酸 --> 2-溴吡啶-5-硼酸 --> 3-氰基苯硼酸 --> 2,3-二氟苯硼酸 --> 5-甲氧基吡啶-3-硼酸 --> 2-氟-4-甲基苯硼酸 --> 5-氯吡啶-2-硼酸 --> 3-异丙基苯硼酸 --> 4-氯-2-甲基苯硼酸 --> 1-萘硼酸 --> 5-溴吡啶-3-硼酸 --> 2-溴吡啶-3-硼酸 --> 对甲氧基苯硼酸 --> 4-羧基苯硼酸频那醇酯 --> 5-甲基吡啶-2-硼酸 --> 2-氯-5-吡啶硼酸
  • 类别:易燃液体
  • F:10-21
  • 存储注意事项:湿度敏感;氮气保护
  • 储运特性:库房通风低温干燥
  • TCI Shanghai:硼酸三异丙酯 Triisopropyl Borate,>;98.0%(T)(5419-55-6)
  • TSCA:T
  • 灭火剂:干粉, 二氧化碳, 砂土, 泡沫
  • 用途一:用作溶剂、半导体硼扩散源
  • 用途二:用作溶剂、半导体硼扩散源。
  • 蒸气压:76 mm Hg ( 75 °C)
  • 海关编码:29209085
  • Alfa Aesar:硼酸三异丙酯,98+% Triisopropyl borate, 98+%(5419-55-6)
  • Acros Organics:三异丙基硼酸酯 Triisopropyl borate, 98+%(5419-55-6)
  • 急性毒性:口服-小鼠 LD50: 2500 毫克/公斤
  • Sigma Aldrich:5419-55-6(sigmaaldrich)
  • 外观性质:无色液体。
  • 刺激数据:眼睛-兔子 100 毫克 中度
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Organoborates - Boronic Acids and Derivatives
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Boron - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Borylation Reagents

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