Tetraethylammonium tetrafluoroborate 四氟硼酸四乙胺

CAS 429-06-1 MFCD00011827

化学结构图

429-06-1
SMILES: CC[N+](CC)(CC)CC.F[B-](F)(F)F

化学属性

Mol. FormulaC8H20BF4N
Mol. Weight217
Melting Point300
TSCAYes
Appearance 白色至类白色晶体
Solubilityacetonitrile: 0.1 g/mL, clear, colorless
Density1.374
Stability对湿度敏感

别名和识别编码

Chemical NameTetraethylammonium tetrafluoroborate
MDL NumberMFCD00011827
CAS Number429-06-1
PubChem Substance ID2724277
EC Number207-055-1
Beilstein Registry Number3917638
Synonym TETRAETHYLAMMONIUM FLUOROBORATE 四乙基氟硼酸铵 TETRAETHYLAMMONIUM TETRAFLUOROBORATE, 99 % 四乙基四氟硼酸铵;四氟硼酸四乙铵 四乙基四氟硼酸铵 四氟硼酸四乙胺 Tetraethylazanium tetrafluoroborate Tetraethylammonium tetrafluoroborate 99% TETRAETHYLAMMONIUM TETRAFLUOROBORATE Tetraethylaminium·tetrafluoroboronanion Ethanaminium, N,N,N-triethyl-, tetrafluoroborate(1-) Tetraethylammonium·tetrafluoroboronanion TETRAETHYLAMMONIUM TETRAFLUOROBORATE, EL ECTROCHEM. GRADE
Chemical Name Translation四氟硼酸四乙胺
Reaxys-RN3917638
InChIKeyDERCYJCSMRCWEQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00202425
InChIInChI=1S/C8H20N.BF4/c1-5-9(6-2,7-3)8-4;2-1(3,4)5/h5-8H2,1-4H3;/q+1;-1
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分类

  • {SNA} Ammonium Salts, Chemical Synthesis,
  • {SNA} Ammonium Salts, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Phase Transfer Catalysts, Salts, Synthetic Reagents
  • {SA} Ammonium Salts,
  • {SNA} Ammonium Salts, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Phase Transfer Catalysts, Research Essentials, Salts, Synthetic Reagents, 材料科学
  • {SNA} Ammonium Salts, Chemical Synthesis, Electrochemistry, Phase Transfer Catalysts, Supporting Electrolytes for Electrochemistry, Synthetic Reagents, 分析/色谱, 分析试剂

相关文献及参考

  • Electrolyte for electro-organic synthesis, e.g. in the o- and p- hydroxylation of simple aromatic ketones, acids and esters by anodic oxidation in TFA: J. Chem. Soc., Chem. Commun., 262 (1975). In CH3CN, the products are the corresponding o- and p-acetamido compounds (cf Ritter reaction).
  • Use as a supporting electrolyte and F- source for electrochemical fluorination has also been reported: J. Electroanal. Chem., 43, 318 (1973).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312+H332
  • H302 Harmful if swallowed 吞食有害
  • H332 Harmful if inhaled 吸入有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Packing GroupIII
UN Number 1759 2811
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Hygroscopic
Hazard Codes 6.1 Xn Xn,Xi
Hazard Class8

其他信息

  • MOL 文件:429-06-1.mol
  • Alfa Aesar:四乙基四氟硼酸铵,99% Tetraethylammonium tetrafluoroborate, 99%(429-06-1)
  • TCI Shanghai:四乙基四氟硼酸铵 Tetraethylammonium Tetrafluoroborate,>;98.0%(T)(429-06-1)
  • 海关编码:29239000
  • 上游原料:氟硼酸钠 --> 四乙基溴化铵
  • Acros Organics:四乙基四氟硼酸铵 Tetraethylammonium tetrafluoroborate, 99%(429-06-1)
  • Hazard Note:Irritant/Hygroscopic
  • 图谱信息:四乙基四氟硼酸铵(429-06-1)核磁图( 1 HNMR) 四乙基四氟硼酸铵(429-06-1)核磁图( 13 CNMR) 四乙基四氟硼酸铵(429-06-1)红外图谱(IR2) 四乙基四氟硼酸铵(429-06-1)红外图谱(IR1) 四乙基四氟硼酸铵(429-06-1)质谱(MS)
  • MSDS 信息:Tetraethylammonium tetrafluoroborate(429-06-1).msds
  • Sigma Aldrich:429-06-1(sigmaaldrich)
  • 敏感性:Hygroscopic
  • 四乙基四氟硼酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0983 四乙基四氟硼酸铵 Tetraethylammonium Tetrafluoroborate 25G 636元 2010/06/21 221615000 四乙基四氟硼酸铵 Tetraethylammonium tetrafluoroborate 99% 500 GR 15479元 2010/06/21 221610250 四乙基四氟硼酸铵 Tetraethylammonium tetrafluoroborate 99% 25 GR 987元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Ammonium Salts - Phase Transfer Catalysts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amine Salts - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Ammonium Salts - Salts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  1. Functional Group 官能团索引
  2. quaternary ammonium salt