2-Ethylhexyl Acrylate 丙烯酸-2-乙基己酯

CAS 103-11-7 MFCD00009495

化学结构图

103-11-7
SMILES: C=CC(=O)OCC(CC)CCCC

化学属性

Mol. FormulaC11H20O2
Mol. Weight184.28
Density0.885 g/mL at 25 °C(lit.)
Refractive index1.4330 to 1.4370
Autoignition Point496 °F
Vapor Density6.4 (vs air)
Boiling Point215-219 °C at 760 mmHg
Vapor Pressure0.15 mmHg ( 20 °C)
Flash Point79.4°C
TSCAYes
Melting Point-90 °C
Solubility不溶于水，溶于多数有机溶剂。
Stability对光敏感

别名和识别编码

Chemical Name2-Ethylhexyl Acrylate
MDL NumberMFCD00009495
CAS Number103-11-7
EC Number203-080-7
Beilstein Registry Number2(4)1467
Synonym 2-Ethylhexyl acrylate {LY} 2-Ethylhexyl acrylate {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Ethylhexyl acrylate {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87561833
Reaxys-RN1765828
Chemical Name Translation丙烯酸-2-乙基己酯
Wiswesser Line Notation4Y2&1OV1U1
LabNetwork Molecule IDLN00224586
InChIInChI=1S/C11H20O2/c1-4-7-8-10(5-2)9-13-11(12)6-3/h6,10H,3-5,7-9H2,1-2H3
Canonical SMILESC=CC(OCC(CC)CCCC)=O
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分类

  • {SA} Acrylate, Acrylic Monomers, Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters, Materials Science, Monomers, Organic Building Blocks, Polymer Science
  • {SNA} Acrylate, Acrylic Monomers, Building Blocks, C10 to C11, Carbonyl Compounds, Chemical Synthesis, Esters, Monomers, Organic Building Blocks, Polymer Science, 材料科学
  • {SNA} Additional Standards, Alpha Sort, Analytical Standards, Chemical Class, Chromatography,

产品应用

  • 1、有机合成，溶剂。
  • 2、可聚合单体，用于软性聚合物，在共聚物中起内增塑作用。
  • 3、供制备涂料、纺织、造纸、皮革、建筑粘合剂等工业用的各种树脂。

相关文献及参考

  • Short: IV/8H
  • Short: EINECS
  • Short: IV/20B
  • Beilstein:2(4)1467
  • Short: IV/16

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
Risk Statements
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P337+P313
  • P403+P233
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P333+P313+P362+P364
  • P370+P378
  • P304+P340
  • P304+P340+P312
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P333+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P305+P351+P338+P337+P313
  • P405 Store locked up. 上锁保管。
  • P333+
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H227 Combustible liquid 可燃液体
  • H318 Causes serious eye damage 严重伤害眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSAT0855000
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 187 gm/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   JTEHD6 Journal of Toxicology and Environmental Health.  (Hemisphere Pub.,
   1025 Vermont Ave., NW, Washington, DC 20005)  V.1-    1975/76-
   Volume(issue)/page/year: 16,55,1985

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 240 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-1079-0262

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1326 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JDREAF Journal of Dental Research.  (International Assoc. for Dental
   Research, 734 15th St., NW, Suite 809, Washington, DC 20005)  V.1-    1919-
   Volume(issue)/page/year: 51,526,1972

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : >450 mg/m3
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 56(12),19,1991

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >12 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PJPPAA Polish Journal of Pharmacology and Pharmacy.  (ARS Polona, POB 1001,
   00-068 Warsaw 1, Poland) V.25-    1973-  Volume(issue)/page/year:
   32,223,1980

{

TYPE OF TEST            : LCLo - Lowest pu

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 600 mg/m3
TOXIC EFFECTS :
   Behavioral - excitement
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 19

