Ferric Chloride 无水三氯化铁

CAS 7705-08-0 MFCD00011005

化学结构图

7705-08-0
SMILES: Cl[Fe](Cl)Cl

化学属性

Mol. FormulaFeCl3
Mol. Weight162
Melting PointNo Data Available
Density0.868 g/mL at 25 °C
SolubilityFreely soluble in water, alcohol, ether, acetone. Slightly soluble in CS2. Insoluble in ethyl acetate
TSCAYes
Boiling Point
Vapor Density5.61 (vs air)
Vapor Pressure1 mmHg ( 194 °C)
Refractive indexn20/D 1.414
Stability对湿度敏感
Flash Point316°C
Appearance powder
RedoxOxidation
Danger-Level-
pH-:-

别名和识别编码

Chemical NameIron(III) chloride
Synonym Chlorure perrique Eisen(III)-chlorid wasserfrei Eisen(III)-chlorid, wasserfrei Eisen(III)chlorid Eisen-III-chlorid Eisentrichlorid FERRIC FeCl(3) Ferric chloride Ferric chloride, anhydrous Flores martis IRON (III) CHLORIDE ON SILICA IRON ATOMIC SPECTROSCOPY STANDARD IRON CHLORIDE IRON(III) CHLORIDE Iron chloride (FeCl3) Iron trichloride Molysite 氯化铁 Iron(III) Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number7705-08-0
PubChem Substance ID24380
EC Number231-729-4
MDL NumberMFCD00011005
Merck Number14,4019
Chemical Name Translation无水三氯化铁
Wiswesser Line NotationFE G3
LabNetwork Molecule IDLN00194169
InChIInChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
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分类

  • {SNA} ATRP, ATRP Metal Salts, Acids, Acids & Bases, Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Iron, Iron Salts, Lewis Acids, Metal and Ceramic Science, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Research Essentials, Salts, Synthetic Reagents, 材料科学
  • {Che
  • {SNA} 12 Pr
  • {SNA} Essential Chemicals, Iron Salts, Research Essentials, Salts
  • {SNA} Biochemical Reagents for Identification, Identification Tests & Reagents, Microbiology
  • {SNA} Catalysis and Inorganic Chemistry,

产品应用

  • 主要用作工业水处理、照相和印刷制版的腐蚀剂、有机合成工业的催化剂、氧化剂,染料工业的氧化剂和媒染剂制造其它铁盐、颜料、墨水、医药的原料等
  • 高纯级(99.99%)在氢作用下和金属卤化物气相共还原产生可分离的金属间化合物,该化合物具有导热导电、磁感应和抗氧化特性。

相关文献及参考

  • Merck: 14,4019
  • Short: II/25A
  • Short: III/20b

安全信息

GHS Symbol
WGK Germany1
Hazard Codes 8 C,Xn,Xi Xi Xn
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Faceshields, Gloves Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSLJ9100000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P312
  • P301+P316
  • P301+P317
  • P301+P330+P331
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P307+P311
  • P308+P313
  • P308+P316
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P332+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
UN Number 1773
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36 Irritating to eyes 刺激眼睛
  • R38 Irritating to skin 刺激皮肤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Storage condition +20°C 2-8°C 20 20℃ Hygroscopic 充氩保存 密封充氩保存。
Packing GroupIII
Hazard Class8
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 58 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKKZAJ Yakugaku Zasshi.  Journal of Pharmacy.  (Nippon Yakugakkai, 2-12-15
   Shibuya, Shibuya-ku, Tokyo 150, Japan)  No.1-    1881-
   Volume(issue)/page/year: 87,677,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 895 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TRENAF Kenkyu Nenpo--Tokyo-toritsu Eisei Kenkyusho.  Annual Report of Tokyo
   Metropolitan Research Laboratory of Public Health.  (Tokyo-toritsu Eisei
   Kenkyusho, 24-1, 3-chome, Hyakunin-cho, Shin-juku-ku, Tokyo 160, Japan) V.1-
      1949/50-  Volume(issue)/page/year: 27,159,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 450 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 39(5),16,1974

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 500 nmol/tube
REFERENCE :
   LAMEDS LARC Medical.  (19 bis, rue d'Inkermann, 59000 Lille, France)  V.1-
   1981-  Volume(issue)/page/year: 6,252,1986

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 41 ng/well
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 260,349,1991

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intratesticular
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 12976 ug/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
   JRPFA4 Journal of Reproduction and Fertility.  (Biochemical Soc. Book Depot,
   POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK)  V.1-    1960-
   Volume(issue)/page/year: 7,21,1964

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravaginal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 29 mg/kg
SEX/DURATION            : female 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
REFERENCE :
   CCPTAY Contraception.  (Geron-X, Inc., POB 1108, Los Altos, CA 94022)  V.1-
   1970-  Volume(issue)/page/year: 4,91,1971

