Diethyl methylphosphonate 甲基磷酸二乙酯

CAS 683-08-9 MFCD00009813

化学结构图

683-08-9
SMILES: CCOP(C)(=O)OCC

化学属性

Mol. FormulaC₅H₁₃O₃P
Mol. Weight152.13
Density1.041 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.414(lit.)
Boiling Point194 °C(lit.)
Flash Point75°(167°F)
TSCANo

别名和识别编码

Chemical NameDiethyl methylphosphonate
Synonym 1-(Ethoxy-methylphosphoryl)oxyethane AURORA KA-1413 DEMP DEMP Diethoxymethylphosphine oxide 双(二乙氧基氧膦基)甲烷 DIETHYL METHANEPHOSPHONATE DIETHYL METHANEPHOSPONATE DIETHYL METHYLPHOSPHONATE Diethoxymethylphosphine oxide Diethyl Methylphosphonate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {uni_hamburg} O,O-Diethyl methylpho {} {} {} {} {} {} {} {} {uni_hamburg} Methylphosphonsäurediethylester {} {} {} {} {} {} {} {} {} {uni_hamburg} Methylphosphonic acid, diethyl ester {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Methylphosphonic acid diethyl {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} Methanphosphonsäure-diethylester {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} METHYLPHOSPHONIC ACID DIETHYL ESTER {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalb
CAS Number683-08-9
EC Number211-667-4
Beilstein Registry Number1753416
MDL NumberMFCD00009813
PubChem Substance ID12685
Chemical Name Translation甲基磷酸二乙酯
InChIKeyNYYLZXREFNYPKB-UHFFFAOYSA-N
LabNetwork Molecule IDLN00199007
InChIInChI=1S/C5H13O3P/c1-4-7-9(3,6)8-5-2/h4-5H2,1-3H3
Canonical SMILESCCOP(=O)(C)OCC
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/38A Title: Refractive Indices of Inorganic, Organometallic, and Organononmetallic Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38A Year: 1996 Keyword: organicmetallic compounds; inorganic compounds; refractive index; liquids; mixtures ISBN: 3-540-60539-8 ISBN: 978-3-540-60539-3 Internet Resource: DOI:10.1007/b55612 RefComment: VII, 400 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/18A Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organometallic and Organononmetallic Liquids, Binary Liquid Mixtures Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18A Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures ISBN: 3-540-64584-5 ISBN: 978-3-540-64584-9 Internet Resource: DOI:10.1007/b68239 RefComment: VII, 409 pages.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: IV/6 Title: Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch. Editor: Madelung, O. Source: Landolt-Börnstein, New Series Volume: IV/6 Year: 1991 Keyword: organic compounds; di

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSSZ9085000
Hazard Codes Xi 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2240 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FATOBP Farmakologiya i Toksikologiya (Kiev).  Pharmacology and Toxicology.
   (Kievskii Nauchno- Issledovatel'skii Institut Farmakologii i Toksikologii,
   Kiev, USSR)  No.1-    1964-  Volume(issue)/page/year: 10,121,1975

Storage condition 2-8°C 4°C, Hygroscopic

其他信息

  • Acros Organics:二乙基甲基磷酸酯 Diethyl methylphosphonate, 96%(683-08-9)
  • 甲基膦酸二乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 333680050 甲基膦酸二乙酯 Diethyl methylphosphonate 96% 5 GR 644元 2010/06/21 333680010 甲基膦酸二乙酯 Diethyl methylphosphonate 96% 1 GR 227元 2010/06/21 333680250 甲基膦酸二乙酯 Diethyl methylphosphonate 96% 25 GR 2224元
  • Sigma Aldrich:683-08-9(sigmaaldrich)
  • MOL 文件:683-08-9.mol
  • Alfa Aesar:甲基磷酸二乙酯,97% Diethyl methylphosphonate, 97%(683-08-9)
  • MSDS 信息:Diethyl methylphosphonate(683-08-9).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonates/Phosphinates - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Horner-Wadsworth-Emmons Reagents - Olefination