其他信息

  • Alfa Aesar:2-乙基己基丙烯酸酯,98% 2-Ethylhexyl acrylate, 98%(103-11-7)
  • 毒性分级:中毒
  • Sigma Aldrich:103-11-7(sigmaaldrich)
  • 存储注意事项:光敏感;热敏感
  • 丙烯酸 2-乙基己酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A29081501 丙烯酸-2-乙基己酯 25ml 330元 2011/04/16 A0144 丙烯酸-2-乙基己酯单体(含稳定剂MEHQ) 2-Ethylhexyl Acrylate Monomer (stabilized with MEHQ) 25ML 131元 2011/04/16 A0144 丙烯酸-2-乙基己酯单体(含稳定剂MEHQ) 2-Ethylhexyl Acrylate Monomer (stabilized with MEHQ) 500ML 248元
  • 检测方法:GC,NMR
  • 甘甜味。易聚合，易与多种乙烯基单体共聚。能与乙醇、乙醚混溶。有催泪性、刺激性。
  • 可燃性危险特性:可燃; 加热分解释放刺激烟雾
  • MSDS 信息:丙烯酸-2-乙基己酯(103-11-7).msds
  • TCI Shanghai:丙烯酸-2-乙基己酯单体(含稳定剂甲氧基氢醌) 2-Ethylhexyl Acrylate Monomer (stabilized with MEHQ),>;99.0%(GC)(103-11-7)
  • 类别:易燃液体
  • MOL 文件:103-11-7.mol
  • 方法一:1.直接酯化法丙烯酸与2-乙基己醇以硫酸为催化剂进行酯化，再经中和，脱醇和精馏得成品。2.酯交换法丙烯酸甲酯与2-乙基己醇在催化剂四氯化钛存在下进行酯交换反应生成丙烯酸-2-乙基己酯，经精馏制得成品。
  • 刺激数据:皮肤-兔子 20 毫克/24小时 中度; 眼睛-兔子 5 毫克 重度
  • 蒸气压:0.15 mm Hg ( 20 °C)
  • 海关编码:29161290
  • 用途三:1、有机合成，溶剂。 2、可聚合单体，用于软性聚合物，在共聚物中起内增塑作用。3、供制备涂料、纺织、造纸、皮革、建筑粘合剂等工业用的各种树脂。
  • 储运特性:库房通风低温干燥
  • Acros Organics:丙烯酸-2-乙基己酯 2-Ethylhexyl acrylate, stabilized, 99+%(103-11-7)
  • 蒸气密度:6.4 (vs air)
  • 急性毒性:腹腔-大鼠 LD50: 1670 毫克/公斤; 口服-小鼠 LD50: 4400 毫克/公斤
  • 上游原料:丙烯酸甲酯 --> 丙烯酸 --> 正辛醇 --> 2-乙基己醇 --> 四氯化钛
  • 用途二:丙烯酸2-乙基已酯为高分子聚合物的单体，与其他单体进行共聚、交联、接枝等到丙烯酸类树脂产品，用于合成纤维织物加工、粘合剂、涂料、塑料改性等许多方面。
  • 用途一:用作聚合单体，用于软性聚合物，在共聚物中起内增塑作用
  • F:10-23
  • 外观性质:无色液体。
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 图谱信息:丙烯酸 2-乙基己酯(103-11-7)红外图谱(IR2) 丙烯酸 2-乙基己酯(103-11-7)红外图谱(IR1) 丙烯酸 2-乙基己酯(103-11-7)Raman光谱 丙烯酸 2-乙基己酯(103-11-7)核磁图( 13 CNMR) 丙烯酸 2-乙基己酯(103-11-7)质谱(MS)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Esters - Chemical Class
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Ammonium - Inorganic Salts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. E - Alphabetic
  5. EQ - EZ - E
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C10 to C11 - Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C10 to C11 - Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Acrylic Monomers 丙烯酸单体
  5. Acrylamide and Methacrylamide

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