Restrict -

其他信息

  • 灭火剂:水、二氧化碳、泡沫
  • 图谱信息:三氯化铁(7705-08-0)红外图谱(IR1)
  • 用途五:主要用作饮水的净水剂和废水的处理净化沉淀剂。印染工业用作靛蓝染料染色时的氧化剂和印染媒染剂。有机合成二氯乙烷等生产的催化剂。银矿和铜矿的氯化浸提剂。照相和印刷制版的刻蚀剂。制造磷酸铁等铁盐、医药、颜料和墨水的原料。在建筑混凝土中渗入其溶液后能增加建筑物强度、抗腐蚀性和防止渗水。用于电子工业线路板及荧光数字筒生产。生产肥皂的废液回收甘油时的凝聚剂。
  • 下游产品:2,2'-联吡啶 --> 敌稗 --> 乳酸亚铁 --> 氯乙烯 --> 2,3-二氯-1,4-萘醌 --> 2-氨基-5-羧基-1,3,4-噻二唑 --> 反式-1,4-二氯-2-丁烯 --> 6-甲基-2-吡啶腈 --> 2-氯-6-硝基甲苯 --> 2-氯-4-硝基苯甲酸 --> 氯醚菊酯 --> 3-氯对甲苯胺 --> 2,3,4-三甲氧基苯硼酸 --> 丁烯酯甲酸 --> 乙二胺四乙酸铁钠 --> 酮麝香 --> 焦磷酸铁 --> 邻甲氧基苯丙酮 --> 甜菊糖 --> 2-氨基-1,3,4-噻二唑-5-甲酸乙酯 --> 3,4-己二酮 --> (1S)-(+)-3-蒈烯 --> 7-(3,5,6-三甲基-1,4-苯醌-2-基)-7-苯基庚酸 --> 聚丁噻吩 --> 间氯三氟甲苯 --> 环烷酸铁 --> 间三氟甲基三氯甲苯 --> 2,5-二氯苯甲酰氯 --> 6-甲氧基-4-甲基喹啉 --> 对氯苯基对氯苯磺酸酯 --> 聚(3-烷基噻吩)纤维 --> 油黑 --> 3,4-噻吩二羧酸 --> 4-(三氟甲氧基)苯乙酮 --> 2-氨基-3-羟基吩嗪 --> 2,3-二氨基酚嗪 --> 2,5-二氯对二甲苯 --> 磷酸亚铁 --> 田安
  • {Chemi
  • 用途四:用作饮水的净水剂和废水的处理净化沉淀剂。用于印刷电路作刻蚀剂。
  • 三氯化铁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81015228 无水三氯化铁 500g 9.3元 2010/06/21 169430025 三氯化铁 Iron(III) chloride 98%, pure, anhydrous 2.5 KG 989元 2010/06/21 169430050 三氯化铁 Iron(III) chloride 98%, pure, anhydrous 5 GR 261元
  • 可燃性危险特性:高温分解有毒氯气
  • 上游原料:氯 --> 铁粉 --> 氧 --> 铁屑 --> 氟氯菊酯 --> 六水三氯化铁 --> 氯化亚铁 --> 游离氯
  • 毒性分级:中毒
  • Sigma Aldrich:7705-08-0(sigmaaldrich)
  • Acros Organics:三氯化铁 Iron(III) chloride, reagent, anhydrous (powder), 98%(7705-08-0)
  • 蒸气压:1 mm Hg ( 194 °C)
  • 类别:腐蚀物品
  • 防护措施:三氯化铁有腐蚀性。其粉尘能刺激粘膜引起炎症。 生产操作人员和装卸搬运人员要穿工作服、橡皮围裙，戴乳胶手套等劳保用品，防止与皮肤接触，生产设备要密闭，车间通风良好。
  • 无臭,有涩味。易溶于水,溶于乙醇、乙醚和丙酮，微溶于CS2，不溶于乙酸乙酯。其溶液呈酸性。可使蛋白质凝固。有潮解性,
  • 用途一:主要用作水处理剂，还用作媒染剂、催化剂、氯化剂，并用于制造其他铁盐等 主要用于净水，也用于印刷制板、颜料、染料及药物等
  • 用途七:主要用作工业水处理、照相和印刷制版的腐蚀剂、有机合成工业的催化剂、氧化剂,染料工业的氧化剂和媒染剂制造其它铁盐、颜料、墨水、医药的原料等高纯级(99.99%)在氢作用下和金属卤化物气相共还原产生可分离的金属间化合物,该化合物具有导热导电、磁感应和抗氧化特性。
  • 方法二:在由铁屑与盐酸制得的氯化亚铁溶液内，通入氯气，转变成氯化铁溶液。再加铁还原成氯化亚铁溶液，重新通入氯气制成氯化铁溶液。重复这一操作至氯化铁的浓度提高到约60%，放冷析出晶体(含水物)。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iron - 铁催化剂
  1. Life Science 生命科学
  2. Microbiology 微生物学
  3. Identification Tests & Reagents - Microbiology
  4. Biochemical Reagents for Identification - Identification Tests & Reagents
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. Reagent Grade - Inorganic Salts, Solutions and Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  4. Boron - Lewis Acids
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  4. Iron - Lewis Acids
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents TLC - Derivatization Reagents
  5. TLC Visualization Reagents (by application) - Derivatization Reagents TLC
  6. Amines - TLC Visualization Reagents (by application)
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 10.00 g/L - AAS Concentrates
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 1.00 g/L - AAS Concentrates
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 1.00 g/L - AAS Concentrates
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Crystal Grade Inorganics 晶体级无机物
  4. Iron - Crystal Grade Inorganics
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Iron - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Iridium
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (alphabetic sort)
  4. TLC Reagents, A-C
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (alphabetic sort)
  4. TLC Reagents, D-F
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Alkaloids
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. TLC Visualization Reagents (by application)
  4. Nitrogen-containing compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (alphabetic sort)
  5. TLC Reagents, A-C
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (alphabetic sort)
  5. TLC Reagents, D-F
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Alkaloids
  1. Analytical & Chromatography 分析化学与色谱
  2. Derivatization Reagents
  3. Derivatization Reagents TLC
  4. TLC Visualization Reagents (by application)
  5. Nitrogen-containing compounds
  1. Chemical Synthesis 化学合成
  2. 无机盐
  1. Chemical Synthesis 化学合成
  2. 无机盐
  1. Chemical Synthesis 化学合成
  2. 无机盐