Tetrabutylammonium Chloride 四正丁基氯化铵

CAS 1112-67-0 MFCD00011635

化学结构图

1112-67-0
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[Cl-]

化学属性

Mol. FormulaC16H36ClN
Mol. Weight277.92
Melting Point47-50°C
TSCAYes
Density1.05
Solubility可溶
Stability对光线和湿度敏感
Flash Point113°C
Appearance 白色至类白色晶体,密度 1.05 ,熔点 83-86 ℃ ,可溶于水。

别名和识别编码

Chemical NameTetrabutylammonium Chloride
CAS Number1112-67-0
PubChem Substance ID70681
Beilstein Registry Number3571227
MDL NumberMFCD00011635
EC Number214-195-7
Reaxys-RN3571227
Synonym Tetrabutylammonium chloride {LY} Tetrabutylammonium chloride {} {LY} Tetrabutylammonium chloride {} {} {LY} Tetrabutylammonium chloride {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium chloride {} {
Chemical Name Translation四正丁基氯化铵
InChIKeyNHGXDBSUJJNIRV-UHFFFAOYSA-M
LabNetwork Molecule IDLN00195023
InChIInChI=1S/C16H36N.ClH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
Canonical SMILESCCCC[N+](CCCC)(CCCC)CCCC.[Cl-]
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分类

  • {SNA} Acidic Ion Pair Reagents (Anionic),
  • {SNA} Acidic Ion Pair Reagents (Anionic), Analytical Reagents, Analytical/Chromatography, Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, Ion Pair Reagents, Ion Pair Reagents - Anionic
  • {SNA} Acidic Ion Pair Reagents (Anionic), Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, Ion Pair Reagents, Ion Pair Reagents - Anionic Concentrate, 分析/色谱, 分析试剂
  • {SNA} Ammonium Salts, Chemical Synthesis, Phase Transfer Catalysts, Synthetic Reagents
  • {SNA} 12 Principles Alig
  • Acidic Ion Pair Reagents (Anionic), Analytical Reagents, Analytical/Chromatography, Buffers & Reagents, Chromatography Reag

产品应用

  • 离子对色谱试剂。相转移催化剂。

相关文献及参考

  • Beilstein: 4,IV,550
  • For improved phase-transfer alkylation of ethyl acetoacetate and diethyl malonate using toluene-water, see: Org. Prep. Proced. Int., 26, 469 (1994).
  • Short: IV/1a
  • Beilstein: 4,IV,557
  • Short: IV/1b
  • Short: IV/8A
  • Phase-transfer catalyst (see Appendix 2) used in the N-alkylation of ureas: Monatsh., 123, 599 (1994).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool Store at room temperature,keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool

其他信息

  • 用途二:离子对色谱试剂。相转移催化剂。
  • MOL 文件:1112-67-0.mol
  • Alfa Aesar:四正丁基氯化铵(uptoca15%bromide),95%extotalhalide Tetra-n-butylammonium chloride (up to ca 15% bromide), 95% ex total halide(1112-67-0)
  • 四丁基氯化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30173981 四正丁基氯化铵 25g 310元 2011/08/23 xw060010 四丁基氯化铵一水合物 100g 300元 2011/04/16 I0366 四丁基氯化铵[离子对色谱用试剂] Tetrabutylammonium Chloride [Reagent for Ion-Pair Chromatography] 25G 1750元
  • 易潮解。易溶于水、乙醇、氯仿和丙酮,微溶于苯和乙醚。有刺激性。商品也有含结晶水的。
  • TCI Shanghai:四正丁基氯化铵 Tetrabutylammonium Chloride,>;98.0%(T)(1112-67-0)
  • 检测方法:T
  • Sigma Aldrich:1112-67-0(sigmaaldrich)
  • 图谱信息:四丁基氯化铵(1112-67-0)红外图谱(IR1) 四丁基氯化铵(1112-67-0)质谱(MS) 四丁基氯化铵(1112-67-0)核磁图( 1 HNMR) 四丁基氯化铵(1112-67-0)核磁图( 13 CNMR) 四丁基氯化铵(1112-67-0)红外图谱(IR3) 四丁基氯化铵(1112-67-0)红外图谱(IR2)
  • 敏感性:Light Sensitive
  • MSDS 信息:Tetrabutyl ammonium chloride(1112-67-0).msds
  • F:8-10-23
  • 下游产品:4,6-二甲氧基嘧啶-2-磺酰氯 --> 灭草喹 --> 三联吡啶氯化钌六水合物 --> 3-氨基苯异丙醚
  • 用途一:用作极谱分析试剂
  • Acros Organics:四丁基氯化铵 Tetrabutylammoniumchloride,tech.,containsalsobromide,95%(1112-67-0)

系列性分类


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