Tris(4-Chlorophenyl)Phosphine 三(4-氯苯基)膦

CAS 1159-54-2 MFCD00013639

化学结构图

1159-54-2
SMILES: Clc1ccc(P(c2ccc(Cl)cc2)c2ccc(Cl)cc2)cc1

化学属性

Mol. Formula(ClC6H4)3P
Mol. Weight365.62
Melting Point100-103 °C(lit.)
TSCANo
Appearance white xtl.
Boiling Point427.6°C at 760 mmHg
Flash Point212.4°C

别名和识别编码

Chemical NameTris(4-Chlorophenyl)Phosphine
Synonym Tris(4-chlorophenyl)phosphine {LY} Tris(4-chlorophenyl)phosphine {} {LY} Tris(4-chlorophenyl)phosphine {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-chlorophenyl)
MDL NumberMFCD00013639
CAS Number1159-54-2
PubChem Substance ID70874
EC Number214-596-7
Beilstein Registry Number751458
Alfabeta NameTRISCHLOROPHENYLPHOSPHINE 4()-
Chemical Name Translation三(4-氯苯基)膦
InChIKeyIQKSLJOIKWOGIZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00183056
Canonical SMILESClC1=CC=C(P(C2=CC=C(Cl)C=C2)C3=CC=C(Cl)C=C3)C=C1
InChIInChI=1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
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分类

  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • In a study of the Mitsunobu coupling of phosphonic acids with alcohols in the presence of Diisopropyl­ azodicarboxyl­ate, L10386 to give phosphonate esters, reaction times were greatly reduced by the use of this phosphine in place of the usual triphenylphosphine: J. Org. Chem., 59, 658 (1994).
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Warnings IRRITANT
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under
Hazard Codes Xi
Packing GroupIII
UN Number 3278

其他信息

  • Acros Organics:三（4-氯苯基）膦 Tris(4-chlorophenyl)phosphine, 97%(1159-54-2)
  • 三(4-氯苯基)膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 422210050 三(4-氯苯基)膦 Tris(4-chlorophenyl)phosphine 97% 5 GR 2982元 2010/06/21 MB00008EA 三(4-氯苯基)膦 tri(4-chlorophenyl)phosphine 10 GR 3525元 2010/06/21 422210010 三(4-氯苯基)膦 Tris(4-chlorophenyl)phosphine 97% 1 GR 928元
  • Alfa Aesar:三（4-氯苯基）膦,98% Tris(4-chlorophenyl)phosphine, 98%(1159-54-2)
  • Sigma Aldrich:1159-54-2(sigmaaldrich)
  • MOL 文件:1159-54-2.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling - Catalysis and Inorganic Chemistry
  4. Basic Phosphine Ligands - Cross-Coupling
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Others - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling 交叉偶联
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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